Browsing by Author "Lu, Hui-Hsin"

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Electrical properties of single and multiple poly(3,4-ethylenedioxythiophene) nanowires for sensing nitric oxide gas
(2009-04-27)
Lu, Hui-Hsin
;
Lin, Chia-Yu
;
Hsiao, Tzu-Chien
;
Fang, Yueh-Yuan
;
Ho, Kuo-Chuan
The electrical properties of conducting polymer, poly(3,4-ethylenedioxythiophene) (PEDOT), nanowires were studied to develop nitric oxide (NO) gas sensors with low working temperatures. A nanowire with a diameter of 300 nm was fabricated using dip-pen nanolithography (DPN) across a 55 mu m gap between a pair of electrodes. The electrical properties of single or multiple PEDOT nanowires were examined by plotting the current-voltage (I-V) curves in the range -3 V to +3 V at temperatures between 298 K and 393 K. The conductance of parallel wires was normalized with respect to the dimensions of the fabricated nanowires. The single nanowire exhibited nonlinear conductance associated with hysteresis but multiple wires did not. The currents increased with the temperature and the I-V characteristics were consistent with the power lawG(T)alpha T(alpha) with alpha similar to 5.14 and 5.43. The responses to NO were highly linear and reproducible, indicating that sensing using PEDOT nanowires was reliable with a minimal concentration of NO of 10 ppm. (c) 2009 Elsevier B.V. All rights reserved.
Fabrication of silicon dioxide nano array for bio-mimicking of molecular interactions
(2008-01-01)
Lu, Hui-Hsin
;
Lin, Chii-Wann
;
Hsiao, Tzu-Chien
;
Lee, Chih-Kung
;
Hsu, Su-Ming
We employed atomic force microscopy (AFM) with bias control to fabricate oxided nanopatterns on silicon surface with feature size down to 50nm. The relationship of silicon dioxide nanopattems against humidity was studied and then the optimal parameter was used to make oxide nanoarry for interaction of biotin and streptavidin. The scanning function of AFM was utilized to verify the different height of biomolecules. According to our experimental results, using nano biochip of silicon dioxide can decrease the monitoring scale to nanometer and can be the nano-platform for monitoring the behavior of biomolecular interaction. We anticipate mimicking the correlation of single molecular behavior and an array of biomolecular behavior to understand the coincidence of them.
Nanopatterning on Silicon Wafers Using AFM-Based Lithography-for Solar Cells
(2009-03-01)
Lu, Hui-Hsin
;
Lin, Chii-Wann
;
Hsiao, Tzu-Chien
;
Lee, Chih-Kung
;
Hsu, Su-Ming
In this report, the nanopatterning method based on atomic force microscopy (AFM) with electrical bias to form the oxide patterns on silicon wafer is described. Under constant bias, 30 V, the linear pattern size is proportional to the rising humidity in the working environment. According to our experimental results, the sizes of the most circular nanopatterns are in the range from 50 nm to 70 nm depending on the applied bias and interaction time. In the results of evaluating the generation of oxidative production, the diameters and the number of oxide two dimensional nanopattern array, defaulted to 25 dots in 1 mu m(2), appeared in the AFM images have increasing tendency with the larger bias and the longer dwell time. Moreover, the imaging features of nanopatterns caused by bias 30 V have better performance than those by 10 V, and the dwell time only takes 0.015 s per dot.
Optical Characterization of a 1-D Nanostructure by Dark-Field Microscopy and Surface Plasmon Resonance to Determine Biomolecular Interactions
(2010-03-01)
Lu, Hui-Hsin
;
Hsiao, Tzu-Chien
;
Hsu, Su-Ming
;
Lin, Chii-Wann
;
分子醫學與生物工程研究所
This paper presents a multifunctional imaging system that combines dark-field microscopy (DFM) with spectroscopy to image nanostructures and identify their optical properties from absorption spectra. The optical resolving power of this system is determined using a 1-D nanostructure with pitches of 120, 390, and 770 nm with four formats of optical disks. These pattern sizes are verified by atomic force microscopy (AFM) first. The results demonstrate that the resolving power of current system setup can down to 86 nm. The resultant DFM images appear to be slightly larger than the AFM images. A 50-nm-thick gold film was then deposited on top of these nanostructures, and their absorption spectra were obtained to elucidate its optical properties, enhanced by surface plasmon resonance. The immobilization of streptavidin on the surface of gold-coated nanostructure causes the absorption spectra to shift from 600 to 610 nm. A protein nanoarray with a dot size of 50 nm was also imaged by DFM, and can be implemented as a potential biochemical diagnostic system on an optical disk format. Specimens of adenocarcinoma cells and ovary cancer cells were also imaged using this DFM system, and the nuclei structure and some cellular organs can be recognized using a 100 objective oil lens.