Browsing by Author "Ostrikov, Kostya (Ken)"

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Interface control of surface photochemical reactivity in ultrathin epitaxial ferroelectric films
(2013-05-06)
Chen, Jason
;
Lu, Haidong
;
Liu, Heng-Jui
;
Chu, Ying-Hao
;
Dunn, Steve
Asymmetrical electrical boundary conditions in (001)-oriented Pb(Zr0.2TiO0.8)O-3 (PZT) epitaxial ultrathin ferroelectric films are exploited to control surface photochemical reactivity determined by the sign of the surface polarization charge. It is shown that the preferential orientation of polarization in the as-grown PZT layer can be manipulated by choosing an appropriate type of bottom electrode material. PZT films deposited on the SrRuO3 electrodes exhibit preferential upward polarization (C+) whilst the same films grown on the (La, Sr)CoO3-electrodes are polarized downward (C-). Photochemical activity of the PZT surfaces with different surface polarization charges has been tested by studying deposition of silver nanoparticles from AgNO3 solution under UV irradiation. PZT surfaces with preferential C+ orientation possess a more active surface for metal reduction than their C- counterparts, evidenced by large differences in the concentration of deposited silver nanoparticles. This effect is attributed to band bending at the bottom interface which varies depending on the difference in work functions of PZT and electrode materials. (C) 2013 AIP Publishing LLC.
Plasma-made silicon nanograss and related nanostructures
(2011-05-04)
Shieh, Jiann
;
Ravipati, Srikanth
;
Ko, Fu-Hsiang
;
Ostrikov, Kostya (Ken)
;
材料科學與工程學系
Plasma-made nanostructures show outstanding potential for applications in nanotechnology. This paper provides a concise overview on the progress of plasma-based synthesis and applications of silicon nanograss and related nanostructures. The materials described here include black silicon, Si nanotips produced using a self-masking technique as well as self-organized silicon nanocones and nanograss. The distinctive features of the Si nanograss, two-tier hierarchical and tilted nanograss structures are discussed. Specific applications based on the unique features of the silicon nanograss are also presented.