Browsing by Author "Liu, D. G."
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Item type:Item, Effect of Mn impurities on the superconductivity in NaxCoO2 center dot yH(2)O(2007-09-01) ;Chen, Y.-J. ;Liu, C.-J. ;Wang, J.-S. ;Lin, J.-Y.Sun, C. P.To shed light on the symmetry of the superconducting order parameter in NaxCoO2 center dot yH(2)O, the Mn doping effects are studied. X-ray absorption spectroscopy verifies that the doped Mn impurities occupy the Co sites and are with a valance close to +4. Impurity scattering by Mn is in the unitary limit that, however, does not lead to strong T-c suppression. This absence of the strong impurity effects on T-c is inconsistent with the simple picture of a sign-changing order parameter. Coexistence of the s-wave superconducting order parameter and the nodal one is proposed to reconcile all the existing experiments and has been implied by the specific heat experiments.