Browsing by Author "Su, C. H."

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Development of a heat-generable mold insert and its application to the injection molding of microstructures
(2014-04-01)
Liou, A. C.
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Chen, R. H.
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Huang, C. K.
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Su, C. H.
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Tsai, P. Y.
This work presents a heat-generable mold insert for micro injection molding that solves the problem of de-molding destruction. This mold insert is constructed from silicon wafer by silicon micro-fabrication. Micro electrical heating lines were formed in the wall of the micro mold cavity to control the temperature distribution and the sequence of local solidification of the filled plastic during injection molding. This design reduces the shrinking stress of the plastic filled in the mold. The micro electrical heating lines embedded in the cavity wall are silicon-based with specified resistance, and were fabricated by doping phosphorus ions precisely into the surface of the silicon cavity wall. Ion-implantation was adopted to dope phosphorus ions. The performance of the novel mold insert was studied. Then, the developed mold insert was applied for the injection molding of micro-structures with high aspect ratios. Experimental results reveal that electrical heating lines formed within the novel mold insert can supply stable heating power. These electrical heating lines are used to heat the cavity wall of the silicon mold insert and the nearby plastic with appropriate timing at sufficient power in the cooling stage, such that the de-molding force associated with contraction of the patterned plastic grips to the micro-structured mold insert, is reduced. Furthermore the de-molding destruction of the injection molded micro-structures can be eliminated. Optical micro-structures with aspect ratios of up to eight were successfully injection-molded. (C) 2013 Elsevier B.V. All rights reserved.
Doping dependence of the ultrafast electronic dynamics of Y(1-x)Pr(x)Ba(2)Cu(3)O(7-delta) thin-film superconductors from femtosecond optical spectroscopy
(2010-09-17)
Luo, C. W.
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Lo, H. P.
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Su, C. H.
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Wu, I. H.
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Chen, Y. -J.
Time-domain spectroscopy, which probes the dynamics of the electronic states near Fermi surface that are associated with superconductivity, has proven to be a powerful method for providing insights into the fundamental nature of both pseudogap and superconducting gap. This study shows that the unique T-x phase diagram with the time-evolving ultrafast dynamics of Y(1-x)Pr(x)Ba(2)Cu(3)O(7-delta) can be used to identify clearly the Nernst, pseudogap, and superconducting regions. All of the orders appear together at a specific delay time, such as 1.2-3 ps, after pumping by an ultrashort pulse. These discoveries suggest that the Nernst effect, the pseudogap and even superconductivity may have the same physical origin.
Doping dependence of the ultrafast electronic dynamics of Y1-xPrxBa2Cu3O7-delta thin-film superconductors from femtosecond optical spectroscopy
(2010-09-17)
Luo, C. W.
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Lo, H. P.
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Su, C. H.
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Wu, I. H.
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Chen, Y. -J.
Time-domain spectroscopy, which probes the dynamics of the electronic states near Fermi surface that are associated with superconductivity, has proven to be a powerful method for providing insights into the fundamental nature of both pseudogap and superconducting gap. This study shows that the unique T-x phase diagram with the time-evolving ultrafast dynamics of Y1-xPrxBa2Cu3O7-delta can be used to identify clearly the Nernst, pseudogap, and superconducting regions. All of the orders appear together at a specific delay time, such as 1.2-3 ps, after pumping by an ultrashort pulse. These discoveries suggest that the Nernst effect, the pseudogap and even superconductivity may have the same physical origin.
Ordered YBCO sub-micron array structures induced by pulsed femtosecond laser irradiation
(2008-12-08)
Luo, C. W.
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Lee, C. C.
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Li, C. H.
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Shih, H. C.
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Chen, Y. -J.
We report on the formation of organized sub-micron YBa(2)Cu(3)O(7) (YBCO) dots induced by irradiating femtosecond laser pulses on YBCO films prepared by pulse laser deposition with fluence in the range of 0.21 similar to 0.53 J/cm(2). The morphology of the YBCO film surface depends strongly on the laser fluences irradiated. At lower laser fluence (similar to 0.21 J/cm(2)) the morphology was pattern of periodic ripples with sub-micrometer spacing. Slightly increasing the laser fluence to 0.26 J/cm(2) changes the pattern into organized sub-micron dots with diameters ranging from 100 nm to 800 nm and height of 150 nm. Further increase of the laser fluence to over 0.32 J/cm(2), however, appeared to result in massive melting and led to irregular morphology. The mechanism and the implications of the current findings will be discussed. Arrays of YBCO sub-micron dots with T(c) = 89.7 K were obtained. (C) 2008 Optical Society of America
Thermodynamic Characterization of Polymorphs in Bulk-Crystallized Syndiotactic Polystyrene via Small/Wide-Angle X-ray Scattering and Differential Scanning Calorimetry
(2009-06-23)
Su, C. H.
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Jeng, U.
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Chen, S. H.
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Cheng, C. -Y.
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Lee, J. -J.
By means of in situ small/wide-angle X-ray scattering (SAXS/WAXS) and differential scanning calorimetry (DSC), we examined evolutions of lamellar crystal thickness for alpha and beta crystals, respectively, in bulk-crystallized syndiotactic polystyrene (sPS) during the partial melting-reorganization process upon progressive heating up to 290 degrees C. For the SAXS data analysis, the Kratky-Porod approximation proves to be particularly helpful in extracting the crystal thickness when approaching final melting where crystalline lamellae (near equilibration with the melt) exist in low concentrations as dispersed entities instead of in arrays. On the basis of the crystal thicknesses at elevated temperatures under solid-melt equilibration, we constructed melting lines of the two separate forms in the Gibbs-Thomson phase plane. The extrapolated (to infinite lamellar thickness) equilibrium melting temperature T(m,alpha)* approximate to 294 degrees C of the a form is moderately lower than T(m,beta)* approximate to 306 degrees C of the beta form. The two melting lines intercept at a crossover temperature T(Q) approximate to 284 degrees C and crystal thickness l(Q) approximate to 9.6 nm, where the relative thermal stability of the two phases inverses. For crystals thicker than l(Q) (practically hard to reach for bulk crystallization under ambient pressure), the beta form is the stable phase; for crystals thinner than I(Q) (the commonly accessible case), the a form is circumstantially more stable. With crystallinity-corrected values of the heat of fusion Delta H(f,alpha) approximate to 82 MJ m(-3) and Delta H(f,beta) approximate to 146 MJ m(-3) obtained from a combination of DSC and WAXS results, we determined from the slope (= 2 sigma(e)/Delta H(f)) of the melting line that basal surface energy sigma(e,alpha) approximate to 8.2 mJ m(-2) and sigma(e,beta) approximate to 26.8 mJ m(-2) which are considerably lower than those expected for tight folds, indicative of nonadjacently re-entered or loosely looped folds. The combination of lower T(m)*, Delta H(f), Delta S(f), and sigma(e) values renders the a phase highly competitive in the rate of nucleation at low temperatures but much less so at high temperatures as compared to the beta phase. The higher sigma(e,beta) value is also consistent with the observation that the beta phase is more responsive to externally added heterogeneous nucleation agents.
Waveguide based energy transfer with gold nanoclusters for detection of hydrogen peroxide
(2014)
Lin, T. N.
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Chang, Y. L.
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Shu, G. W.
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Yuan, C. T.
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Shen, J. L.
H2O2 detection that uses fluorescence resonance energy transfer from InGaN quantum wells to Au nanoclusters via optical waveguiding has been developed. Steady and time-resolved photoluminescence studies have been used to demonstrate the waveguide-based energy transfer. H2O2 detection is achieved by the quenching of the red emission from Au nanoclusters. Advantages of the sensing technique include the capability of visual detection and large area analysis.