A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using MO(CO)(6)

Title:	A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using MO(CO)(6)
Authors:	Senthilvelan, Annamalai Lee, Gene-Hsiang Chung, Wen-Sheng 應用化學系 Department of Applied Chemistry
Keywords:	adamantane isoxazolines;photorearrangement;isomerization;enaminoketones
Issue Date:	2-Oct-2006
Abstract:	The MO(Co)(6)-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and beta-hydroxy ketones as minor ones; in contrast, only beta-hydroxy ketones and alpha,beta-unsaturated ketones were obtained under thermal condition. (c) 2006 Elsevier Ltd. All rights reserved.
URI:	http://dx.doi.org/10.1016/j.tetlet.2006.07.156 http://hdl.handle.net/11536/11687
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2006.07.156
Journal:	TETRAHEDRON LETTERS
Volume:	47
Issue:	40
Begin Page:	7179
End Page:	7183
Appears in Collections:	Articles

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