Browsing by Author "Sugimori, Taiki"

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Synthesis of perinaphthenones through rhodium-catalyzed dehydrative annulation of 1-naphthoic acids with alkynes
(2018-11-07)
Fukuyama, Takahide
;
Sugimori, Taiki
;
Maetani, Shinji
;
Ryu, Ilhyong
;
應用化學系
An efficient approach to the synthesis of perinaphthenones via the rhodium-catalyzed dehydrative annulation of 1-naphthoic acids with internal alkynes was developed. Norbornadiene can act as an acetylene equivalent to give unsubstituted perinaphthenones at the 2- and 3-positions via dehydrative annulation followed by a retro Diels-Alder reaction.