Browsing by Author "Lin, Jui-Nien"

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High-Rate Hydrogen Generation by Direct Sunlight Irradiation with a Triruthenium Complex
(2019-02-04)
Wu, Tung-Kung
;
Chen, Yi-Ting
;
Peng, Chun-Sheng
;
Lin, Jia-Hoa
;
Gliniak, Jacek
Herein we report a biomimetic triruthenium catalyst that, when under direct sunlight irradiation, facilitates high-rate H-2 production from formic acid (FA) dehydrogenation. The system consists of 2 mu mol of catalyst and 6 mu mol of tri-o-tolylphosphine in 1 mL of dimethylformamide (DMF) and 4 mL of FA/triethylamine (TEA; 5:2). With 0.4 mM catalyst loaded, a high turnover frequency of 1.15 X 10(6) h(-1) was detected when under direct sunlight irradiation. In an experiment with 0.2 mM catalyst loaded, more than 140 L of H-2 (280 L of H-2 + CO2) was produced, and a turnover number of approximately 2.78 X 10(6) was obtained within 5 h without decline in H-2 generation activity, making it suitable for high-rate H-2 production.
Sulfur-Doped Graphene Oxide Quantum Dots as Photocatalysts for Hydrogen Generation in the Aqueous Phase
(2017-08-24)
Gliniak, Jacek
;
Lin, Jia-Hoa
;
Chen, Yi-Ting
;
Li, Chuen-Ru
;
Jokar, Efat
Sulfur-doped graphene oxide quantum dots (S-GOQDs) were synthesized and investigated for efficient photocatalytic hydrogen generation application. The UV/Vis, FTIR, and photoluminescence spectra of the synthesized S-GOQDs exhibit three absorption bands at 333, 395, and 524 nm, characteristic of C=S and C=S stretching vibration signals at 1075 and 690 cm(-1), and two excitation-wavelength-independent emission signals with maxima at 451 and 520 nm, respectively, confirming the successful doping of S atom into the GOQDs. Electronic structural analysis suggested that the S-GOQDs exhibit conduction band minimum (CBM) and valence band maximum (VBM) levels suitable for water splitting. Under direct sunlight irradiation, an initial rate of 18166 mu molh(-1) g(-1) in pure water and 30519 mu molh(-1) g(-1) in 80% ethanol aqueous solution were obtained. Therefore, metal-free and inexpensive S-GOQDs hold great potential in the development of sustainable and environmentally friendly photocatalysts for efficient hydrogen generation from water splitting.