Browsing by Author "Miyoshi, Hayato"

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Electron transfer-induced reduction of organic halides with amines
(2018-06-04)
Fukuyama, Takahide
;
Fujita, Yuki
;
Miyoshi, Hayato
;
Ryu, Ilhyong
;
Kao, Shih-Chieh
Reduction of a variety of organo halides was examined by using amines as a sacrificial hydrogen source. UV light-induced reduction of vinyl and aryl halides with triethylamine proceeded smoothly to give the corresponding reduced products. High temperature heating also caused the reduction and DABCO (1,4-diazabicyclo[2.2.2]octane) also served as a good reducing reagent.