Browsing by Author "Cheng, HF"

Now showing 1 - 3 of 3

Activation of carbon nanotube emitters by using supercritical carbon dioxide fluids with propyl alcohol
(2006)
Liu, PT
;
Tsai, CT
;
Chang, TC
;
Kin, KT
;
Chang, PL
This paper explores the application of supercritical carbon dioxide fluids on the field emission enhancement for vertically aligned carbon nanotubes. The typical heating process cannot effectively activate the deionized-water-rinsed carbon nanotube emitters, exhibiting poorer field emission performance, due to residual moisture uptake in the carbon nanotubes. In contrast, the field emission enhancement can be achieved significantly by applying the supercritical carbon dioxide fluids associated with 3 to 9 vol % propyl alcohol. It is found the cosolvent propyl alcohol plays a critical role in the activation efficiency of supercritical carbon dioxide fluids. A physical model is also deduced to clarify the observation. (c) 2006 The Electrochemical Society.
Biodegradation of di-(2-ethylhexyl) phthalate in sewage sludge
(2000)
Cheng, HF
;
Chen, SY
;
Lin, JG
;
環境工程研究所
;
Institute of Environmental Engineering
Di-(2-ethylhexyl) phthalate (DEHP) is widely used as a plasticizer in the production of polyvinyl chloride to impart flexibility to the product. Because of its mutagenicity and carcinogenicity, the presence of DEHP in sludge limits the application of sludge as a soil fertilizer. In this study, sludges were collected from three sewage treatment plants and thirteen wastewater treatment plants of different industries in Taiwan. A supercritical fluid extraction (SFE) was first established as an effective method for determining the concentration of DEHP in sludge. Laboratory-scale land-simulated experiments were performed to investigate the biodegradation of DEHP in sludge under various conditions (moisture, temperature, sunlight and ventilation). DEHP was found in aerobically and anaerobically digested sludges and their values significantly exceeded the restricted concentration of DEHP for sludge land application. DEHP was found to degrade in sludge under the conditions of good ventilation, sufficient sunlight and proper moisture. The indigenous microorganisms in the sludge appeared to dominate the biodegradation of DEHP in sludge. However about 70% of DEHP remained in sludge after 189 d indicating that DEHP is persistent in the environment.
Hazardous organic matters in municipal sewage sludge in Taiwan
(2001)
Cheng, HF
;
Chen, SY
;
Lin, JG
;
環境工程研究所
;
Institute of Environmental Engineering
Application of municipal sewage sludge to agricultural land has attracted significant attention in recent years because it conserves abundant nutrients and hydrocarbons that can be used as a soil amendment. The presence of hazardous organic matters (HOMs) in sewage sludge limits the feasibility of reuse of sewage sludge. The purpose of this study was to investigate the types and the concentrations of HOMs in municipal sewage sludge in Taiwan. An efficient SFE/GC/MS method was used to determine HOMs in sludge samples. The results indicated that di-(2-ethylhexyl) phthalate (DEHP) was persistently found in both aerobically and anaerobically digested sludges. 4-nonylphenol (4-NP) was only found in anaerobically digested sludges. Both DEHP and 4-NP have been characterized as endocrine disrupting chemicals (EDCs) or environmental endorine disruptors (EEDs). It suggested that sludges containing high levels of DEHP and 4-NP need further treatment and reduction of possible impacts on the environment before their reuse as soil fertilizers.