Intensities of line features in vibration-rotational bands 2-0 to 6-0 of (NO)-N-14-O-16 X-2 Pi(r) and experimental evaluation of a radial function for electric dipolar moment
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10.1016/j.infrared.2005.01.002
Abstract
We measured the strengths of individual line-like features, representing unresolved A doublets, in vibration-rotational bands 2-0 to 6-0 of (NO)-N-14-O-16 within each substate of electronic ground state X(2)Pi(1/2,3/2) in mid and near infrared regions. Analyses of these data to derive values of matrix element; for vibrational transitions enabled production of a radial function for electric dipolar moment, containing seven parameters, that satisfactorily reproduces the intensities of about 700 such features for vibrational states up to v = 6. (c) 2005 Elsevier B.V. All rights reserved.