Browsing by Author "Wang, Guan-Wu"

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Annulation of Benzamides with [60]Fullerene through Palladium(II)-Catalyzed C-H Bond Activation
(2011-03-18)
Chuang, Shih-Ching
;
Rajeshkumar, Venkatachalam
;
Cheng, Chun-An
;
Deng, Jie-Cheng
;
Wang, Guan-Wu
Palladium-catalyzed heteroannulation of N-substituted benzamides with [60]fullerene, which proceeds through direct sp(2) C-H bond activation to form 7-membered ring pallada-intermediate with C(60), led to formation of [60]fulleroisoquinolinones in moderate to good yields (8-64% based on recovered C(60)). A plausible reaction pathway is proposed.