Browsing by Author "Corce, Vincent"

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Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis
(2019-02-04)
Cartier, Alex
;
Levernier, Etienne
;
Corce, Vincent
;
Fukuyama, Takahide
;
Dhimane, Anne-Lise
Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.