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Item type:Item, Integration structure of semiconductor circuit and microprobe sensing elements and method for fabricating the same(2011-01-25) ;Chiou ;Jin-Chern ;ChangChih-WeiThe present invention discloses an integration structure of a semiconductor circuit and microprobe sensing elements and a method for fabricating the same. In the method of the present invention, a semiconductor circuit is fabricated on one surface of a semiconductor substrate, and the other surface of the semiconductor substrate is etched to form a microprobe structure for detect physiological signals. Next, a deposition method is used to sequentially form an electrical isolated layer and an electrical conductive layer on the microprobes. Then, an electrical conductive material is used to electrically connect the electrical conductive layer with the electrical pads of the semiconductor circuit. Thus is achieved the integration of a semiconductor circuit and microprobe sensing elements in an identical semiconductor substrate with the problem of electric electrical isolated being solved simultaneously. Thereby, the voltage level detected by the microprobes will not interfere with the operation of the semiconductor circuit.Item type:Item, Seebeck coefficients in nanoscale junctions: Effects of electron-vibration scattering and local heating(2011-01-25) ;Hsu, Bailey C. ;Liu, Yu-Shen ;Lin, Sheng Hsien ;Chen, Yu-Chang電子物理學系We report first-principles calculations of inelastic Seebeck coefficients in an aluminum monatomic junction. We compare the elastic and inelastic Seebeck coefficients with and without local heating. In the low-temperature regime, the signature of normal modes in the profiles of the inelastic Seebeck effects is salient. The inelastic Seebeck effects are enhanced by the normal modes and further magnified by local heating. In the high-temperature regime, the inelastic Seebeck effects are weakly suppressed due to the quasiballistic transport.Item type:Item, Investigation of low-temperature electroluminescence of InGaN/GaN based nanorod light emitting arrays(2011-01-28) ;Huang, Ying-Yuan ;Chen, Liang-Yi ;Chang, Chun-Hsiang ;Sun, Yu-HsuanCheng, Yun-WeiFor InGaN/GaN based nanorod devices using a top-down etching process, the optical output power is affected by non-radiative recombination due to sidewall defects (which decrease light output efficiency) and the mitigated quantum confined Stark effect (QCSE) due to strain relaxation (which increases internal quantum efficiency). Therefore, the exploration of low-temperature optical behaviors of nanorod light emitting diodes (LEDs) will help identify the correlation between these two factors. In this work, low-temperature electroluminescent (EL) spectra of InGaN/GaN nanorod arrays were explored and compared with those of planar LEDs. The nanorod LED exhibits a much higher optical output percentage increase when the temperature decreases. The increase is mainly attributed to the increased carriers in the quantum wells for radiative recombination. Also, due to a better spatial overlap of electrons and holes in the quantum wells, the increased number of carriers can be more efficiently recombined in the nanorod device. Next, while the nanorod array shows nearly constant peak energy in the EL spectra at various injection currents at the temperature of 300 K, a blue shift has been observed at 190 K. The results suggest that with less non-radiative recombination and thus more carriers in the quantum wells, carrier screening and band filling still prevail in the partially strain relaxed nanorods. Moreover, when the temperature drops to 77 K, the blue shift of both nanorod and planar devices disappears and the optical output power decreases since there are fewer carriers in the quantum wells for radiative recombination.Item type:Item, Association structures of ionic liquid/DMSO mixtures studied by high-pressure infrared spectroscopy(2011-01-28) ;Jiang, Jyh-Chiang ;Lin, Kuan-Hung ;Li, Sz-Chi ;Shih, Pao-MingHung, Kai-ChanUsing high-pressure infrared methods, we have investigated close interactions of charge-enhanced C-H-O type in ionic liquid/dimethyl sulfoxide (DMSO) mixtures. The solvation and association of the 1-butyl-3-methylimidazolium tetrafluoroborate (BMI(+)BF(4)(-)) and 1-butyl-2,3-dimethylimidazolium tetrafluoroborate (BMM(+)BF(4)(-)) in DMSO-d(6) were examined by analysis of C-H spectral features. Based on our concentration-dependent results, the imidazolium C-H groups are more sensitive sites for C-H-O than the alkyl C-H groups and the dominant imidazolium C-H species in dilute ionic liquid/DMSO-d(6) should be assigned to the isolated (or dissociated) structures. As the dilute mixtures were compressed by high pressures, the loss in intensity of the bands attributed to the isolated structures was observed. In other words, high pressure can be used to perturb the association-dissociation equilibrium in the polar region. This result is remarkably different from what is revealed for the imidazolium C-H in the BMM(+)BF(4)(-)/D(2)O mixtures. DFT-calculations are in agreement with our experimental results indicating that C(4)-H-O and C(5)-H-O interactions seem to play non-negligible roles for BMM(+)BF(4)(-)/DMSO mixtures. (C) 2011 American Institute of Physics. [doi:10.1063/1.3526485]Item type:Item, Molecular structural property and potential energy dependence on nonequilibrium-thermodynamic state point of liquid n-hexadecane under shear(2011-01-28) ;Tseng, Huan-Chang ;Chang, Rong-Yeu ;Wu, Jiann-Shing ;應用化學系Department of Applied ChemistryExtensive computer experiments have been conducted in order to shed light on the macroscopic shear flow behavior of liquid n-hexadecane fluid under isobaric-isothermal conditions through the nonequilibrium molecular dynamic methodology. With respect to shear rates, the accompanying variations in structural properties of the fluid span the microscopic range of understanding from the intrinsic to extrinsic characteristics. As drawn from the average value of bond length and bond angle, the distribution of dihedral angle, and the radius distribution function of intramolecular and intermolecular van der Waals distances, these intrinsic structures change with hardness, except in the situation of extreme shear rates. The shear-induced variation of thermodynamic state curve along with the shear rate studied is shown to consist of both the quasiequilibrium state plateau and the nonequilibrium-thermodynamic state slope. Significantly, the occurrence of nonequilibrium-thermodynamic state behavior is attributed to variations in molecular potential energies, which include bond stretching, bond bending, bond torsion, and intra-and intermolecular van der Waals interactions. To unfold the physical representation of extrinsic structural deformation, under the aggressive influence of a shear flow field, the molecular dimension and appearance can be directly described via the squared radius of gyration and the sphericity angle, R(g)(2) and phi, respectively. In addition, a specific orientational order S(x) defines the alignment of the molecules with the flow direction of the x-axis. As a result, at low shear rates, the overall molecules are slightly stretched and shaped in a manner that is increasingly ellipsoidal. Simultaneously, there is an obvious enhancement in the order. In contrast to high shear rates, the molecules spontaneously shrink themselves with a decreased value of R(g)(2), while their shape and order barely vary with an infinite value of phi and S(x). It is important to note that under different temperatures and pressures, these three parameters are integrated within a molecular description in response to thermodynamic state variable of density and rheological material function of shear viscosity. (C) 2011 American Institute of Physics. [doi:10.1063/1.3541825]Item type:Item, Compact microdisk cavity laser with type-II GaSb/GaAs quantum dots(2011-01-31) ;Hsu, K. S. ;Chiu, T. T. ;Lin, Wei-Hsun ;Chen, K. L.Shih, M. H.Microdisk lasers with active region made of type-II GaSb/GaAs quantum dots on the GaAs substrate have been demonstrated. A microdisk cavity with diameter of 3.9 mu m was fabricated from a 225-nm-thick GaAs layer filled with GaSb quantum dots. Lasing at wavelengths near 1000 nm at 150 K was achieved for this microdisk. A high threshold characteristic temperature of 77 K was also observed. It is found that the lasing wavelength matches closely with the first-order whispering-gallery mode of the cavity as obtained from the finite-element method simulation. (c) 2011 American Institute of Physics. [doi: 10.1063/1.3543839]Item type:Item, A reflective polarizer-free electro-optical switch using dye-doped polymer-stabilized blue phase liquid crystals(2011-01-31) ;Lin, Yi-Hsin ;Chen, Hung-Shan ;Chiang, Tsung-Han ;Wu, Chun-HungHsu, Hsu-KuanWe demonstrate a reflective polarizer-free electro-optical switch using dye-doped polymer-stabilized blue phase liquid crystals (DDPSBP-LC). At the voltage-off state, the dye molecules and liquid crystals form the structure of the double twist cylinders. As a result, the DDPSBP-LC is in dark state due to the combination of Bragg reflection and light absorption. At the voltage-on state, the blue phase structure is unwound locally. The DDPSBP-LC is then in bright state because of the small light absorption only. The applications of such a switch are shutter glass of 3D displays, and electronic papers. (C) 2011 Optical Society of AmericaItem type:Item, Stacked GeO/SrTiO(x) Resistive Memory with Ultralow Resistance Currents(2011-01-31) ;Cheng, C. H. ;Chin, Albert ;Yeh, F. S. ;電子工程學系及電子研究所Department of Electronics Engineering and Institute of ElectronicsWe report a high performance and low-power operated resistive memory. Using stacked covalent-bond-dielectric GeO(x) on metal-oxide SrTiO(x) to form the cost-effective Ni/GeO(x)/SrTiO(x)/TaN resistive random access memory, ultralow set power of small 1 mu W (0.9 mu A at 1.2 V), reset power of 13 pW (0.13 nA at 0.1 V), fast 50 ns switching time and good 10(6) cycling endurance are realized. (C) 2011 American Institute of Physics. [doi:10.1063/1.3549689]Item type:Item, Implementation issues of the nearfield equivalent source imaging microphone array(2011-01-31) ;Bai, Mingsian R. ;Lin, Jia-Hong ;Tseng, Chih-Wen ;機械工程學系Department of Mechanical EngineeringThis paper revisits a nearfield microphone array technique termed nearfield equivalent source imaging (NESI) proposed previously. In particular, various issues concerning the implementation of the NESI algorithm are examined. The NESI can be implemented in both the time domain and the frequency domain. Acoustical variables including sound pressure, particle velocity, active intensity and sound power are calculated by using multichannel inverse filters. Issues concerning sensor deployment are also investigated for the nearfield array. The uniform array outperformed a random array previously optimized for far-field imaging, which contradicts the conventional wisdom in far-field arrays. For applications in which only a patch array with scarce sensors is available, a virtual microphone approach is employed to ameliorate edge effects using extrapolation and to improve imaging resolution using interpolation. To enhance the processing efficiency of the time-domain NESI, an eigensystem realization algorithm (ERA) is developed. Several filtering methods are compared in terms of computational complexity. Significant saving on computations can be achieved using ERA and the frequency-domain NESI, as compared to the traditional method. The NESI technique was also experimentally validated using practical sources including a 125 cc scooter and a wooden box model with a loudspeaker fitted inside. The NESI technique proved effective in identifying broadband and non-stationary sources produced by the sources. (C) 2010 Elsevier Ltd. All rights reserved.Item type:Item, Nitrogenated amorphous InGaZnO thin film transistor(2011-01-31) ;Liu, Po-Tsun ;Chou, Yi-Teh ;Teng, Li-Feng ;Li, Fu-HaiShieh, Han-PingThis work presents the electrical characteristics of the nitrogenated amorphous InGaZnO thin film transistor (a-IGZO:N TFT). The a-IGZO: N film acting as a channel layer of a thin film transistor (TFT) device was prepared by dc reactive sputter with a nitrogen and argon gas mixture at room temperature. Experimental results show that the in situ nitrogen incorporation to IGZO film can properly adjust the threshold voltage and enhance the ambient stability of a TFT device. Furthermore, the a-IGZO: N TFT has a 44% increase in the carrier mobility and electrical reliability and uniformity also progress obviously while comparing with those not implementing a nitrogen doping process. (C) 2011 American Institute of Physics. [doi:10.1063/1.3551537]Item type:Item, A facile route to prepare PdPt alloys for ethanol electro-oxidation in alkaline electrolyte(2011-01-31) ;Lin, Sheng-Chieh ;Chen, Jing-Yu ;Hsieh, Yi-Fan ;Wu, Pu-Wei材料科學與工程學系We adopted a displacement reaction in acidic solution that enabled the spontaneous reduction of Pd and Pt cations in conjunction with corrosive dissolution of Ni. The composition for the PdPt was adjusted by varying the concentration of Pd and Pt cations. From SEM images and XRD patterns, the PdPt formed an fcc alloy uniformly deposited on the Ni substrate. Electro-oxidation of ethanol was conducted in alkaline electrolyte for samples of Pd, Pt, and PdPt alloys. In cyclic voltammetric profiles, the Pd(77)Pt(23) revealed the highest electrocatalytic ability in both apparent current and mass activity, followed by Pd(87)Pt(13), Pd, and Pt. Similar behaviors were observed in life time measurements in which stable performances for ethanol electro-oxidation were obtained. (C) 2010 Elsevier B.V. All rights reserved.Item type:Item, Vertical polymer phototransistor featuring photomultiplication due to base-field shielding(2011-01-31) ;Zan, Hsiao-Wen ;Tsai, Wu-Wei ;Meng, Hsin-Fei ;物理研究所光電工程學系We introduce a vertical polymer phototransistor with low operational voltage (-1.5 V). A blended polymer layer with both acceptor and donor materials was used as a channel material in the vertical space-charge-limited transistor. Under illumination, we obtained external quantum efficiency (EQE) as high as 360% at 620 nm. We propose the effects of base-field shielding as a means to explain high EQE. This proposition has been supported by two-dimensional simulation of the device. (C) 2011 American Institute of Physics. [doi:10.1063/1.3552714]Item type:Item, Stacked GeO/SrTiOx Resistive Memory with Ultralow Resistance Currents(2011-01-31) ;Cheng, C. H. ;Chin, Albert ;Yeh, F. S. ;電子工程學系及電子研究所Department of Electronics Engineering and Institute of ElectronicsWe report a high performance and low-power operated resistive memory. Using stacked covalent-bond-dielectric GeOx on metal-oxide SrTiOx to form the cost-effective Ni/GeOx/SrTiOx/TaN resistive random access memory, ultralow set power of small 1 mu W (0.9 mu A at 1.2 V), reset power of 13 pW (0.13 nA at 0.1 V), fast 50 ns switching time and good 10(6) cycling endurance are realized. (C) 2011 American Institute of Physics. [doi:10.1063/1.3549689]Item type:Item, 2-Step self-assembly method to fabricate broadband omnidirectional antireflection coating in large scale(2011-02-01) ;Yeung, K. M. ;Luk, W. C. ;Tam, K. C. ;Kwong, C. Y.Tsai, M. A.We have developed a simple and reproducible 2-step self-assembly method for the fabrication of broadband, omnidirectional antireflection coating on glass substrate with 4 in. size. The glass surface has been modified to be positively charged, then the negatively charged nano silica is self-assembled to the glass substrate by electrostatic attraction. The nanostructure on the glass substrate reduces the reflection significantly, which results in enhanced transmittance. Transmittance as high as 97.7% at 499 nm has been obtained for a double-side coated glass substrate. Obvious reduction in weighted reflectance is still observed up to 60 degrees incident angle. (C) 2010 Elsevier B.V. All rights reserved.Item type:Item, Investigation of the Atmospheric Helium Dielectric Barrier Discharge Driven by a Realistic Distorted-Sinusoidal Voltage Power Source(2011-02-01) ;Hung, C. -T. ;Chiu, Y. -M. ;Hwang, F. -N. ;Chiang, M. -H.Wu, J. -S.The non-equilibrium atmospheric-pressure parallel-plate helium dielectric barrier discharge (DBD) driven by a realistic 20 kHz distorted-sinusoidal voltage waveform has been investigated by means of simulations and experiments. A self-consistent one-dimensional fluid modeling code considering the non-local electron energy balance was applied to simulate the helium DBD. The effect of selecting plasma chemistry was investigated by comparing simulations with experiments. The results show that the simulations, which include more excited helium, metastable helium and electron-ion-related reaction channels, can faithfully reproduce the measured discharged temporal current quantitatively. Based on the simulated discharge properties, we have found that there is complicated mode transition of discharges from the long Townsend-like to the "dark current"-like, then to the short primary Townsend-like and the short secondary Townsend-like for the helium DBD that is driven by a realistic distorted-sinusoidal voltage power source. Discharge properties in different periods of discharge are discussed in detail in the paper.Item type:Item, All-optical controllable trapping and transport of subwavelength particles on a tapered photonic crystal waveguide(2011-02-01) ;Lin, Pin-Tso ;Lee, Po-Tsung ;光電工程學系Department of PhotonicsWe propose that a tapered photonic crystal waveguide design can unify optical trapping and transport functionalities to advance the controllability of optical manipulation. Subwavelength particles can be trapped by a resonance-enhanced field and transported to a specified position along the waveguide on demand by varying the input wavelength. A simulated transport ability as high as 148 (transport distance/wavelength variation) is obtained by the waveguide with 0.1 degrees tilted angle. Stable trapping of a 50 nm polystyrene particle can be achieved with input power of 7 mW. We anticipate that this design would be beneficial for future life science research and optomechanical applications. (C) 2011 Optical Society of AmericaItem type:Item, Hybrid-Patent Classification Based on Patent-Network Analysis(2011-02-01) ;Liu, Duen-Ren ;Shih, Meng-Jung ;資訊管理與財務金融系 註:原資管所+財金所Department of Information Management and FinanceEffective patent management is essential for organizations to maintain their competitive advantage. The classification of patents is a critical part of patent management and industrial analysis. This study proposes a hybrid-patent-classification approach that combines a novel patent-network-based classification method with three conventional classification methods to analyze query patents and predict their classes. The novel patent network contains various types of nodes that represent different features extracted from patent documents. The nodes are connected based on the relationship metrics derived from the patent metadata. The proposed classification method predicts a query patent's class by analyzing all reachable nodes in the patent network and calculating their relevance to the query patent. It then classifies the query patent with a modified k-nearest neighbor classifier. To further improve the approach, we combine it with content-based, citation-based, and metadata-based classification methods to develop a hybrid- classification approach. We evaluate the performance of the hybrid approach on a test dataset of patent documents obtained from the U.S. Patent and Trademark Office, and compare its performance with that of the three conventional methods. The results demonstrate that the proposed patent-network-based approach yields more accurate class predictions than the patent network-based approach.Item type:Item, Development of an improved spatial reconstruction technique for the HLL method and its applications(2011-02-01) ;Smith, Matthew R. ;Lin, K. -M. ;Hung, C. -T. ;Chen, Y. -S.Wu, J. -S.The integral form of the conventional HLL fluxes are presented by taking integrals around the control volume centred on each cell interface. These integrals are demonstrated to reduce to the conventional HLL flux through simplification by assuming spatially constant conserved properties. The integral flux expressions are then modified by permitting the analytical inclusion of spatially linearly varying conserved quantities. The newly obtained fluxes (which are named HLLG fluxes for clarification, where G stands for gradient inclusion) demonstrate that conventional reconstructions at cell interfaces are invalid and can produce unstable results when applied to conventional HLL schemes. The HLLG method is then applied to the solution of the Euler Equations and Shallow Water Equations for various common benchmark problems and finally applied to a 1D fluid modeling for an argon RF discharge at low pressure. Results show that the correct inclusion of flow gradients is shown to demonstrate superior transient behavior when compared to the existing HLL solver and conventional spatial reconstruction without significantly increasing computational expense. (C) 2010 Elsevier Inc. All rights reserved.Item type:Item, 靜態隨機存取記憶體裝置(2011-02-01) ;楊仕琪 ;楊皓義 ;莊景德黃威本發明係揭露一種靜態隨機存取記憶體裝置,包含複數個記憶體組、複數個寫入控制電路、複數個電源開關組及一位址解碼器,每一寫入控制電路對應連接於每一記憶體組,當位址解碼器接收一寫入資料而產生一控制訊號,並據此開啟其中一電源開關組,使對應之寫入控制電路將一寫入位元資料寫入於對應之記憶體組內,寫入完成後隨之關閉,以減少靜態隨機存取記憶體裝置中的電晶體開啟時間,讓電晶體可進入回復的狀態,因此,可有效減緩晶片(IC)中的靜態隨機存取記憶體受正/負溫度偏壓不穩定性的影響,進而提高存取速度、穩定度及降低功率消耗等優點。Item type:Item, 奈米級之藥物傳送裝置、製備方法及用途(2011-02-01) ;陳三元 ;胡尚秀 ;劉典謨郭冠廷在此揭示活體內監控及釋放藥物的奈米裝置與方法。所揭示的奈米裝置特徵在於具有一裝載有藥物的奈米球,可透過磁性刺激而將其中的藥物釋出。也可將此奈米裝置當作一種顯影劑,於活體內造影並監控所釋出藥物或是單獨注入活體標的位置處之藥物的濃度與分佈情形。