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Browsing by Author "Hsu, Ching-Yun"

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    Synthesis of a Furanosyl-pyranone Derivative Related to the Tri-O-heterocyclic Core of Herbicidins
    (2012-03-01)
    Hsu, Ching-Yun
    ;
    Lee, I-Chi
    ;
    Lico, Larry S.
    ;
    Uang, Biing-Jiun
    ;
    Hung, Shang-Cheng
    A new compound that is structurally related to the undecose ring structure of herbicidins has been prepared. The synthesis of this novel furanosyl-pyranone derivative was made possible through the regioselective reductive ring-opening of a 3,5-O-benzylidene-D-xylofuranose and the hetero-Diels-Alder reaction of an aldehyde and a Danishefsky-type diene. The highly functionalized pyranone derivative can be a useful precursor for the synthesis of herbicidins.