Browsing by Author "Berger, H."

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Anisotropic spin-flip-induced multiferroic behavior in kagome Cu3Bi(SeO3)(2)O2Cl
(2017-03-15)
Wu, H. C.
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Chandrasekhar, K. Devi
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Yuan, J. K.
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Huang, J. R.
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Lin, J. -Y.
Compared to the previous report on Cu3Bi(SeO3)(2)O2X (X = Cl, Br) [V. Gnezdilov et al., (arXiv: 1604.04249)], where no dielectric anomaly was observed without magnetic field near T-N similar to 25.6K, we further present the dielectric behaviors without and with magnetic field in Cu3Bi(SeO3)(2)O2Cl. At zero field H = 0, an antiferromagnetic transition from magnetization and specific heat measurements is clearly established at T-N, while no dielectric anomaly was observed. Those results are similar to the previous report [V. Gnezdilov et al., (arXiv: 1604.04249)]. Above the critical field H-c similar to 0.8 T, a metamagnetic spin-flip transition from antiferromagnetic to ferrimagnetic order at T similar to T-N is induced anisotropically only for H broken vertical bar broken vertical bar c. Meanwhile, a ferroelectric behavior from dielectric and pyroelectric current measurements is observed below T similar to T-N; then a corresponding type-II multiferroics emerges above H-c. The key mechanism of the anisotropic spin-flip-induced multiferroicity in Cu3Bi(SeO3)(2)O2Cl can be ascribed to the breaking of magnetic twofold symmetry in the bc plane above H-c.
Antiferroelectric antiferromagnetic type-I multiferroic Cu9O2(SeO3)(4)Cl-6
(2019-12-11)
Wu, H. C.
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Denisova, K. N.
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Menzel, D.
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Kakarla, D. Chandrasekhar
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Maximova, O. V.
We report that Cu9O2(SeO3)(4)Cl-6 is a new multiferroic compound. Comprehensive studies of this compound have been carried out on single crystals as well as polycrystalline samples. Magnetic susceptibility chi and specific heat C with H parallel to c axis both reveal an anomaly at T-N = 37 K associated with the long-range antiferromagnetic order. However, no signature of this phase transition is seen with the H parallel to b axis, providing evidence of the anisotropic nature of its magnetic properties. The results of chi measurements are consistent with the temperature evolution of the intensity of magnetic reflections from the neutron diffraction experiments. The magnetic structure derived from neutron scattering measurements shows that half of the Cu(5) ions carry no moments. Furthermore, an anomaly in the dielectric constant near T-N and observable magnetoelectric coupling below T-N are found. At high temperatures, a dielectric peak at T-E = 267 K is identified with no measurable spontaneous polarization below T-E, thereby suggesting an antiferroelectric order. A steplike anomaly seen in chi(T) at T-E hints the weak spin-lattice coupling. Concomitantly, high-resolution temperature-dependent synchrotron x-ray diffraction experiments elucidate a local structural distortion at T-E.
Colossal electroresistance and colossal magnetoresistance in spinel multiferroic CdCr(2)S(4)
(2010-03-22)
Sun, C. P.
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Huang, C. L.
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Lin, C. C.
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Her, J. L.
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Ho, C. J.
Colossal magnetoresistance (CMR) and colossal electroresistance (CER) induced by the electric field in spinel multiferroic CdCr(2)S(4) are reported. It is found that a metal-insulator transition in CdCr(2)S(4) is triggered by the electrical field. In magnetic fields, the resistivity rho of CdCr(2)S(4) responds similarly to that of CMR manganites. Combing previous reports, these findings make CdCr(2)S(4) the unique compound to possess all four properties of the colossal magnetocapacitive, colossal electrocapacitive, CER, and CMR. The present results open a new venue for searching new materials to show CMR by tuning electric and magnetic fields.
Colossal electroresistance and colossal magnetoresistance in spinel multiferroic CdCr2S4
(2010-03-22)
Sun, C. P.
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Huang, C. L.
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Lin, C. C.
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Her, J. L.
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Ho, C. J.
Colossal magnetoresistance (CMR) and colossal electroresistance (CER) induced by the electric field in spinel multiferroic CdCr2S4 are reported. It is found that a metal-insulator transition in CdCr2S4 is triggered by the electrical field. In magnetic fields, the resistivity rho of CdCr2S4 responds similarly to that of CMR manganites. Combing previous reports, these findings make CdCr2S4 the unique compound to possess all four properties of the colossal magnetocapacitive, colossal electrocapacitive, CER, and CMR. The present results open a new venue for searching new materials to show CMR by tuning electric and magnetic fields.
Electronic structure of pyrochlore Cd(2)Re(2)O(7)
(2009-05-13)
Huang, Shih-Wen
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Jeng, Horng-Tay
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Lin, J-Y
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Chang, W. J.
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Chen, J. M.
Detailed band structure calculations have been performed for Cd(2)Re(2)O(7) in high-, middle- and low-temperature (T) phases. The calculations are based on the observed lattice structures from x-ray diffraction measurements. The spin-orbit interaction is incorporated self-consistently in both the generalized gradient approximation (GGA) and the GGA plus Hubbard U (GGA + U) approaches. It is found that the on-site U has negligible effects on the Re 5d band structures; therefore both the GGA and GGA + U Re 5d band energies agree well with the observed O K-edge x-ray absorption spectroscopy (XAS) spectrum, whereas the Cd 4d band energy observed from photoemission spectroscopy can only be correctly reproduced by GGA + U calculations, indicating the relatively itinerant Re 5d and localized Cd 4d electrons. On the other hand, the spin-orbit coupling gives rise to nontrivial spin and orbital magnetic moments for the middle-T phase. Most unexpectedly, we found that the low-T phase exhibits quasi-two-dimensional Fermi surfaces. The calculated carrier numbers for the three phases are, at least qualitatively, consistent with the measured Hall coefficient.
Electronic structure of pyrochlore Cd2Re2O7
(2009-05-13)
Huang, Shih-Wen
;
Jeng, Horng-Tay
;
Lin, J-Y
;
Chang, W. J.
;
Chen, J. M.
Detailed band structure calculations have been performed for Cd2Re2O7 in high-, middle- and low-temperature (T) phases. The calculations are based on the observed lattice structures from x-ray diffraction measurements. The spin-orbit interaction is incorporated self-consistently in both the generalized gradient approximation (GGA) and the GGA plus Hubbard U (GGA + U) approaches. It is found that the on-site U has negligible effects on the Re 5d band structures; therefore both the GGA and GGA + U Re 5d band energies agree well with the observed O K-edge x-ray absorption spectroscopy (XAS) spectrum, whereas the Cd 4d band energy observed from photoemission spectroscopy can only be correctly reproduced by GGA + U calculations, indicating the relatively itinerant Re 5d and localized Cd 4d electrons. On the other hand, the spin-orbit coupling gives rise to nontrivial spin and orbital magnetic moments for the middle-T phase. Most unexpectedly, we found that the low-T phase exhibits quasi-two-dimensional Fermi surfaces. The calculated carrier numbers for the three phases are, at least qualitatively, consistent with the measured Hall coefficient.
Experimental evidence for a two-gap structure of superconducting NbSe(2): A specific-heat study in external magnetic fields
(2007-12-01)
Huang, C. L.
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Lin, J. -Y.
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Chang, Y. T.
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Sun, C. P.
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Shen, H. Y.
To resolve the discrepancies of the superconducting order parameter in quasi-two-dimensional NbSe(2), comprehensive specific-heat measurements have been carried out. By analyzing both the zero-field and mixed-state data with magnetic fields perpendicular (H perpendicular to c) to and parallel (H parallel to c) to the c axis of the crystal and using the two-gap model, we conclude that (1) more than one energy scale of the order parameter is required for superconducting NbSe(2) due to the thermodynamic consistency; (2) Delta(L)=1.26 meV and Delta(S)=0.73 meV are obtained; (3) N(S)(0)/N(0)=11%-20%; (4) the observation of the kink in gamma(H) curve suggests that the two-gap scenario is more favorable than the anisotropic s-wave model to describe the gap structure of NbSe(2); and (5) Delta(S) is more isotropic and has a three-dimensional-like feature and is located either on the Se or the bonding Nb Fermi sheets.
Experimental evidence for a two-gap structure of superconducting NbSe2: A specific-heat study in external magnetic fields
(2007-12-01)
Huang, C. L.
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Lin, J. -Y.
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Chang, Y. T.
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Sun, C. P.
;
Shen, H. Y.
To resolve the discrepancies of the superconducting order parameter in quasi-two-dimensional NbSe2, comprehensive specific-heat measurements have been carried out. By analyzing both the zero-field and mixed-state data with magnetic fields perpendicular (H perpendicular to c) to and parallel (H parallel to c) to the c axis of the crystal and using the two-gap model, we conclude that (1) more than one energy scale of the order parameter is required for superconducting NbSe2 due to the thermodynamic consistency; (2) Delta(L)=1.26 meV and Delta(S)=0.73 meV are obtained; (3) N-S(0)/N(0)=11%-20%; (4) the observation of the kink in gamma(H) curve suggests that the two-gap scenario is more favorable than the anisotropic s-wave model to describe the gap structure of NbSe2; and (5) Delta(S) is more isotropic and has a three-dimensional-like feature and is located either on the Se or the bonding Nb Fermi sheets.
Observation of charge-transfer-driven antiferroelectricity in 3d-pyrochlore multiferroic Cu2OCl2
(2019-03-01)
Wu, H. C.
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Yuan, J. K.
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Chandrasekhar, K. D.
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Lee, C. H.
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Li, W. H.
Very recently, multiferroic behavior close to the boiling temperature of liquid nitrogen was reported in oxohalide-based Cu2OCl2. In this study, we have established yet another novel mechanism for the origin of charge ordering in multiferroic Cu2OCl2. The direct current (DC) magnetization, specific heat, and neutron diffraction measurements confirm the antiferromagnetic (AFM) ordering (T-N) of Cu2OCl2 near 70 K. The collinear AFM spin structure in Cu(2)OCl(2)was obtained from neutron powder diffraction experiments based on the fitting to the combination of two irreducible representations-Gamma(1)circle plus Gamma(2). Electrical properties, such as dielectric constant, pyroelectric current, and polarization-electric field hysteresis-loop measurements, together suggest a long-range antiferroelectric ordering near T-E approximate to 75 K. The charge transfer from Cl to O along the c-axis was found to induce antiferroelectricity near TE and is supported from ab initio calculations. This finding largely reduces the possibility of well-known Dzyaloshinskii -Moriya interaction in the observed multiferroic behaviors and provides insight into the various origins of high-T-c multiferroics. (C) 2018 Elsevier Ltd. All rights reserved.
Phonon dynamics in CuxBi2Se3 (x=0, 0.1, 0.125) and Bi2Se2 crystals studied using femtosecond spectroscopy
(2012-09-17)
Chen, H. -J.
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Wu, K. H.
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Luo, C. W.
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Uen, T. M.
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Juang, J. Y.
Phonon dynamics in Bi, Bi2Se2, and CuxBi2Se3 (x=0, 0.1, 0.125) single crystals was investigated using femtosecond pump-probe spectroscopy. Two damped oscillations in measured transient reflectivity changes were observed, respectively, attributed to coherent optical and acoustic phonons. The frequency shift of the phonon modes in Bi-rich Bi2Se2 crystals indicates the intercalation of the additional Bi atoms into the Bi2Se3 matrix and formation of the Bi-2 layer between the quintuple layers (QLs). The deformation of QLs in CuxBi2Se3 crystals was also found. These phonon dynamics results suggest that Cu atoms in CuxBi2Se3 crystals are predominantly intercalated between pair of QLs. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4754005]
Ultrafast dynamics in topological insulators
(2013)
Luo, C. W.
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Chen, H. -J.
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Wang, H. J.
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Ku, S. A.
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Wu, K. H.
Ultrafast dynamics of carriers and phonons in topological insulators CuxBi2Se3-y (x= 0, 0.1, 0.125, y= 0, 1) was studied using femtosecond optical pump-probe spectroscopy. One damped oscillation was clearly observed in the transient reflectivity changes (Delta R/R), which is assigned to the coherent optical phonon (A(1g)(1)). According to the red shift of A(1g)(1) phonon frequency, the Cu atoms in CuxBi2Se3 crystals may predominantly intercalated between pair of the quintuple layers. Moreover, the carrier dynamics in the Dirac-cone surface state is significantly different from that in bulk state, which was investigated using optical pump mid-infrared (mid-IR) probe spectroscopy. The rising time and decay time of the negative component in Delta R/R, which is assigned to carrier relaxation in Dirac cone, is 1.62 ps and 20.5 ps, respectively.