標題: | Intramolecular Interactions of a Phenyl/Perfluorophenyl Pair in the Formation of Supramolecular Nanofibers and Hydrogels |
作者: | Hsu, Shu-Min Lin, Yu-Chun Chang, Jui-Wen Liu, Yu-Hao Lin, Hsin-Chieh 材料科學與工程學系 Department of Materials Science and Engineering |
關鍵字: | hydrogels;nanofibers;noncovalent interactions;self-assembly;supramolecular chemistry |
公開日期: | 10-二月-2014 |
摘要: | A new system for the incorporation of a phenyl/perfluorophenyl pair in the structure of a peptide hydrogelator was developed. The strategy is based on the idea that the integration of an end-capped perfluorophenyl group and a phenylalanine with a phenyl moiety in the side chain forms an intramolecular phenyl/perfluorophenyl pair, which can be used to promote the formation of the supramolecular nanofibers and hydrogels. This work illustrates the importance of structure-hydrogelation relationship and provides new insights into the design of self-assembly nanobiomaterials. |
URI: | http://dx.doi.org/10.1002/anie.201307500 http://hdl.handle.net/11536/23790 |
ISSN: | 1433-7851 |
DOI: | 10.1002/anie.201307500 |
期刊: | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION |
Volume: | 53 |
Issue: | 7 |
起始頁: | 1921 |
結束頁: | 1927 |
顯示於類別: | 期刊論文 |