Browsing by Author "Landais, Yannick"

Now showing 1 - 1 of 1

Vicinal difunctionalization of alkenes by four-component radical cascade reaction of xanthogenates, alkenes, CO, and sulfonyl oxime ethers
(2019-07-31)
Sumino, Shuhei
;
Fukuyama, Takahide
;
Sasano, Mika
;
Ryu, Ilhyong
;
Jacquet, Antoine
Four-component coupling reactions between xanthogenates, alkenes, CO, and sulfonyl oxime ethers were studied. In the presence of hexabutylditin, working as a propagating radical reagent, the chain reaction proceeds, as expected, taking into account reagents polarities, affording the corresponding functionalized alpha-keto oximes. Although yields are modest, this rare one-pot four-component process is easy to carry out and the resulting compounds, bearing multiple functionalities, have the potential for further elaboration.