Title: | Scalable Flow Synthesis of [6,6]-Phenyl-C-61-butyric Acid Methyl Ester (PCBM) using a Flow Photoreactor with a Sodium Lamp |
Authors: | Ueda, Mitsuhiro Imai, Naoyuki Yoshida, Shunsuke Yasuda, Hiroshi Fukuyama, Takahide Ryu, Ilhyong 應用化學系 Department of Applied Chemistry |
Keywords: | Continuous flow;Fullerenes;Cycloaddion;Isomerization;Photoreactors |
Issue Date: | 1-Dec-2017 |
Abstract: | An efficient flow system was constructed for the synthesis of [6,6]-phenyl-C-61-butyric acid methyl ester (PCBM); the process involved flow [2+1] addition of C-60 and subsequent flow photoisomerization of the resulting fulleroid to PCBM by using a flow photoreactor in combination with an Na lamp. With the present flow system, a scalable synthesis of PCBM (0.79 g/3.3 h) was achieved by continuous operation for 3.3 h. |
URI: | http://dx.doi.org/10.1002/ejoc.201700745 http://hdl.handle.net/11536/144134 |
ISSN: | 1434-193X |
DOI: | 10.1002/ejoc.201700745 |
Journal: | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY |
Begin Page: | 6483 |
End Page: | 6485 |
Appears in Collections: | Articles |