| 標題: | A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using MO(CO)(6) |
| 作者: | Senthilvelan, Annamalai Lee, Gene-Hsiang Chung, Wen-Sheng 應用化學系 Department of Applied Chemistry |
| 關鍵字: | adamantane isoxazolines;photorearrangement;isomerization;enaminoketones |
| 公開日期: | 2-十月-2006 |
| 摘要: | The MO(Co)(6)-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and beta-hydroxy ketones as minor ones; in contrast, only beta-hydroxy ketones and alpha,beta-unsaturated ketones were obtained under thermal condition. (c) 2006 Elsevier Ltd. All rights reserved. |
| URI: | http://dx.doi.org/10.1016/j.tetlet.2006.07.156 http://hdl.handle.net/11536/11687 |
| ISSN: | 0040-4039 |
| DOI: | 10.1016/j.tetlet.2006.07.156 |
| 期刊: | TETRAHEDRON LETTERS |
| Volume: | 47 |
| Issue: | 40 |
| 起始頁: | 7179 |
| 結束頁: | 7183 |
| 顯示於類別: | 期刊論文 |

