Browsing by Author "Chen, Tzu-Pei"

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Bridging the "green gap" of LEDs: giant light output enhancement and directional control of LEDs via embedded nano-void photonic crystals
(2016-01-01)
Tsai, Yu-Lin
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Liu, Che-Yu
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Krishnan, Chirenjeevi
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Lin, Da-Wei
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Chu, You-Chen
Green LEDs do not show the same level of performance as their blue and red cousins, greatly hindering the solid-state lighting development, which is the so-called "green gap". In this work, nano-void photonic crystals (NVPCs) were fabricated to embed within the GaN/InGaN green LEDs by using epitaxial lateral overgrowth (ELO) and nano-sphere lithography techniques. The NVPCs act as an efficient scattering back-reflector to outcouple the guided and downward photons, which not only boost the light extraction efficiency of LEDs with an enhancement of 78% but also collimate the view angle of LEDs from 131.5 degrees to 114.0 degrees. This could be because of the highly scattering nature of NVPCs which reduce the interference giving rise to Fabry-Perot resonance. Moreover, due to the threading dislocation suppression and strain relief by the NVPCs, the internal quantum efficiency was increased by 25% and droop behavior was reduced from 37.4% to 25.9%. The enhancement of light output power can be achieved as high as 151% at a driving current of 350 mA. Giant light output enhancement and directional control via NVPCs point the way towards a promising avenue of solid-state lighting.
Color-conversion efficiency enhancement of quantum dots via selective area nano-rods light-emitting diodes
(2016-08-22)
Liu, Che-Yu
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Chen, Tzu-Pei
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Kao, Tsung Sheng
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Huang, Jhih-Kai
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Kuo, Hao-Chung
A large enhancement of color-conversion efficiency of colloidal quantum dots in light-emitting diodes (LEDs) with novel structures of nanorods embedded in microholes has been demonstrated. Via the integration of nano-imprint and photolithography technologies, nanorods structures can be fabricated at specific locations, generating functional nanostructured LEDs for high-efficiency performance. With the novel structured LED, the color-conversion efficiency of the existing quantum dots can be enhanced by up to 32.4%. The underlying mechanisms can be attributed to the enhanced light extraction and nonradiative energy transfer, characterized by conducting a series of electroluminescence and time-resolved photoluminescence measurements. This hybrid nanostructured device therefore exhibits a great potential for the application of multi-color lighting sources. (C) 2016 Optical Society of America
Enhanced Color-Conversion Efficiency of Hybrid Nanostructured-Cavities InGaN/GaN Light-Emitting Diodes Consisting of Nontoxic InP Quantum Dots
(2017-09-01)
Liu, Che-Yu
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Chen, Tzu-Pei
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Huang, Jhih-Kai
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Lin, Tzu-Neng
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Huang, Chia-Yen
Color-conversion efficiency enhancement of hybrid light-emitting diodes (LEDs) by cadmium-free colloidal quantum dots (QDs) and a novel selective area nanocavities structure has been demonstrated. Combining nanoimprinting and photolithography techniques, nanocavities array can be fabricated at designated locations on the LEDs. The color-conversion efficiency of selective area nanocavities LED can be enhanced by up to 13%. The significant color-conversion efficiency enhancement is attributed to resonance of InP QDs emission in nanocavities and nonradiative energy transfer from LED active layers to InPQDs, which has been investigated and characterized by finite domain time-domain simulation, electroluminescence, and time-resolved photoluminescence measurements. This hybrid nanostructured device, therefore, exhibits a great potential for the applications of multicolor lighting sources and micro-LED.
High Color-Conversion Efficiency CdSe Quantum Dots Hybrid Light Emitted Diode
(2016)
Liu, Che-Yu
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Kao, Tsung Sheng
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Chen, Tzu-Pei
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Chi, Gou-Chung
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Kuo, Hao-Chung
In this work, we have successfully demonstrated that the color-conversion efficiency in colloidal quantum dots can be greatly enhanced by light-emitting diodes (LEDs) with novel structures of nanorods embedded in microholes. Via an integrated technology of the nano-imprint and photolithography, nanorods structures can be fabricated at specific locations, generating functional nanostructured LEDs for high-efficiency light-emitting performance. With such a structured LED, the color-conversion efficiency of the existing quantum dots can be enhanced up to 12.5 %.
High-Efficiency InGaN/GaN Core-Shell Nanorod Light-Emitting Diodes With Low-Peak Blueshift and Efficiency Droop
(2017-03)
Tzou, An-Jye
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Hsieh, Dan-Hua
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Hong, Kuo-Bin
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Lin, Da-Wei
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Huang, Jhih-Kai
In this study, novel three-dimensional (3-D) nanoscale structures and methodology are demonstrated for application in high-efficiency core-shell nanorod (NR) light-emitting diodes (LEDs). The key to our successful growth of the structures is the introduction of passivation, which can be used to selectively grow active layers in desired structures. Through the fabrication methodology, core-shell NR green LEDs exhibiting large nonpolar active region and homogeneous indium distributions without a point tip shape were achieved. Stable light emission at a central wavelength of 518 nm was achieved as the injected current increased to more than 40 mA. The improved NR LEDs exhibited a stable luminescence emission wavelength (blueshift of 62 nm) and low-efficiency droop (18.1%) at 200 mA. Our scheme is scalable and compatible with current technologies, which provides a new perspective for developing high-performance, 3-D nanoscale optoelectronic devices.
Intrinsic Carrier Transport of Phase-Pure Homologous 2D Organolead Halide Hybrid Perovskite Single Crystals
(2018-12-27)
Li, Min-Ken
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Chen, Tzu-Pei
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Lin, Yen-Fu
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Raghavan, Chinnambedu Murugesan
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Chen, Wei-Liang
This work reveals the intrinsic carrier transport behavior of 2D organolead halide perovskites based on phase-pure homologous (n = 1, 2, and 3) Ruddelsden-Popper perovskite (RPP) (BA)(2)(MA)(n-1)PbnI3n+1 single crystals. The 2D perovskite field effect transistors with high-quality exfoliated 2D perovskite bulk crystals are fabricated, and characteristic output and transfer curves are measured from individual single-crystal flakes with various n values under different temperatures. Unipolar n-type transport dominated the electrical properties of all these 2D RPP single crystals. The transport behavior of the 2D organolead halide hybrid perovskites exhibits a strong dependence on the n value and the mobility substantially increases as the ratio of the number of inorganic perovskite slabs per organic spacer increases. By extracting the effect of contact resistances, the corrected mobility values for n = 1, 2, and 3 are 2 x 10(-3), 8.3 x 10(-2), and 1.25 cm(2) V-1 s(-1) at 77 K, respectively. Furthermore, by combining temperature-dependent electrical transport and optical measurements, it is found that the origin of the carrier mobility dependence on the phase transition for 2D organolead halide perovskites is very different from that of their 3D counterparts. Our findings offer insight into fundamental carrier transport behavior of 2D organic-inorganic hybrid perovskites based on phase-pure homologous single crystals.
Origin of Extended UV Stability of 2D Atomic Layer Titania-Based Perovskite Solar Cells Unveiled by Ultrafast Spectroscopy
(2019-06-19)
Thilakan, Anusha Puliparambil
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Li, Jia-Xing
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Chen, Tzu-Pei
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Li, Shao-Sian
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Chen, Chun-Wei
The inherent instability of UV-induced degradation in TiO2-based perovskite solar cells was largely improved by replacing the anatase-phase compact TiO2 layer with an atomic sheet transport layer (ASTL) of two-dimensional (2D) Ti1-delta O2. The vital role of microscopic carrier dynamics that govern the UV stability of perovskite solar cells was comprehensively examined in this work by performing time-resolved pump-probe spectroscopy. In conventional perovskite solar cells, the presence of a UV-active oxygen vacancy in compact TiO2 prohibits current generation by heavily trapping electrons after UV degradation. Conversely, the dominant vacancy type in the 2D Ti1-delta O2 ASTL is a titanium vacancy, which is a shallow acceptor and is not UV-sensitive. Therefore, it significantly suppresses carrier recombination and extends UV stability in perovskite solar cells with a 2D Ti1-delta O2 ASTL. Other carrier dynamics, such as electron diffusion, electron injection, and hot hole transfer processes, were found to be less affected by UV irradiation. Quantitative pump-probe data clearly show a correlation between the carrier dynamics and UV aging of perovskite solar cells, thus providing a profound insight into the factors driving UV-induced degradation in perovskite solar cells and the origin of its performance.