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Item type:Item, Structural change of ionic association in ionic liquid/water mixtures: A high-pressure infrared spectroscopic study(2009-03-28) ;Umebayashi, Yasuhiro ;Jiang, Jyh-Chiang ;Shan, Yu-Lun ;Lin, Kuan-HungFujii, KentaHigh-pressure infrared measurements were carried out to observe the microscopic structures of two imidazolium-based ionic liquids, i.e., 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide [EMI(+)(CF(3)SO(2))(2)N(-), EMI(+)TFSA(-)] and 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)amide [EMI(+)(FSO(2))(2)N(-), EMI(+)FSA(-)]. The results obtained at ambient pressure indicate that the imidazolium C-H may exist in two different forms, i.e., isolated and network structures. As the sample of pure EMI(+)FSA(-) was compressed, the network configuration is favored with increasing pressure by debiting the isolated form. For EMI(+)TFSA(-)/H(2)O mixtures, the imidazolium C-H peaks split into four bands at high pressures. The new spectral features at approximately 3117 and 3190 cm(-1), being concentration sensitive, can be attributed to the interactions between the imidazolium C-H and water molecules. The alkyl C-H absorption exhibits a new band at approximately 3025 cm(-1) under high pressures. This observation suggests the formation of a certain water structure around the alkyl C-H groups. The O-H stretching absorption reveals two types of O-H species, i.e., free O-H and bonded O-H. For EMI(+)TFSA(-)/H(2)O mixtures, the compression leads to a loss of the free O-H band intensities, and pressure somehow stabilizes the bonded O-H configurations. The results also suggest the non-negligible roles of weak hydrogen bonds in the structure of ionic liquids.Item type:Item, Earthlings(2009-03-29) ;趙祿平 ;Department of Communication and Technology傳播與科技學系“如果我能讓世界上每一個人看一部電影的話,我會要他們看《地球上的生靈》(Earthlings)。”~哲學家與倫理學家彼德‧辛格(Peter Singer)Item type:Item, 甜食之王巧克力(2009-03-29) ;洪效凡 ;Department of Communication and Technology傳播與科技學系巧克力稱霸於甜食界,出現在許多舞台上,它可做為蛋糕原料、甜食副料、或者成為甜點主食。在名瑯滿目的巧克力世界裡,消費者臣服在它的魅力之下,甘願與之陪伴到天長地久。Item type:Item, Item type:Item, 青春。搖滾。《海洋熱》(2009-03-29) ;楊純芳 ;Department of Communication and Technology傳播與科技學系每年七月,全台大大小小的樂團為了站上福隆海邊的大舞台,無不卯足全力奮戰,希望有一天能站上夢幻般的演唱會大舞台,對著台下萬人聽眾表演。導演陳龍男於2003年拍攝長達二小時的記錄片《海洋熱》,記載2003年第四屆貢寮海洋音樂祭的選拔實錄,記錄五個入圍樂團的青春搖滾追夢之旅。Item type:Item, Item type:Item, Item type:Item, Item type:Item, 自傳改編電影 一窺社會端倪(2009-03-29) ;楊睿愷 ;Department of Communication and Technology傳播與科技學系《無家可歸的中學生》、《佐賀的超級阿嬤》、《東京鐵塔》相互對照Item type:Item, 向日葵大叔 與 葵瓜子小姐(2009-03-29) ;曾韋澐 ;Department of Communication and Technology傳播與科技學系我上面寫了"圖文",就不要幫我加"圖說"了喔~謝謝Item type:Item, Item type:Item, Item type:Item, Item type:Item, Item type:Item, Item type:Item, Item type:Item, Item type:Item, 電影改編與原創 如何拿捏(2009-03-29) ;余建良 ;Department of Communication and Technology傳播與科技學系美漫改編電影 顆顆 歹勢,原本想要寫影評 但是做完功課之後...發現稿子發在文化現象比較適合 造成編輯台不便之處 在此致歉 Q"QItem type:Item, Item type:Item, 你今天 Hiphop了嗎?(2009-03-29) ;洪上筑 ;Department of Communication and Technology傳播與科技學系QQ 我做了好久好久好久好久好久~!!!!!!!!