Browsing by Author "Lin, Rongrong"

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Intercepting the Nazarov Oxyallyl Intermediate with -Formylvinyl Anion Equivalents to Access Formal Morita-Baylis-Hillman Alkylation Products
(2017-07-01)
Wu, Yen-Ku
;
Lin, Rongrong
;
West, F. G.
;
應用化學系
;
Department of Applied Chemistry
A Lewis acid catalyzed cationic domino reaction involving sequential electrocyclization and polar addition of allenol ethers onto the resulting oxyallyl species is described. The overall sequence allows a highly stereoselective synthesis of densely substituted cyclopentanoid compounds containing -formylvinyl functionality which is formally equivalent to products of a Morita-Baylis-Hillman alkylation process.