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Browsing by Author "Gorobets, E"

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    Approaches to tacamonine.
    (2001-04-01)
    Ho, TL
    ;
    Su, CY
    ;
    Gorobets, E
    ;
    應用化學系
    ;
    Department of Applied Chemistry
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    Synthesis of tacamonine
    (2002-06-10)
    Ho, TL
    ;
    Gorobets, E
    ;
    應用化學系
    ;
    Department of Applied Chemistry
    Tacamonine has been synthesized in 3.2% overall yield from cyclohexanone-4-carboxylic acid ethyleneacetal. The tetrahydro-beta-carboline intermediate was submitted to a Mannich reaction to provide a bridged ring system embodying latent branches of the quinolizidine portion. The final stages included fragmentation and Grignard reaction. (C) 2002 Published by Elsevier Science Ltd.