Browsing by Author "Shiao, SJ"

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Chemical modification of dicyclopentadiene-based epoxy resins to improve compatibility and thermal properties
(2001)
Hsiue, GH
;
Wei, HF
;
Shiao, SJ
;
Kuo, WJ
;
Sha, YA
A. series of siloxane-containing epoxy resins was obtained by curing dicyclopentadiene-containing epoxy DG with the silicon-containing curing agents TS, DS, and AS. Curing behavior was studied using DSC, and the activation energies of the DG curing reaction with curing agents TA, DS, and AS were found to be 59, 80, and 157 KJ/mol. Meanwhile, the curing reaction of DG with diamines was found to be a first-order reaction using Arrhenius plots. In addition, thermal stability and the weight loss behavior of the cured polymers were studied via TGA. The silicon-containing resins displayed higher weight loss temperatures and higher char yields than the silicon-free resin. The activation energies of degradation ranged from 108 to 206 KJ/mol. The morphology of the cured pieces were investigated using SEM. The DG/TS and DG/DS are more compatible between the epoxy and the curing agents than DG/AS. The limited oxygen index (LOI) values of 31 to 34 for the DG-based resin confirmed the effectiveness of silicon-containing epoxy resins as flame retardants. (C) 2001 Elsevier Science Ltd. All rights reserved.
Dry self-lubricating composites
(1996)
Shiao, SJ
;
Wang, TZ
;
交大名義發表
;
應用化學系
;
National Chiao Tung University
Chopped strand carbon fibers, glass fibers and their hybrids were used to reinforce an epoxy matrix to which additives of PTFE, graphite and molybdenum disulfide were used for producing a dry self-lubricating material. Their tribology properties were studied using testing machines of thrust and journal radial. Also, the PV value, friction coefficient, wear rate and the contact surface temperatures were determined. The compression strength of the bush ring and the impact strength of material were evaluated. The surfaces of wear were investigated. The mode of fracture mechanism is proposed according to the specimens morphology. The relationship between friction coefficient and loading correlated well with the Myoshis equation in the case of a backing material. This study provided an optimal approach of making dry wear bearings by glass fibers backing at low friction coefficient. Copyright (C) 1996 Elsevier Science Limited
Novel phosphorus-containing dicyclopentadiene-modified phenolic resins for flame-retardancy applications
(2001-01-10)
Hsiue, GH
;
Shiao, SJ
;
Wei, HF
;
Kuo, WJ
;
Sha, YA
2- [4-(2-hydroxyphenyl)tricyclo[5.2.1.0(2,6)]dec-8-yl]phenol (HPTCDP) were prepared from dicyclopentadiene (DCPD) and phenol via Friedel-Crafts alkylation. DCPD-containing phenolic resin (DPR) was also synthesized by incorporating the DCPD-containing monomer HPTCDP with formaldehyde. DPR was further modified by grafting the phosphate group. The phosphorylation was confirmed by a Fourier transform infrared, P-31-NMR spectroscopy, and an element analysis. The phosphorus content in the DPR could be successfully tailored to give values of 3.46 to 7.79 wt % by varying the feeding ratios of the phosphorus group. The thermal stabilities of the phosphorus-containing polymers were identified by differential scanning calorimeter and thermogravimetric analysis. The glass transition temperature values were decreased as the content of phosphorus increased. High char yield 39-47 wt % in thermogravimetric analysis evaluation and limiting oxygen index values of 27 to 34 were found for all the phosphorylated phenolic resins. Such properties make these polymers highly promising for flame-retardant applications. (C) 2000 John Wiley & Sons, Inc.
Polymer-based self-lubricating material
(2001-05-31)
Shiao, SJ
;
Fu, WS
;
Tuo, CL
;
Cheng, UI
;
應用化學系
A low-friction coefficient material with color based on proper selection of polar conditions of pigment and liquid lubricant was developed. Bush-type bearings were made from poly oxymethylene reinforced with inorganic fillers, including polar compounds of white carbon and glass powder, and nonpolar compounds of carbon black and graphite. The fillers were coated with different levels of titanate, and with polar lubricants such as cetyl alcohol and palmitic acid, and nonpolar lubricants of motor oil, and paraffin. The frictional properties at constant velocity and at constant loading, and the relationships between materials polarity are discussed. An excellent self-lubricating material of frictional coefficient less than 0.02 was obtained. That is superior to the most current commercial products claiming mu = 0.05 similar to 0.06. (C) 2001 John Wiley & Sons, Inc.