Browsing by Author "Carty, AJ"

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Highly efficient electrophosphorescent devices with saturated red emission from a neutral osmium complex
(2005-06-28)
Niu, YH
;
Tung, YL
;
Chi, Y
;
Shu, CF
;
Kim, JH
Highly efficient electrophosphorescent polymer light-emitting diodes (LEDs) with saturated red emission (Commission Internationale de L'Eclairage chromaticity coordinates exactly at x = 0.67, y = 0.33) are achieved by blending a novel neutral Osmium complex into a single-component bipolar polymer host that possesses balanced hole- and electron-transporting ability. By using a tetraphenylenebiphenyldiamine (TPD)-based cross-linkable hole-transport layer as well as a layer of 1,3,5-tris(N-phenylbenzimidazol-2-yl)benzene (TPBI) as an electron-tran sport layer, a device structure with both effective hole/electron injection and efficient carriers/excitons blocking or confinement at both electrode sides is constituted. In this way, external quantum efficiency 12.8% is reached the first time with an organometallic complex with heavy metal core other than iridium.
Highly efficient red phosphorescent osmium(II) complexes for OLED applications
(2004-07-19)
Tung, YL
;
Wu, PC
;
Liu, CS
;
Chi, Y
;
Yu, JK
The nonionic, red-emitting complexes [Os(fppz)(2)L-2] (L = PPh2Me (1), PPhMe2 (2)) and [Os(bptz)(2)L-2] (L = PPh2Me (3)) were synthesized, showing highly intense red phosphorescent emission in CH2Cl2 solution at lambda(max) 617, 632, and 649 nm, respectively. The electroluminescent properties of these compounds on OLEDs showed promising device efficiencies required for future OLED applications.