Browsing by Author "Dodda, R"

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Bright red-emitting electrophosphorescent device using osmium complex as a triplet emitter
(2003-07-28)
Kim, JH
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Liu, MS
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Jen, AKY
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Carlson, B
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Dalton, LR
A series of efficient and bright double-layer light-emitting devices have been fabricated using the osmium (Os) complex as the triplet emissive dopant in both a blue-emitting polyfluorene derivative (PF-TPA-OXD) containing hole-transporting triphenylamine (TPA) and electron-transporting oxadiazole (OXD) as side chains and a blend of 2-(4-t-butylphenyl)-5(4-biphenylyl)-1,3,4-oxadizole (PBD) in poly(N-vinylcarbazole) (PVK). Due to a balanced charge injection and transport in PF-TPA-OXD and very efficient energy transfer from this polymer to the Os complex, the resulting device (indium tin oxide/HTL/OsCF3:PF-TPA-OXD/Ca/Ag) reaches a maximum external quantum efficiency of 2.1% with a peak brightness of 2920 cd/m(2). These results are significantly higher than those obtained from the commonly used host, PVK:PBD (0.49% and 1270 cd/m(2)). (C) 2003 American Institute of Physics.
Enhancing the thermal and spectral stabilities of polyfluorene-based bluelight-emitting materials by incorporating pendent spiro-cycloalkyl groups
(2004-05-20)
Wu, FI
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Dodda, R
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Jakka, K
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Huang, JH
;
Hsu, CS
We have synthesized polyfluorene-based copolymers containing spiro-cycloalkyl groups functionalized on the C-9 position of alternate fluorene units using the Suzuki coupling reaction. The presence of the rigid spiro-cycloalkyl pendent groups not only hinders the close packing and intermolecular interactions between polymer chains, but also preserves the molecular rigidity of the polymer, leading to polyfluorenes with high glass transition temperatures and improved thermal and spectral stabilities. The results of photoluminescence measurements of the isothermally heated spiro-polyfluorene thin films (150degreesC for 20h) show that the commonly observed aggregate/excimer formation is suppressed effectively in these polymers. Blue electroluminescence was demonstrated in a double-layer LED device using the spiro-derivatized polyfluorene as the emitting layer. (C) 2004 Elsevier Ltd. All rights reserved.
Fungichromin: A substance from Streptomyces padanus with inhibitory effects on Rhizoctonia solani
(2003-01-01)
Shih, HD
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Liu, YC
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Hsu, FL
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Mulabagal, V
;
Dodda, R
Streptomyces padanus strain PMS-702 is an antagonist of Rhizoctonia solani AG-4, the causal agent of damping-off of cabbage. Treatment of cabbage seeds with the culture filtrate of S. padanus strain PMS-702 was effective in reducing the incidence of damping-off of cabbage. The major active ingredient from the culture filtrate of S. padanus strain PMS-702 was purified by silica gel column chromatography and identified as the polyene macrolide, fungichromin, by NMR and mass spectral data. Bioassay studies showed that fungichromin had a strong antifungal activity against R. solani AG-4, and its minimum inhibitory concentration (over 90% inhibition) was found to be 72 mug/mL. This is the first report of fungichromin from S. padanus as an active ingredient for the control of Rhizoctonia damping-off of cabbage.
Highly efficient blue-light-emitting diodes from polyfluorene containing bipolar pendant groups
(2003-09-09)
Shu, CF
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Dodda, R
;
Wu, FI
;
Liu, MS
;
Jen, AKY
A highly efficient blue-light-emitting copolymer with bulky hole-transporting triphenylamine (TPA) and electron-transporting oxadiazole (OXD) pendant groups at the C-9 position of fluorene was synthesized. The results from photoluminescence and electrochemical measurements reveal that both the side chains and the polyfluorene main chain retain their own electronic characteristics in the copolymer. It shows a pure blue emission with no aggregates or excimers formed even after being annealed at 150 degreesC under nitrogen for 20 h. In addition, it also demonstrates improved charge injection and balanced charge transport in electroluminescence. The maximum external quantum efficiency of a single-layer device using this copolymer as the emitting layer is 1.21% (at a brightness of 354 cd/m(2) with driving voltage of 7.6 V). The maximum luminance of the device reaches 4080 cd/m(2) at a bias of 12.0 V and a current density of 640 mA/cm(2).
Spirobifluorene-linked bisanthracene: An efficient blue emitter with pronounced thermal stability
(2004-03-09)
Shen, WJ
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Dodda, R
;
Wu, CC
;
Wu, FI
;
Liu, TH
Spiro-FPA, a novel blue emitter, in which two identical anthracene luminophores are linked orthogonally around a spirobifluorene core, has been synthesized and characterized. The introduction of a spiro linkage into the structure of spiro-FPA leads to a reduction in crystallization tendency and an increase in glass transition temperature relative to the monomeric units. In addition, the tetrahedral nature of the carbon atom at the spiro center preserves the optical and electrochemical characteristics of the pristine anthracene units. As demonstrated by AFM measurements, high-quality amorphous films of spiro-FPA with good morphological stability can be prepared by vapor deposition. Organic EL devices constructed using a 1.0-wt % TBP-doped spiro-FPA emitting layer produce bright blue emissions with a high luminescence efficiency of 4.9 cd/A (2.07 lm/W).
Synthesis and characterization of spiro-linked poly(terfluorene): a blue-emitting polymer with controlled conjugated length
(2002)
Wu, FI
;
Dodda, R
;
Reddy, DS
;
Shu, CF
;
應用化學系
The synthesis and characterization of a fluorene-spirobifluorene alternating copolymer, P(OF-SBF), are described. In the case of the spiro-segment, the two fluorene rings are orthogonally arranged and connected through a tetrahedral bonding carbon atom ( the spiro center). As a consequence, the polymer chain periodically zigzags, with an angle of 90degrees at each spiro center. This structural feature not only preserves the rigidity of the polymer chain but also prevents the pi-stacking of the polymer backbone, resulting in an improvement in both thermal and spectroscopic stabilities. Comparing the absorption and emission spectra of P(OF-SBF) and of a terfluorene model compound, it was revealed that P(OF-SBF) possesses a well-defined conjugation length. The polymer can serve as a host matrix to effectively transfer its excitation energy to a derivatized perylene dopant, yielding an efficient blue-light-emitting layer.