Browsing by Author "Yeh, Jui-Ming"

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Effects of isomeric transformation on characteristics of Alq3 amorphous layers prepared by vacuum deposition at various substrate temperatures
(2007-06-15)
Jian, Zhi-An
;
Luo, Ying-Zi
;
Chung, Jia-Ming
;
Tang, Shiow-Jing
;
Kuo, Ming-Chin
Organic tris(8-hydroxyquinoline)aluminum (Alq3) amorphous layers are prepared by vacuum deposition at various substrate temperatures T-sub from 30 to 180 degrees C. The surface morphology and electrical characteristics of these as-deposited layers are studied by atomic force microscopy and current-density versus electric-field (J-E) curves. The temperature dependence of the dark electrical conductivity sigma(T) determined from J-E curves is also examined. These experimental results reveal that the surface and electrical properties of Alq3 amorphous layers deposited at T-sub between 90 and 120 degrees C exhibit an anomalous T-sub dependence. However, this anomalous T-sub dependence is not observed from infrared absorption measurements, and therefore is not the result of chemical degradation. The observed behavior is explained in terms of the property that the vacuum deposition of Alq3 with T-sub between 90 and 120 degrees C involves a thermal interconversion between meridional and facial Alq3 isomers. (c) x 2007 American Institute of Physics.
Highly efficient solar-heat shield based on the bipolaron-assisted PEDOT:PSS thin film
(2020-08-01)
Thakur, Diksha
;
Wu, Jia-Ren
;
Chandel, Anjali
;
Liu, Shih-Yao
;
Lin, Pei-Chen
We report on an efficient solar-heat shield based on the highly transparent PEDOT:PSS thin film, which significantly reduces the temperature from 38.2 degrees C to 33.5 degrees C. To understand the superior solar-heat shielding ability, the modified PEDOT:PSS thin films were investigated by using the transmittance spectra, Raman scattering spectra, atomic-force microscopic (AFM) images and broadband refractive index spectra. The experimental results show that the molecular structure of the PEDOT chains can be manipulated by varying the Brownian motion of PEDOT polymers in the PEDOT:PSS solutions and the spin rate. The lower Brownian motion of PEDOT polymers and the higher spin rate both can change the molecular structure of the PEDOT chains from bended structures (de-doping states) to linear structures (doping states), which simultaneously increase the near-infrared absorption strength and the visible transparency due to the formation of bipolarons.