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Browsing by Author "Yang, Yi-Chi"

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    Palladium-Catalyzed Cascade Arylation of Vinylogous Esters Enabled by Tris(1-adamantyl)phosphine
    (2019-12-06)
    Yang, Yi-Chi
    ;
    Lin, Yi-Ching
    ;
    Wu, Yen-Ku
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    應用化學系
    ;
    Department of Applied Chemistry
    Described is a method for the transformation of a cyclic vinylogous ester to the corresponding polyarylated product. We found a catalytic system comprising palladium diacetate and tris(1-adamantyl)phosphine is quite effective in promoting a set of controlled cascade arylations. As a result, a range of novel (hetero)aryl-containing scaffolds was synthesized with a high level of efficiency.