Browsing by Author "Oxley, M. P."
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Item type:Item, Suppression of Octahedral Tilts and Associated Changes in Electronic Properties at Epitaxial Oxide Heterostructure Interfaces(2010-08-19) ;Borisevich, A. Y. ;Chang, H. J. ;Huijben, M. ;Oxley, M. P.Okamoto, S.Epitaxial oxide interfaces with broken translational symmetry have emerged as a central paradigm behind the novel behaviors of oxide superlattices. Here, we use scanning transmission electron microscopy to demonstrate a direct, quantitative unit-cell-by-unit-cell mapping of lattice parameters and oxygen octahedral rotations across the BiFeO(3)-La(0.7)Sr(0.3)MnO(3) interface to elucidate how the change of crystal symmetry is accommodated. Combined with low-loss electron energy loss spectroscopy imaging, we demonstrate a mesoscopic antiferrodistortive phase transition near the interface in BiFeO(3) and elucidate associated changes in electronic properties in a thin layer directly adjacent to the interface.