Title: Scalable Flow Synthesis of [6,6]-Phenyl-C-61-butyric Acid Methyl Ester (PCBM) using a Flow Photoreactor with a Sodium Lamp
Authors: Ueda, Mitsuhiro
Imai, Naoyuki
Yoshida, Shunsuke
Yasuda, Hiroshi
Fukuyama, Takahide
Ryu, Ilhyong
應用化學系
Department of Applied Chemistry
Keywords: Continuous flow;Fullerenes;Cycloaddion;Isomerization;Photoreactors
Issue Date: 1-Dec-2017
Abstract: An efficient flow system was constructed for the synthesis of [6,6]-phenyl-C-61-butyric acid methyl ester (PCBM); the process involved flow [2+1] addition of C-60 and subsequent flow photoisomerization of the resulting fulleroid to PCBM by using a flow photoreactor in combination with an Na lamp. With the present flow system, a scalable synthesis of PCBM (0.79 g/3.3 h) was achieved by continuous operation for 3.3 h.
URI: http://dx.doi.org/10.1002/ejoc.201700745
http://hdl.handle.net/11536/144134
ISSN: 1434-193X
DOI: 10.1002/ejoc.201700745
Journal: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Begin Page: 6483
End Page: 6485
Appears in Collections:Articles