Browsing by Issue Date, starting with "2006-09-16"
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Item type:Item, 去除硫化物與資源再生之系統(2006-09-16) ;曾慶平鍾竺均本發明係為一去除硫化物與資源再生之系統,其藉由化學吸收法將硫化氫氣體吸收與轉化,使轉化之產物於沉澱槽裝置進行分離與回收,並利用生物氧化法將化學吸附劑再生,並將再生後之化學吸附劑迴流至化學除硫槽裝置,繼續與入流之硫化氫氣體進行反應,使系統成為一吸收-氧化-分離-回收-再生之生化密閉循環系統。Item type:Item, 音效處理裝置及其處理方法(2006-09-16) ;白明憲 ;白淦元周中權本發明提出一種音效處理裝置及其處理方法,藉由在一裝置內整合多種特殊音效的處理,並且可以進行雜音效除及斷點消除,使得聲音品質提高,且增進娛樂效果,且因整合於一裝置,可即時播放及操作,可達到較低的運算量。Item type:Item, Evaluating IT/IS investments: A fuzzy multi-criteria decision model approach(2006-09-16) ;Chou, Tzy-Yuan ;Chou, Seng-cho T. ;Tzeng, Gwo-Hshiung ;科技管理研究所Institute of Management of TechnologyIT/IS represents a substantial financial investment for many organizations. Whether or not to invest in new IT/IS is, therefore, a difficult decision. Simply considering human resource cost saving criteria is not enough, especially when a corporation has had many information systems. What kind of criteria should we consider when we evaluate IT/IS? How can a new IT/IS project be evaluated in an easy, cost-effective, and collective manner? We need a tool that will help decision-makers evaluate potential new investment projects. Apart from evaluating the new project per se, its compatibility and ability to integrate with an existing IT portfolio must also be considered. Hence, we propose a new approach based on the fuzzy multi-criteria decision model (FMCDM), featuring a 2-stage evaluation process with 26 criteria for IT/IS investment. All stakeholders in a corporation can decide the relative weights they give to the criteria when they evaluate a new IT/IS project by using linguistic values. Experts can also use linguistic values to evaluate all candidates easily. Only an Excel worksheet is needed to obtain an evaluation result. It is cost-effective and efficient. We conduct a case study to show how this model can be used and discuss the results. (c) 2005 Elsevier B.V. All rights reserved.Item type:Item, Emission characteristics of optically pumped GaN-based vertical-cavity surface-emitting lasers(2006-09-18) ;Chu, Jung-Tang ;Lu, Tien-Chang ;You, Min ;Su, Bor-JyeKao, Chih-ChiangThe laser emission characteristics of a GaN-based vertical-cavity surface-emitting laser with two dielectric distributed Bragg reflectors were investigated under optically pumped operation at room temperature. The laser emitted wavelength at 415.9 nm with an emission linewidth of 0.25 nm and threshold pumping energy of 270 nJ. The laser has a high characteristic temperature of about 278 K and high spontaneous emission coupling factor of 10(-2). The laser emission showed single and multiple spot emission patterns with spectral and spatial variations under different pumping conditions. (c) 2006 American Institute of Physics.Item type:Item, Structure of HfO2 films epitaxially grown on GaAs(001)(2006-09-18) ;Hsu, C. -H. ;Chang, P. ;Lee, W. C. ;Yang, Z. K.Lee, Y. J.High-quality HfO2 films of technologically important thickness ranging from 1.8 to 17 nm have been grown epitaxially on GaAs (001) by molecular beam epitaxy. Thorough structural and morphological investigations were carried out by x-ray scattering and high-resolution transmission electron microscopy. The films exhibit an atomically sharp interface with the substrate and are of a monoclinic phase with predominant (001)-plane epitaxy between the HfO2 films and GaAs, in spite of a large lattice mismatch of > 8.5%.Item type:Item, Highly efficient and stable sky blue organic light-emitting devices(2006-09-18) ;Lin, Mei-Fang ;Wang, Lei ;Wong, Wai-Kwok ;Cheah, Kwok-WaiTam, Hoi-LamA highly efficient and stable sky blue organic light-emitting device doped with a sky blue dopant BUBD-1 has been fabricated, achieving an electroluminescence efficiency of 13.2 cd/A and 6.1 lm/W at 20 mA/cm(2) and 6.7 V, with Commission Internationale del'Eclairage coordinates of (0.16, 0.30) and a half-decay lifetime of 1815 h at an initial brightness of 2640 cd/m(2). This performance is one of the best blue devices ever reported without using hole blocking layer or any p or n dopant in hole or electron transport layer. (c) 2006 American Institute of Physics.Item type:Item, Method for fabrication of polycrystallin silicon thin film transistors(2006-09-19) ;Yeh ;Ching-Fa ;Chen ;Tien-FuLouA method for fabricating polycrystalline silicon film transistors, which includes a polysilicon spacer capping onto a sidewall of an active layer in the thin film transistors by an isotropic dry etching of the silicon film. This method suppresses the shrinkage of the active layer during recrystallization by the laser. Large grains are formed in the channel after recrystallization utilizing a high-energy continuous wavelength laser or an excimer laser annealing the active layer. This process does not require an additional mask. Uniform arrangement of grain boundaries and large grain sizes promotes uniformity of performance of the device, which is important in the fields of low temperature polycrystalline silicon thin film transistors (LTPS-TFTs).Item type:Item, Syntheses and specific interactions of poly (hydroxyethyl methacrylate-b-vinyl pyrrolidone) diblock copolymers and comparisons with their corresponding miscible blend systems(2006-09-20) ;Huang, Chih-Feng ;Kuo, Shiao-Wei ;Lin, Fang-Ju ;Wang, Chih-FengHung, Chen-JuiCombination of atom transfer radical and conventional free radical polymerizations has been successfully used to prepare poly(hydroxyethyl methacrylate-b-vinyl pyrrolidone) (PHEMA-b-PVP) copolymers with controlled molecular weight and low polydispersity (< 1.4). The thermal behavior and specific interaction of PHEMA-b-PVP diblock copolymers and their corresponding PHEMA/PVP blends were characterized. The result shows that glass transition temperatures of diblock copolymers analysed by differential scanning calorimetry (DSC) are higher than those of the blends. Infrared and solid-state NMR spectroscopic analyses show that hydrogen-bonding interaction of hydroxyl-carbonyl groups of diblock copolymers was also greater than that of the blends. Measurement of the proton spin-lattice relaxation time in the rotating frame, (T-1P(H)), reveals that all diblock copolymers and blends possess one composition-dependent T H, indicating that both diblock copolymers and blends are homogeneous, which is consistent with the DSC analysis. (c) 2006 Elsevier Ltd. All rights reserved.Item type:Item, 製造奈米線的方法和儀器(2006-09-21) ;朝春光 ;郭金國 ;陳建仲陳蓉萱一種製造奈米線的方法,是以一液壓使熔融材料進入 模板之奈米通道,再凝固熔融材料,以形成數個奈米線。 本發明可製作各種成份之合金奈米線且對環境污染性低。 再者,本發明所製作出的合金奈米線之純度高、缺陷少、 製程簡單且效率高。另外,本發明之方法亦適用於製作高 分子、陶瓷及複合材料等奈米線。Item type:Item, 感應地層移動之光纖光柵雙軸承式偏斜儀(2006-09-21) ;黃安斌何彥德本發明提供一種用於感應地層移動之監測儀,包括:感測元件是由兩端剛性鋁片加上中間一節撓性軟管所組成,且利用應變監測管之原理與節理式機構之設計而達到訊號放大之效應。其中,在節理間安裝兩個雙軸承,其中一個軸承與監測管方向同軸(滑動軸承),在於解除感測器受監測管軸向力(包括重力與摩擦力)對感測器之影響,另一個軸承與監測管方向垂直(轉動軸承),在於限制偏斜儀節理之間只能以橫向軸承為中心旋轉而增加結果分析之可靠度。使用此一設計可以獲得穩定而具有高度重複性之讀數,以便使用雙軸承式偏斜儀做定量之監測與結果分析。Item type:Item, 語音定位系統(2006-09-21) ;胡竹生 ;劉維瀚鄭价呈本發明係為一語音定位系統,將聲音訊號藉由麥克 風陣列接收並傳送至語音偵測系統,以決定系統之運作 狀態流程,再將聲波訊號傳送至環境參數訓練子系統藉 由加成性原理模擬產生訓練訊號,並將該訓練訊號經由 特徵之抽取及描述此特徵之分佈狀況以產生一統計參 數,最後將麥克風陣列所擷取之聲音訊號及統計參數驅 動語音位置偵測子系統以偵測語者位置。Item type:Item, 廢水混凝加藥之控制法(2006-09-21) ;江萬豪 ;黃志彬蘇育俊本發明係為一廢水混凝加藥之控制法,藉由直接滴定來決定加藥劑量,將混凝劑作為酸滴定藥劑,直接對氧化化學機械研磨廢水進行滴定加藥,至適當pH值時,滴定加藥停止,此時之加藥劑量為電性中和去穩之控制點,可精確控制加藥劑量,使加藥劑量降低,處理成本隨之降低,也不因於廢水進流濃度的變化而產生不能適用的情形,可不受限制而使用不同之混凝劑。Item type:Item, Transient behavior of CO poisoning of the anode catalyst layer of a PEM fuel cell(2006-09-22) ;Chu, H. S. ;Wang, C. P. ;Liao, W. C. ;Yan, W. M.機械工程學系A one-dimensional transient mathematical model is applied to simulate the carbon monoxide poisoning effect on the performance of a PEM fuel cell. Based on the CO kinetic model developed by Springer et al. [T.E. Springer, T. Rockward, T.A. Zawodzinski, S. Gottesfeld, J. Electrochem. Soc. 148 (2001) A11-A23], the transient behaviors of the CO poisoning process across the anode catalyst layer is investigated. The results show that the hydrogen coverage, OH, decreases with the time due to CO adsorption on the catalyst sites. A higher CO concentration results in fewer available catalyst sites for hydrogen electro-oxidation and a significant decrease in the response time to reach steady state, t(ss). Increasing the anode overpotential and the gas porosity would result in an increase in the current density, especially at low levels of CO concentration. (c) 2006 Elsevier B.V. All rights reserved.Item type:Item, Polyhedral oligomeric silsesquioxane containing copolymers for negative-type photoresists(2006-09-22) ;Lin, Ho-May ;Wu, Shi-Yin ;Huang, Pei-Yuan ;Huang, Chih-FengKuo, Shiao-WeiA series of methacrylate copolymers containing polyhedral oligomeric silsesquioxane (POSS) was synthesized from the free radical copolymerization of methacrylic acid, methyl methacrylate, and isobutyl propylmethacryl polyhedral oligosilsesquioxanes, and then were modified with glycidyl methacrylate to serve as negative-type photoresists. The UV/Vis spectroscopy reveals that the incorporation of POSS moiety into the copolymer results in a slight decrease in transparency from 99 to 92.5% (at wavelength = 365 nm). The photosensitivity in terms of resist sensitivity (D-n(0.5)), contrast (gamma), and photopolymerization rate are significantly increased with increase in the POSS content. In addition, the induction time is reduced from 0.520 to 0.515 min after incorporating the POSS unit based on photo-DSC analyses. These observed results can be rationalized as due to hydrogen bonding interactions between siloxane and hydroxyl groups in copolymers which tend to attract the methacrylate double bonds surrounding POSS units to crosslink, thereby enhancing the photopolymerization rate and sensitivity. We further evaluate the lithographic property of a photoresist under a collimated exposure.Item type:Item, Visible quantum cutting through downconversion in green-emitting K2GdF5 : Tb3+ phosphors(2006-09-25) ;Lee, Te-Ju ;Luo, Li-Yang ;Diau, Eric Wei-Guang ;Chen, Teng-MingCheng, Bing-MingVisible quantum cutting under excitations at 212 and 172 nm in a green-emitting phosphor K2GdF5:Tb3+ (11%) via a downconversion mechanism is investigated. The authors measured the vacuum ultraviolet (VUV) excitation and emission spectra and proposed mechanisms to rationalize the quantum-cutting effect. One short-UV or one VUV photon absorbed by Tb3+ is split into multiple visible photons emitted by Tb3+ through cross relaxation and direct energy transfer. Calculations indicate an optimal quantum efficiency as great as 189% for this phosphor. (c) 2006 American Institute of Physics.Item type:Item, ZnO nanopowders fabricated by dc thermal plasma synthesis(2006-09-25) ;Ko, T. S. ;Yang, S. ;Hsu, H. C. ;Chu, C. P.Lin, H. F.Ultrafine ZnO nanopowders were successfully synthesized by the de thermal plasma process with a high production rate of 1.2 kg/h. The combination of plasma was found to affect the nanoparticles morphology. Both X-ray diffraction and Raman spectrum analysis confirmed a high quality wurtzite structure of the ZnO nanopowders. Photoluminescence study exhibited strong ultraviolet emission corresponding to the near band edge emission in the ZnO nanopowders. Random laser action observed in the ZnO nanostructures by optical pumping demonstrated high optical and crystal quality of the ZnO nanopowders fabricated by the dc thermal plasma synthesis. (c) 2006 Elsevier B.V. All rights reserved.Item type:Item, Photovoltaic effect on the conductive atomic force microscopic characterization of thin dielectric films(2006-09-25) ;Chang, M. N. ;Chen, C. Y. ;Yang, M. J. ;Chien, C. H.電子工程學系及電子研究所The authors have used front-wing conductive probes to investigate the photovoltaic effect on the conductive atomic force microscopic (C-AFM) characterization of thin dielectric films. The surface photovoltage induced by the laser beam of an atomic force microscope can enhance the electrical field across the studied dielectric film, decreasing the onset voltage of the leakage current, resulting in a modified C-AFM image with a larger current distribution. Moreover, the experimental results also revealed that the influence of the photovoltaic effect on C-AFM would be more significant for dielectric films that are grown on a substrate with a higher carrier concentration. (c) 2006 American Institute of Physics.Item type:Item, Codon-usage bias versus gene conversion in the evolution of yeast duplicate genes(2006-09-26) ;Lin, Yeong-Shin ;Byrnes, Jake K. ;Hwang, Jenn-Kang ;Li, Wen-Hsiung生物科技學系Many Saccharomyces cerevisiae duplicate genes that were derived from an ancient whole-genome duplication (WGD) unexpectedly show a small synonymous divergence (K-S), a higher sequence similarity to each other than to orthologues in Saccharomyces bayanus, or slow evolution compared with the orthologue in Kluyveromyces waltii, a non-WGD species. This decelerated evolution was attributed to gene conversion between duplicates. Using approximate to 300 WGD gene pairs in four species and their orthologues in non-WGD species, we show that codon-usage bias and protein-sequence conservation are two important causes for decelerated evolution of duplicate genes, whereas gene conversion is effective only in the presence of strong codon-usage bias or protein-sequence conservation. Furthermore, we find that change in mutation pattern or in tDNA copy number changed codon-usage bias and increased the K-S distance between K. waltii and S. cerevisiae. Intriguingly, some proteins showed fast evolution before the radiation of WGD species but little or no sequence divergence between orthologues and paralogues thereafter, indicating that functional conservation after the radiation may also be responsible for decelerated evolution in duplicates.Item type:Item, Stable superhydrophobic polybenzoxazine surfaces over a wide pH range(2006-09-26) ;Wang, Chih-Feng ;Wang, Yi-Ting ;Tung, Pao-Hsiang ;Kuo, Shiao-WeiLin, Chun-HungIn this study, we report on a simple two-step casting process designed to create a stable superhydrophobic surface. This method possesses the advantages of being both simple and inexpensive as well as utilizing non-fluorine-containing compounds. Most interestingly, we found that the as-prepared surface possesses superhydrophobic properties not only for pure water but also for corrosive water under both acidic and basic conditions. Furthermore, the superhydrophobic polybenzoxazine surfaces had excellent environmental stability with regard to both heating and organic solvent treatment in terms of the contact angle to water.Item type:Item, High-resolution XANES study of Eu(Ba1-xRx)(2)Cu3O7+delta (R = Eu, Pr)(2006-09-27) ;Chen, J. M. ;Liu, R. S. ;Lee, J. M. ;T Lu, K.Yang, T. J.We have probed the distribution of hole carriers in Eu(Ba1-xEux)(2) Cu3O7+delta (x = 0 - 0.2) and Eu(Ba1-xPrx)(2)Cu3O7+delta (x = 0 - 0.25) by O K-edge and Cu L-edge x-ray absorption spectra. Upon Eu and Pr substitution at the Ba site in Eu(Ba1-xRx)(2)Cu3O7+delta, the concentration of holes in the CuO2 planes becomes greatly diminished. The depletion rate of hole carriers within the CuO2 planes in Eu(Ba1-xPrx)(2)Cu3O7+delta is greater than that in Eu(Ba1-xEux)(2)Cu3O7+delta. The rate of T-c suppression with Pr doping in Eu(Ba1-xPrx)(2)Cu3O7+delta is accordingly greater than that in Eu(Ba1-xEux)(2)Cu3O7+delta.