Browsing by Author "Huang, Jen-Shien"

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Dibenzo[f,h]thieno[3,4-b] quinoxaline-fullerene heterojunction bilayer solar cells with complementary spectrum coverage
(2010-10-01)
Kekuda, Dhananjaya
;
Huang, Jen-Shien
;
Velusamy, Marappan
;
Lin, Jiann T.
;
Chu, Chih-Wei
In the present article, potential of a bilayer organic solar cell has been investigated. We utilize newly synthesized small molecules, namely dibenzo[f,h]thieno[3,4-b]quinoxaline as electron donors for solar cells in heterojunction bilayer configuration. These small molecules with a narrow absorption band in the range 400-450 nm provide a complementary spectrum for the fullerene C(70), thereby leading to an overall power conversion efficiency of 2.6 +/- 0.2% under 100 mW/cm(2) incident radiation. Thermal annealing seems to impact the charge separation at the donor-acceptor interface, which eventually affects device performance. This work demonstrates that carefully optimized bilayer devices are comparable to the bulk heterojunction counterparts. (C) 2010 Elsevier B.V. All rights reserved.