Browsing by Author "Cheng, Jing-Rong"

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Enhancing device efficiencies of solid-state white light-emitting electrochemical cells by employing waveguide coupling
(2015-01-01)
Cheng, Chia-Yu
;
Wang, Chi-Wei
;
Cheng, Jing-Rong
;
Chen, Hsiao-Fan
;
Yeh, Yun-Shiuan
Solid-state white light-emitting electrochemical cells (LECs) have received intense scientific attention owing to their potential applications in display and lighting. Although device efficiencies of white LECs have been significantly improved in recent years, further improvements are still required for their practical applications. In this work, we demonstrate the enhancement of device efficiencies of white LECs by employing waveguide coupling. Two transparent photoresist (TPR) layers doped with TiO2 nanoparticles (NPs) are inserted between the indium tin oxide (ITO) layer and the glass substrate. By tuning the doping concentration of 25 nm TiO2 NPs in the upper TPR layer to adjust the refractive index, effective waveguide coupling between the ITO layer and the lower TPR layer can be achieved. Since the lower TPR layer contains 250 nm TiO2 NPs, electroluminescence (EL) outcoupled from the ITO layer can be scattered and redirected into the forward direction. Furthermore, the EL trapped in the glass substrate can also transmit into the lower TPR layer and then is scattered to the forward direction. When the EL trapped in the ITO layer and the glass substrate can be effectively recycled into the forward direction, the peak external quantum efficiency and power efficiency obtained in white LECs employing waveguide coupling are up to 19.4% and 34.1 lm W-1, respectively. These efficiencies are among the highest reported for white LECs and thus confirm that waveguide coupling would be useful for realizing highly efficient white LECs. In addition to the enhanced device efficiencies, improved color migration of EL spectra, which is desired for lighting applications, can be obtained in white LECs with scattering waveguide layers since EL of different angles can be mixed in the forward direction.
Solid-state white light-emitting electrochemical cells based on scattering red color conversion layers
(2015-01-01)
Lin, Guan-Rung
;
Cheng, Jing-Rong
;
Wang, Chi-Wei
;
Sarma, Monima
;
Chen, Hsiao-Fan
Solid-state white light-emitting electrochemical cells (LECs) based on ionic transition metal complexes are capable of generating efficient white electroluminescence (EL). Recently, blue-emitting LECs combined with embedded red color conversion layers (CCLs), which were inserted between indium tin oxide (ITO) and a glass substrate, have been reported to offer an external quantum efficiency (EQE) >12%. However, the output spectrum of EL from such white LECs changed with time due to the altered microcavity effect when the recombination zone was moving. Furthermore, the device efficiency should be further improved to realize practical applications. In this work, TiO2 nanoparticles (NPs) of two sizes are incorporated into red CCLs to improve device performance. Large NPs (250 nm) can scatter and redirect the light passing through red CCLs and further enhance the extracted light. Small NPs (25 nm) increase the refractive index of red CCLs and raise the amount of light intensity in the evanescent tail of the waveguide mode near the ITO layer. Therefore, more trapped light in the evanescent tail of the waveguide mode can be recycled to the external mode by scattering. The peak EQE and power efficiency of white LECs employing scattering red CCLs reach 20.0% and 39.5 lm W-1, respectively. Furthermore, with scattering NPs to average the EL in different directions, white EL is almost invariant with time. These results show that blue-emitting LECs combined with scattering red CCLs would be effective to provide efficient and stable white EL.