Browsing by Author "Lin, Heh-Nan"

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An indoor light-activated 3D cone-shaped MoS2 bilayer-based NO gas sensor with PPb-level detection at room-temperature
(2019-06-07)
Chen, Yu-Ze
;
Wang, Sheng-Wen
;
Yang, Chun-Chuan
;
Chung, Chieh-Han
;
Wang, Yi-Chung
Utilization of light to boost the performance of gas sensors allows us to operate sensor devices at room temperature. Here, we, for the first time, demonstrated an indoor light-activated 3D cone-shaped MoS2 bilayer-based NO gas sensor with ppb-level detection operated at room-temperature. Large-area coneshaped (CS)-MoS2 bilayers were grown by depositing 2 nm-thick MoO3 layers on a 2'' three-dimensional (3D) cone-patterned sapphire substrate (CPSS) followed by a sulfurization process via chemical vapor deposition. Because the exposed area of MoS2 bilayers is increased by 30%, the CS-MoS2 gas sensor (GS) demonstrated excellent performance with a response of 470% and a fast response time of 25 s after exposure to 1 ppm of NO gas illuminated by ultraviolet (UV) light with a wavelength of 365 nm. Such extraordinary performance at room temperature is attributed to the enhanced light absorption because of the light scattering effect caused by the 3D configuration and photo-desorption induced by UV illumination. For NO concentrations ranging from 2 ppm down to 0.06 ppm, the CS-MoS2 GS demonstrated a stable sensing behavior with a high response and fast response time (470% and 25 s at 2 ppm NO) because of the light absorption enhanced by the 3D structure and photo-desorption under constant UV illumination. The CS-MoS2 GS exhibits a high sensitivity (189.2 R% ppm-1), allowing the detection of NO gas at 0.06 ppm in 130 s. In addition, the 3D cone-shaped structure prolonged the presence of sulfur vapor around MoO3, allowing MoO3 to react with sulfur completely. Furthermore, the CS-MoS2 GS using an indoor lighting to detect NO gas at room temperature was demonstrated for the first time where the CS-MoS2 GS exhibits a stable cycling behavior with a high response (165% at 1 ppm NO) in 50 s; for concentration as low as 0.06 ppm, the response of 75% in 150 s can be achieved.
Electron Field Emission Properties of Nanomaterials on Rough Silicon Rods
(2010-01-14)
Wu, Hung-Chi
;
Tsai, Tsung-Yen
;
Chu, Fu-Hsuan
;
Tai, Nyan-Hwa
;
Lin, Heh-Nan
Highly porous, individually separated, and vertically aligned rough silicon rods (r-SiRs) were formed via a modified electroless metal deposition (EMD) approach. Despite inheriting the length of crowded silicon nanowires (NWs) obtained by the conventionally adopted EMD method, the r-SiRs are distributed sparsely, subsequently forming an excellent field emitter substrate. The electron field emission (EFE) of carbon nanotubes (CNTs) grown on r-SiRs can be turned on at (E(0))(CNTs/r-SiRs) = 2.3 V/mu m, yielding a high EFE current density, (J(c))(CNTs/r-SiR) = 3.7 mA/cm(2) in an applied field of 5.1 V/mu m, Additionally, a cactuslike structure consisting of zinc oxide NWs on r-SiRs can be turned on at 2.9 V/mu m. The absence of a high-temperature or expensive photolithographic process makes r-SiRs a promising alternative as a silicon base field emitter substrate.
Near-Field Optical Imaging of a Porous Au Film: Influences of Topographic Artifacts and Surface Plasmons
(2013-06-01)
Lin, Yu-Hsuan
;
Haendel, Benjamin
;
Huang, Hung Ji
;
Chen, Hsiang-An
;
Chen, Yung-Fu
In this work, near-field scanning optical microscopy is employed to study a porous Au film and the direct observation of topographic artifacts and surface plasmon influences is revealed. Under tip illumination, topographic artifacts are found to be present in a reflection mode optical image but not in a transmission mode image. A simple algorithm is used for filtering the topographic artifacts and extracting a correct near-field optical image approximately. On the other hand, surface plasmon influences are present in both modes. By using three exciting wavelengths of 488, 647.1, and 520.8 nm, it is confirmed that a suitable wavelength should be chosen for avoiding the surface plasmon interference in a near-field optical investigation of morphological or material dielectric contrast. Finally, plasmonic or nonplasmonic regions on the porous Au film can be identified from the observed optical intensity variation in the optical images obtained at incident polarizations of 0 degrees, 90 degrees, and 45 degrees.
Sodium niobate nanowire and its piezoelectricity
(2008-06-19)
Ke, Tsung-Ying
;
Chen, Hsiang-An
;
Sheu, Hwo-Shuenn
;
Yeh, Jien-Wei
;
Lin, Heh-Nan
Nanowires of crystalline orthorhombic sodium niobate (NaNbO3) with diameters of approximately 100 nm and lengths of several to hundreds of microns, as well as cubes with edges of lengths of hundreds of nanometers were obtained by reacting niobium oxide (Nb2O5) with 10 and 12.5 M NaOH solutions, respectively. The microstructures of the synthesized wiry and cubic piezoelectric materials were investigated, and the details of the reactions were elucidated as well. The piezoelectricity of individual NaNbO3 (Pbma) nanowires was confirmed by piezoresponse force microscopy, and an effective piezoelectric coefficient along the vertical direction of around a few pm/V was obtained. To our knowledge, the present work is the first report of the preparation of NaNbO3 nanowires as well as the determination of piezoelectricity.