Browsing by Author "Yen, Yu-Ting"

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Enhanced Photocarrier Generation with Selectable Wavelengths by M-Decorated-CuInS2 Nanocrystals (M = Au and Pt) Synthesized in a Single Surfactant Process on MoS2 Bilayers
(2019-02-22)
Tang, Shin-Yi
;
Medina, Henry
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Yen, Yu-Ting
;
Chen, Chia-Wei
;
Yang, Tzu-Yi
A facile approach for the synthesis of Au- and Pt-decorated CuInS2 nanocrystals (CIS NCs) as sensitizer materials on the top of MoS2 bilayers is demonstrated. A single surfactant (oleylamine) is used to prepare such heterostructured noble metal decorated CIS NCs from the pristine CIS. Such a feasible way to synthesize heterostructured noble metal decorated CIS NCs from the single surfactant can stimulate the development of the functionalized heterostructured NCs in large scale for practical applications such as solar cells and photodetectors. Photodetectors based on MoS2 bilayers with the synthesized nanocrystals display enhanced photocurrent, almost 20-40 times higher responsivity and the On/Off ratio is enlarged one order of magnitude compared with the pristine MoS2 bilayers-based photodetectors. Remarkably, by using Pt- or Au-decorated CIS NCs, the photocurrent enhancement of MoS2 photodetectors can be tuned between blue (405 nm) to green (532 nm). The strategy described here acts as a perspective to significantly improve the performance of MoS2-based photodetectors with the controllable absorption wavelengths in the visible light range, showing the feasibility of the possible color detection.
Fabrication of large-scale single-crystal Cu(In, Ga)Se-2 nanotip arrays solar cell by one-step ion milling processes
(2013-11-01)
Wang, Yi-Chung
;
Yen, Yu-Ting
;
Liu, Chin-Hung
;
Chen, Chia-Hsiang
;
Kuo, Wei-Chen
Template-free, one step formation of Cu(In, Ga)Se-2 (CIGS) nanotip arrays (NTRs) to enhance device efficiency were discussed. Through Ar+ ion milling process, the CIGS NTRs could be formed directly on the CIGS layer. The angles and lengths of CIGS NTRs could be precisely controlled by incident angle of Ar+ beam and milling time, respectively. Mechanisms were proposed to be a self-masking effect by Cu segregation formed at early stage confirmed by Transmission Electron Microscopy, Grazing Incidence X-ray Diffraction, Energy Dispersive Spectroscopy, and Auger Electron Spectroscopy. Measurements of devices on various KCN washing time and thickness of CdS buffer layer were reported to achieve the highest efficiency of CIGS NTRs devices. This approach provides one-step fast process without templates, easy integration with in-line sputtering process, and no post-selenizatoin process for the formation of CIGS nanostructure, which can stimulate great attention not only in academic investigations but also in industrial side for practical applications. Crown Copyright (C) 2013 Published by Elsevier B.V. All rights reserved.
Improved Efficiency of a Large-Area Cu(In,Ga)Se-2 Solar Cell by a Nontoxic Hydrogen-Assisted Solid Se Vapor Selenization Process
(2014-04-09)
Wu, Tsung-Ta
;
Hu, Fan
;
Huang, Jyun-Hong
;
Chang, Chia-ho
;
Lai, Chih-chung
A nontoxic hydrogen-assisted solid Se vapor selenization process (HASVS) technique to achieve a large-area (40 X 30 cm(2)) Cu(In,Ga)Se-2 (CIGS) solar panel with enhanced efficiencies from 7.1 to 10.8% (12.0% for active area) was demonstrated. The remarkable improvement of efficiency and fill factor comes from improved open circuit voltage (V-oc) and reduced dark current due to (1) decreased interface recombination raised from the formation of a widened buried homojunction with n-type Cd-cu participation and (2) enhanced separation of electron and hole carriers resulting from the accumulation of Na atoms on the surface of the CIGS film. The effects of microstructural, compositional, and electrical characteristics with hydrogen-assisted Se vapor selenization, including interdiffusion of atoms and formation of buried homojunction, were examined in detail. This methodology can be also applied to CIS (CuInSe2) thin film solar cells with enhanced efficiencies from 5.3% to 8.5% (9.4% for active area) and provides a facile approach to improve quality of CIGS and stimulate the nontoxic progress in the large scale CIGS PV industry.
Large Scale Single-Crystal Cu(In,Ga)Se(2) Nanotip Arrays For High Efficiency Solar Cell
(2011-10-01)
Liu, Chin-Hung
;
Chen, Chia-Hsiang
;
Chen, Szu-Ying
;
Yen, Yu-Ting
;
Kuo, Wei-Chen
In this paper, we demonstrated direct formation of large area Cu(In,Ga)Se(2), nanotip arrays (GIGS NTRs) by using one step Ar(+) milling process without template. By controlling milling time and incident angles, the length of CIGS NTRs with adjustable tilting orientations can be precisely controlled. Formation criteria of these CIGS NTRs have been discussed in terms of surface curvature, multiple components, and crystal quality, resulting in a highly anisotropic milling effect. The CIGS NTRs have very low reflectance <0.1% at incident wavelengths between 300 to 1200 nm. Open circuit voltage and short circuit current of CIGS NTRs solar cell were measured to be similar to 390 mV and similar to 22.56 mA/cm(2), yielding the filling factor and the efficiency of 59 and 5.2%, respectively. In contrast to CIGS thin film solar cell with efficiency of 3.2%, the nanostructured CIGS NTRs can have efficiency enhancement of similar to 160% due to the higher light absorption ability because of the nanostructure. The merits of current approach include the latest way via template-free direct creating process of nanostructured CIGS NTRs with controllable dimensionality and large scale production without postselenization process.
Large Scale Single-Crystal Cu(In,Ga)Se-2 Nanotip Arrays For High Efficiency Solar Cell
(2011-10-01)
Liu, Chin-Hung
;
Chen, Chia-Hsiang
;
Chen, Szu-Ying
;
Yen, Yu-Ting
;
Kuo, Wei-Chen
In this paper, we demonstrated direct formation of large area Cu(In,Ga)Se-2, nanotip arrays (GIGS NTRs) by using one step Ar+ milling process without template. By controlling milling time and incident angles, the length of CIGS NTRs with adjustable tilting orientations can be precisely controlled. Formation criteria of these CIGS NTRs have been discussed in terms of surface curvature, multiple components, and crystal quality, resulting in a highly anisotropic milling effect. The CIGS NTRs have very low reflectance <0.1% at incident wavelengths between 300 to 1200 nm. Open circuit voltage and short circuit current of CIGS NTRs solar cell were measured to be similar to 390 mV and similar to 22.56 mA/cm(2), yielding the filling factor and the efficiency of 59 and 5.2%, respectively. In contrast to CIGS thin film solar cell with efficiency of 3.2%, the nanostructured CIGS NTRs can have efficiency enhancement of similar to 160% due to the higher light absorption ability because of the nanostructure. The merits of current approach include the latest way via template-free direct creating process of nanostructured CIGS NTRs with controllable dimensionality and large scale production without postselenization process.
Large scale two-dimensional nanobowl array high efficiency polymer solar cell
(2012)
Chen, Szu-Ying
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Yen, Yu-Ting
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Chen, Yi-Yang
;
Hsu, Chain-Shu
;
Chueh, Yu-Lun
A two-dimensional nanobowl array (2D-NBRs) with a unique honeycomb nanostructure was demonstrated with controllable morphologies synthesized by the Langmuir-Blodgett (LB) method. The periodicity of 2D-NBRs can be controlled by utilizing different diameters of polystyrene (PS) balls ranged from 500 nm, 870 mu m, 1 mu m to 2 mu m. The reflectance measurements revealed that the planar structure with a poly(3-hexylthiophene) (P3HT)/(6,6)-phenyl-C61-butyric acid methyl ester (PCBM) bulk heterojunction layer as an active layer exhibits a reflectance of similar to 20 %, while a significant reduction of the reflectance <5-7 % can be achieved after formation of 2D-NBRs at a PS ball diameter of 500 nm, which perfectly matches simulation results. From experimental results, the highest efficiency of 5.4 % with a filling factor of 66 % was achieved for the device with 2D-NBRs at PS ball diameter of 870 nm. Compared to a planar device with an efficiency of 3.9 %, a maximum enhancement of similar to 40 % can be achieved owing to the enhancement of Jsc because of unique honeycomb geometry, which exhibits a broadband and omnidirectional light harvesting behavior. Furthermore, a flexible solar cell was demonstrated with an enhanced efficiency of 30 % for a planar structure of 1 % to 1.3 % for 2D-NBRs structure.
Non-antireflective Scheme for Efficiency Enhancement of Cu(In,Ga)Se-2 Nanotip Array Solar Cells
(2013-08-01)
Liao, Yu-Kuang
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Wang, Yi-Chung
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Yen, Yu-Ting
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Chen, Chia-Hsiang
;
Hsieh, Dan-Hua
We present systematic works in characterization of CIGS nanotip arrays (CIGS NTRs). CIGS NTRs are obtained by a one-step ion-milling process by a direct-sputtering process of CIGS thin films (CIGS TF) without a postselenization process. At the surface of CIGS NTRs, a region extending to 100 nm in depth with a lower copper concentration compared to that of CIGS TF has been discovered. After KCN washing, removal of secondary phases can be achieved and a layer with abundant copper vacancy (V-Cu) was left. Such compositional changes can be a benefit for a CIGS solar cell by promoting formation of Cd-occupied Cu sites (Cd-Cu) at the CdS/CIGS interface and creates a type-inversion layer to enhance interface passivation and carrier extraction. The raised V-Cu concentration and enhanced Cd diffusion in CIGS NTRs have been verified by energy dispersive spectrometry. Strengthened adhesion of Al:ZnO (AZO) thin film on CIGS NTRs capped with CdS has also been observed in SEM images and can explain the suppressed series resistance of the device with CIGS NTRs. Those improvements in electrical characteristics are the main factors for efficiency enhancement rather than antireflection.
Toward Omnidirectional Light Absorption by Plasmonic Effect for High-Efficiency Flexible Nonvacuum Cu(In,Ga)Se-2 Thin Film Solar Cells
(2014-09-01)
Chen, Shih-Chen
;
Chen, Yi-Ju
;
Chen, Wei Ting
;
Yen, Yu-Ting
;
Kao, Tsung Sheng
We have successfully demonstrated a great advantage of plasmonic Au nanoparticles for efficient enhancement of Cu(In,Ga)Se-2(CIGS) flexible photovoltaic devices. The incorporation of Au NPs can eliminate obstacles in the way of developing ink-printing CIGS flexible thin film photovoltaics (TFPV), such as poor absorption at wavelengths in the high intensity region of solar spectrum, and that occurs significantly at large incident angle of solar irradiation. The enhancement of external quantum efficiency and photocurrent have been systematically analyzed via the calculated electromagnetic field distribution. Finally, the major benefits of the localized surface plasmon resonances (LSPR) in visible wavelength have been investigated by ultrabroadband pump-probe spectroscopy, providing a solid evidence on the strong absorption and reduction of surface recombination that increases electron hole generation and improves the carrier transportation in the vicinity of pn-juction.