Browsing by Author "Liao, Yen-Fa"

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Anti-site defect effect on the electronic structure of a Bi2Te3 topological insulator
(2018-01-01)
Chuang, Pei-Yu
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Su, Shu-Hsuan
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Chong, Cheong-Wei
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Chen, Yi-Fan
;
Chou, Yu-Heng
Tuning the Fermi level (EF) in Bi2Te3 topological-insulator (TI) films is demonstrated on controlling the temperature of growth with molecular-beam epitaxy (MBE). Angle-resolved photoemission spectra (ARPES) reveal that EF of Bi2Te3 thin films shifts systematically with the growth temperature (Tg). The key role that a Bi-on-Te(1) (BiTe1) antisite defect plays in the electronic structure is identified through extended X-ray-absorption fine-structure (EXAFS) spectra at the Bi L-3-edge. Calculations of electronic structure support the results of fitting the EXAFS, indicating that the variation of EF is due to the formation and suppression of BiTe1 that is tunable with the growth temperature. Our findings provide not only insight into the correlation between the defect structure and electronic properties but also a simple route to control the intrinsic topological surface states, which could be useful for applications in TIbased advanced electronic and spintronic devices.
Deviatoric deformation kinetics in high entropy alloy under hydrostatic compression
(2019-07-05)
Huang, E-Wen
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Lin, Chih-Ming
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Juang, Jenh-Yih
;
Chang, Yao-Jen
;
Chang, Yuan-Wei
An equiatomic CoCrFeMnNi high-entropy alloy under hydrostatic compression is investigated using insitu angular-dispersive X-ray diffraction to explore the polymorphism in high entropy alloy systems. The metallic system is of face-centered-cubic structure at ambient condition and applied hydrostatic pressures up to 20 GPa via diamond anvil cell. The angle-resolved diffraction-intensity evolutions of multiple diffraction peaks were collected simultaneously to elucidate the phase stability examinations. The phase transformation from face-centered-cubic to hexagonal-close-packed structure was evidently observed in CoCrFeMnNi alloy accompanied by a deviatoric strain subjected to the hydrostatic compression. We found lattice-asymmetric crossover before and after the phase transformation subjected to hydrostatic compression surroundings. Deviatoric strain triggers fcc-hcp phase transformation as local heterogeneity-driven lattice distortion is significant for CoCrFeMnNi alloy. (c) 2019 The Authors. Published by Elsevier B.V.
Irreversible phase transformation in a CoCrFeMnNi high entropy alloy under hydrostatic compression
(2018-03-01)
Huang, E-Wen
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Lin, Chih-Ming
;
Jain, Jayant
;
Shieh, Sean R.
;
Wang, Ching-Pao
An equal-molar CoCrFeMnNi, face-centered-cubic high-entropy alloy system is investigated using in-situ angular-dispersive X-ray diffraction under hydrostatic compression up to 20 GPa via diamond anvil cell. The evolutions of multiple diffraction peaks are collected simultaneously to elucidate the phase stability field. The results indicated that an irreversible phase transformation had occurred in the high entropy alloy upon decompression to ambient pressure. A reference material (n-type silicon-doped gallium arsenide) was investigated following the same protocol to demonstrate the different deformation mechanisms. It is suggested that the atomic bonding characteristics on the phase stability may play an important role in the high entropy alloys.
Pressure effect on impurity local vibrational mode and phase transitions in n-type iron-doped indium phosphide
(2018-01-19)
Lin, Chih-Ming
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Hsu, I-Jui
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Lin, Sin-Cheng
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Chuang, Yu-Chun
;
Chen, Wei-Ting
The evolution of iron local vibrational mode (Fe LVM) and phase transitions in n-type iron-doped indium phosphide (InP:Fe) were investigated at ambient temperature. In-situ angle-dispersive X-ray diffraction measurements revealed that InP: Fe starts to transform from zinc-blende (ZB) to rock-salt (RS) structure around 8.2(2) GPa and completes around 16.0(2) GPa. The Raman shift of both transverse and longitudinal optical modes increases monotonically with increasing pressure, while their intensities become indiscernible at 11.6(2) GPa, suggesting that the pressure-induced phase transition is accompanied by significant metallization. In contrast, originally absent at ambient pressure, the Raman shift of Fe LVM appears at similar to 420 cm(-1) near 1.2 GPa and exhibits a dome shape behavior with increasing pressure, reaching a maximum value of similar to 440 cm-1 around 5 GPa, with an apparent kink occurring around the ZB-RS transition pressure of similar to 8.5(2) GPa. The Fe K-edge X-ray absorption near edge structure (XANES) confirmed the tetrahedral site occupation of Fe3+ with a crystal field splitting parameter Delta(t)=38k . mole(-1). Our calculations indicate that the energy parameters governing the phase transition are Delta(t)=0.49 and Delta(o) =1.10 kJ . mole(-1),respectively, both are much smaller than Delta(t) = 38 kJ . mole(-1) at ambient.
Pressure-Induced Phase Transitions in InAs Studied by Angular-Dispersive X-ray Diffraction and Raman Spectroscopy
(2015-06-01)
Lin, Chih-Ming
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Lin, Kung-Liang
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Chern, Yu-Ker
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Lin, Yu-Kun
;
Chuang, Yu-Chun
Pressure-induced phase transitions in indium arsenide (In As) at ambient temperature were investigated by using angular-dispersive X-ray diffraction (ADXRD) and Raman scattering under high pressure up to around 9.8(1) and 9.9(2) GPa, respectively, with a 4:1 (in volume ratio) methanol-ethanol mixture as the pressure transmitting medium (PTM). In situ ADXRD measurements revealed that In As starts to transform from zinc blende (ZB) structure to rock-salt (RS) phase at 6.7(1) GPa, consistent with most previously reported studies. The phase transition proceeds steadily over a wide range of pressures and reaches completion at the highest applied pressure of 9.8 GPa with significant metallization, as suggested by the disappearance of Raman modes. In contrast to previous studies, our data did not show evidence of structural transition to Cnncm phase, presumably due to the different PTMs used and/or insufficient pressure applied. The order of appearance of the major diffraction peaks of RS phase In As with increasing pressure and intensity are explained by the binding energy density of the corresponding plane families. The zero-pressure isothermal bulk moduli (B-0) and its first-pressure derivatives (B-0\') for the ZB In As are 64(4) GPa and 3.8(2), respectively. The intensity of both the LO and TO phonon modes of ZB phase In As exhibits an abrupt decrease at 7.7(1) GPa, where equal weight fractions of ZB and RS phases are identified, suggesting the metallic nature of the RS phase.
Pressure-induced structural phase transition in bulk Zn0.98Mn0.02O by angular dispersive X-ray diffraction
(2014-08-15)
Lin, Chih-Ming
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Lin, Kung-Liang
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Chern, Yu-Ker
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Hsu, Chia-Hung
;
Sheu, Hwo-Shuenn
The high pressure induced phase transition in bulk Zn0.98Mn0.02O at ambient temperature have been investigated using angular-dispersive X-ray diffraction (ADXRD) under high pressure up to around 13.80 GPa. For loading run, in situ ADXRD measurements found that a wurtzite-to-rocksalt structural phase transition pressure of bulk Zn0.98Mn0.02O began at 7.35 GPa. The fitting of volume compression data to the third-order Birch-Murnaghan equation of state yielded that the zero-pressure isothermal bulk moduli and the first-pressure derivatives were 157(8) GPa and 8(3) for the B4 phase, respectively. When decompress bulk Zn0.98Mn0.02O to ambient pressure a large part of the bulk Zn0.98Mn0.02O reverted to the B4 phase and only a small amount of the metastable B1 phase remained. We have exhibits the pressure dependence of lattice constant a and c axis, and the normalized ratio c/a of the bulk Zn0.98Mn0.02O. Possible pressure-induced phase transition mechanisms were explored by examining the cell parameters and the internal structural parameter (u) with pressures. The effect of the 3d electrons of manganese to increase the nearest-neighbor distance of O to Zn (Mn) parallel to the c axis may be the main reason for the phase transition of bulk Zn0.98Mn0.02O. An increase in the u value with pressure indicates that the B4-to-B1 phase transformation in bulk Zn0.98Mn0.02O is likely via the hexagonal path. (C) 2014 Elsevier B.V. All rights reserved.
Structural properties of pressure-induced structural phase transition of Si-doped GaAs by angular-dispersive X-ray diffraction
(2016-02)
Lin, Kung-Liang
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Lin, Chih-Ming
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Lin, Yu-Sheng
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Jian, Sheng-Rui
;
Liao, Yen-Fa
Pressure-induced phase transitions in n-type silicon-doped gallium arsenide (GaAs: Si) at ambient temperature were investigated by using angular-dispersive X-ray diffraction (ADXRD) under high pressure up to around 18.6 (1) GPa, with a 4:1 (in volume ratio) methanol-ethanol mixture as the pressure-transmitting medium. In situ ADXRD measurements revealed that n-type GaAs: Si starts to transform from zinc-blende structure to an orthorhombic structure [GaAs-II phase], space group Pmm2, at 16.4 (1) GPa. In contrast to previous studies of pure GaAs under pressure, our results show no evidence of structural transition to Fmmm or Cmcm phase. The fitting of volume compression data to the third-order Birch-Murnaghan equation of state yielded that the zero-pressure isothermal bulk moduli and the first-pressure derivatives were 75 (3) GPa and 6.4 (9) for the B3 phase, respectively. After decompressing to the ambient pressure, the GaAs: Si appears to revert to the B3 phase completely. By fitting to the empirical relations, the Knoop microhardness numbers are between H-PK = 6.21 and H-A = 5.85, respectively, which are substantially smaller than the values of 7-7.5 for pure GaAs reported previously. A discontinuous drop in the pressure-dependent lattice parameter, N-N distances, and V/V-0 was observed at a pressure of 11.5 (1) GPa, which was tentatively attributed to the pressure-induced dislocation activities in the crystal grown by vertical gradient freeze method.
Structural Transitions in Nanosized Zn0.97Al0.030 Powders under High Pressure Analyzed by in Situ Angle-Dispersive X-ray Diffraction
(2016-07-01)
Lin, Chih-Ming
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Liu, Hsin-Tzu
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Zhong, Shi-Yao
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Hsu, Chia-Hung
;
Chiu, Yi-Te
Nanosized aluminum-doped zinc oxide Zn1-xAlxO (AZO) powders (AZO-NPs) with x = 0.01, 0.03, 0.06, 0.09 and 0.11 were synthesized by chemical precipitation method. The thermogravimetric analysis (TGA) indicated that the precursors were converted to oxides from hydroxides near 250 degrees C, which were then heated to 500 degrees C for subsequent thermal processes to obtain preliminary powders. The obtained preliminary powders were then calcined at 500 degrees C for three hours. The structure and morphology of the products were measured and characterized by angle -dispersive X-ray diffraction (ADXRD) and scanning electron microscopy (SEM). ADXRD results showed that AZO-NPs with Al content less than 11% exhibited wurtzite zinc oxide structure and there was no other impurity phase in the AZO-NPs, suggesting substitutional doping of Al on Zn sites. The Zn0.97Al0.030 powders (A3ZO-NPs) with grain size of about 21.4 nm were used for high-pressure measurements. The in situ ADXRD measurements revealed that, for loading run, the pressure-induced wurtzite (B4)-to-rocksalt (B1) structural phase transition began at 9.0(1) GPa. Compared to the predicted phase-transition pressure of 12.7 GPa for pristine ZnO nanocrystals of similar grain size (similar to 21.4 nm), the transition pressure for the present A(3)ZO-NPs exhibited a reduction of 3.7 GPa. The significant reduction in phase -transition pressure is attributed to the effects of highly selective site occupation, namely Zn2+ and Al3+, were mainly found in tetrahedral and octahedral sites, respectively.
Valence- and element-dependent water oxidation behaviors: in situ X-ray diffraction, absorption and electrochemical impedance spectroscopies
(2017-04-07)
Hsu, Chia-Shuo
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Suen, Nian-Tzu
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Hsu, Ying-Ya
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Lin, Hsuan-Yu
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Tung, Ching-Wei
Metal oxides of the spinel family have shown great potential towards the oxygen evolution reaction (OER), but the fundamental OER mechanism of spinel oxides is still far from being completely understood, especially for the role of the metal ions. Owing to various coordinated sites of divalent/trivalent metals ions and surface conditions (morphology and defects), it is a great challenge to have a fair assessment of the electrocatalytic performance of spinel systems. Herein, we demonstrated a series of MFe2O4 (M = Fe, Co, Ni, Zn) with a well-controlled morphology to achieve a comprehensive study of electrocatalytic activity toward OER. By utilizing several in situ analyses, we could conclude a universal rule that the activities for OER in the metal oxide systems were determined by the occurrence of a phase transformation, and this structural transformation could work well in both crystallographic sites (Td and Oh sites). Additionally, the divalent metal ion significantly dominated the formation of oxyhydroxide through an epitaxial relationship, which depended on the atomic arrangement at the interface of spinel and metal oxyhydroxide, while trivalent metal ions remained unchanged as a host lattice. The metal oxyhydroxide was formed during a redox reaction rather than being formed during OER. The occurrence of the redox reaction seems to accompany a remarkable increase in resistance and capacitance might result from the structural transformation from spinel to metal oxyhydroxide. We believe that the approaching strategies and information obtained in the present study can offer a guide to designing a promising electrocatalytic system towards the oxygen evolution reaction and other fields.