Browsing by Author "Ruamps, Mirko"

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Ni and Pd N-confused porphyrin complexes as catalysts for the synthesis of cyclic carbonates from epoxides and CO2
(2019-06-14)
dela Cruz, Jay-ar B.
;
Ruamps, Mirko
;
Arco, Susan
;
Hung, Chen-Hsiung
;
應用化學系
We have demonstrated the design of a novel bifunctional catalyst that is based on an N-confused tetraphenylporphyrin (NCTPP) motif for the cycloaddition of an epoxide to carbon dioxide via cooperative activation of the epoxide through a Pd(II) or Ni(II) metal center and a peripheral benzoate moiety with percent conversions of up to 99% and TON = 7000.