Browsing by Author "Jen, JS"

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Formation of mononuclear nitrido complexes of chromium(VI) and molybdenum(VI); Syntheses and X-ray crystal structures of N Cr(OBu(t))(3) and N Mo(OSiMe(3))(3)(py)
(1996-01-21)
Chiu, HT
;
Chen, YP
;
Chuang, SH
;
Jen, JS
;
Lee, GH
Mononuclear nitrido complexes of Cr and Mo, N=Cr(OBu(t))(3) and N=Mo(OSiMe(3))(3)(py), are synthesized; the chromium complex has an idealized C-3v symmetry while the molybdenum complex has a distorted square-pyramidal geometry with the nitrido ligand at apical position; the N-Cr distance is 1.538(5) Angstrom while the average N-Mo distance is 1.627 Angstrom.