Browsing by Author "Cartier, Alex"

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Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis
(2019-02-04)
Cartier, Alex
;
Levernier, Etienne
;
Corce, Vincent
;
Fukuyama, Takahide
;
Dhimane, Anne-Lise
Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.
Synthesis of Aliphatic Amides through a Photoredox Catalyzed Radical Carbonylation Involving Organosilicates as Alkyl Radical Precursors
(1970-01-01)
Cartier, Alex
;
Levernier, Etienne
;
Dhimane, Anne-Lise
;
Fukuyama, Takahide
;
Ollivier, Cyril
Alkyl radicals, from primary to tertiary, formed by photocatalyzed oxidation of organosilicates, are involved efficiently in radical carbonylation with carbon monoxide (CO), in the presence of various amines and CCl4, leading to a variety of amides in moderate to good yields.