Browsing by Author "Chang, Kai-Chieh"

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Alignment-Improved and Diameter-Reduced Electrospun Polymer Fibers via the Hot-Stretching Process
(1970-01-01)
Hsu, Hsun-Hao
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Chiu, Yu-Jing
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Li, Jia-Wei
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Tseng, Hsiao-Fan
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Chang, Kai-Chieh
Electrospinning is one of the most facile and versatile techniques to prepare polymer fibers ranging from micrometers to nanometers. Although several parameters can be tuned to control the sizes and morphologies of electrospun fibers, many obstacles are still encountered as the target sizes of the fibers are getting smaller; for example, the sizes of the fibers can be effectively reduced by lowering the polymer solution concentrations but beaded or beads-on-string structures are usually formed. To overcome such obstacles, here a simple technique to prepare alignment-improved and diameter-reduced fibers without bead formation by hot-stretching electrospun fibers at temperatures higher than the glass transition temperatures of the polymers is developed. Polystyrene and poly(methyl methacrylate) are both used in this work as model materials. The relationship between the draw ratio and diameter of the fibers is quantitatively analyzed, demonstrating the control of the fiber diameters. Moreover, higher degrees of alignment improvement at the middle part of the fibers than those at the end part is observed, which results in lower water contact angles at the middle part of the fibers. This work provides a useful post-treatment technique to control the sizes and orientations of electrospun polymer fibers.
Examination of the temporal effect in a flow injection analysis system using multi-channel absorbance detection
(2009-05-22)
Lin, Shu-Hui
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Chang, Kai-Chieh
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Chen, Yu-Chun
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Yu, Tiing
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Pai, Su-Cheng
In addition to the Poiseuille effect, a so-called temporal effect was proposed recently to elucidate the commonly observed tailing peak signals of flow injection analysis (FIA). A multi-channel absorbance detector was used in this study to obtain the FIA peaks on both the spatial and temporal coordinates. The temporal effect was analyzed by comparison of the profiles between the experimental and the corresponding Gaussian peaks. and by comparison of asymmetry factors between the spatial and the temporal peaks. The temporal effect appeared to be the major factor under flow rates ranging from 0.5 to 8 ml min(-1). This was despite the presence of a spatially frontal peak observed in the FIA tubing, which was found to result in a tailing peak on the temporal coordinate due to this discussed cause. in addition, the temporal effect became greater as the flow rate increased. (C) 2009 Published by Elsevier B.V.
Full-Duplex Heterogeneous Networks: Ergodic Rate Analysis with Realistic Interference Modeling
(2017-01-01)
Hu, Heng-Ming
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Liu, Chun-Hung
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Chang, Kai-Chieh
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電機工程學系
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Department of Electrical and Computer Engineering
In this paper, we adopt a realistic approach to modeling a full-duplex heterogeneous cellular network (HetNet) consisting of a tier of small cell base stations (BSs) that can perform half-duplex (HD) or full-duplex (FD) transmission depending on which duplex transmission is needed by their associated users and a tier of macro BSs that only can perform HD transmission due to their strong self-interference (SI). Two realistic issues, void cell and imperfect SI cancellation, that could exist in this HetNet are also considered in the interference model of this two-tier HetNet. We first study the Laplace transforms of the reciprocals of the signal-to-interference power ratios of users and small cell BSs and derive their explicit expressions. These Laplace transforms lead to the derivations of the ergodic rates of users and small cell BSs found in a very compact form for general power-law channel models. We show that FD does not always outperform HD in terms of ergodic rates and demonstrate how to make FD/HD transmission benefits the ergodic rates by deploying macro and small cell BSs with appropriate intensities.
Preparation and thermal dissipation of hollow carbon fibers from electrospun polystyrene/poly(amic acid) carboxylate salt core-shell fibers
(2020-05-05)
Li, Jia-Wei
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Hsu, Hsun-Hao
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Chang, Chia-Jui
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Chiu, Yu-Jing
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Tseng, Hsiao-Fan
Polyimides (PIs) possess great mechanical properties, outstanding thermal stability, solvent inertness, and the ability to be converted into carbon by thermal carbonization. Although studies on carbon materials derived from PIs have been conducted, PI-derived one-dimensional (1D) carbon materials with high surface areas, especially carbon tubes or hollow carbon fibers, have been rarely investigated. In this work, we provide a simple and facile method to prepare hollow carbon fibers by carbonizing hollow PI fibers. Blend solutions of poly(amic acid) carboxylate salts (PAAS) and polystyrene (PS) are electrospun to form core-shell PS/PAAS fibers, in which the PS and PAAS domains are used as sacrificial and precursor materials, respectively. By imidizing the PAAS to PI and selectively removing PS, hollow PI fibers can be obtained. Finally, the hollow PI fibers are carbonized to form hollow carbon fibers. The fiber samples at different stages are examined by thermal gravimetric analysis (TGA), Raman spectrometry, Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). The infrared images show that the thermal energy transfer rates of the hollow carbon fibers are higher than those of the hollow PI and PS/PI core-shell fibers, which can be attributed to the better thermal conductivity of carbon resulting from the covalent sp(2) bonding between carbon atoms and the high surface area of the hollow structure.
Radial Linear Polymer Patterns Driven by the Marangoni Instability and Lateral Phase Separation for the Formation of Nanoscale Perforation Lines
(2019-05-01)
Wu, Bo-Hao
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Chang, Kai-Chieh
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Hsu, Hsun-Hao
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Chiu, Yu-Jing
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Chiu, Tang-Yao
Phase separation under convection, related to the Marangoni instability, is critical in the development of advanced polymer processing technologies. The formation mechanisms of polymer patterns driven by the phase separation under convection, however, still require further investigations. In this work, we study the phase separation of polystyrene (PS)/poly(methyl methacrylate) (PMMA) bilayer films during the spin-coating processes. PMMA film-coated glass substrates are dripped by PS solutions in toluene before spinning. The concentration gradients of the PS solutions and the swollen PMMA films cause the surface tension-driven Marangoni instability; lateral phase separations also occur during the spin-coating processes, forming the interesting and uncommon radial linear patterns with nanoscale heights on the PS/PMMA bilayer films. By changing the solution waiting time and spin rates, the surface morphologies of the PS/PMMA bilayer films can be controlled. At longer waiting times, the higher degrees of swelling of the PMMA films by the solvents allow the formation of the polymer patterns; at higher spin-coating rates, the faster solvent evaporation improves the ordering of the polymer patterns. Furthermore, the morphologies of the PS/PMMA bilayer films can be confirmed using the selective removal technique; the PS films with linear-arranged cavities and the PMMA films with bumps can be obtained using acetic acid and cyclohexane, respectively. Finally, a proof of concept on the potentials in applying the cavities-containing PS films for nanoscale perforation lines is also demonstrated.
Sequential Selective Solvent On-Film Annealing: Fabrication of Monolayers of Ordered Anisotropic Polymer Particles
(2020-08-05)
Tseng, Hsiao-Fan
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Liang, Xiaobin
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Liu, Chih-Ting
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Chiu, Yu-Jing
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Li, Jia-Wei
Although various strategies have been developed to prepare anisotropic polymeric particles, it remains challenging to fabricate monolayers of anisotropic polymeric particles, which can extend the applications of anisotropic particles. Here, we develop a novel and facile approach to fabricate monolayers of anisotropic polymeric particles. Monolayers of polystyrene (PS) microspheres with a mean diameter of 10 mu m are deposited on glass substrates coated with poly(methyl methacrylate) films, followed by sequential selective solvent on-film annealing processes. Monolayers of anisotropic polymeric particles, such as the snowman-like PS particles, are successfully fabricated. Such unique structures possess the long-range ordering of monolayers (the structure factor) and the anisotropic geometry of individual particles (the form factor). The nanomechanical properties of the PS particles are also characterized using atomic force microscopy force volume measurements, showing a decrease in the Young's moduli of the PS particles owing to the looser packing of the polymer chains. This work provides the most facile and versatile strategy by far to fabricate monolayers of ordered anisotropic polymeric particles, which arc inaccessible by other traditional means.
Transconductance Distribution in Program/Erase Cycling of NAND Flash Memory Devices: a Statistical Investigation
(2019-03-01)
Chiu, Yung-Yueh
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Lin, I-Chun
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Chang, Kai-Chieh
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Yang, Bo-Jun
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Takeshita, Toshiaki
A new method for characterizing the evolution of oxide charge (Q(T)) generation during program/erase (P/E) cycles is developed. The concentration of Q(T) can be separated from the floating gate charge (Q(FG)) by statistically analyzing the distribution of transconductance reduction (Delta G(m,max)) after P/E cycles. The effect of the number and position of discrete Q(T) on the distribution of Delta G(m,max) is studied. The cycling dependence of the Q(T) generation is given by a fractional equation that includes a power of the number of P/E cycles in the denominator. For fewer than 30k cycles, the equation can be simplified as a power-law equation in the number of cycles with a power factor of 0.58. For more than 30k cycles, the Q(T) generation gradually goes to a plateau value Q(0) = 1.5 x 10(20) cm(-3). It is indicated that the Q(T) generation is limited by the concentration of inherent weak bonding points inside SiO2 or the Si/SiO2 interface. The temperature dependence of the Q(T) generation is also provided. The activation energy (EA) of the Q(T) generation is approximately 0.1 eV, which is compatible with the EA value of electron traps creation in SiO2.