Browsing by Issue Date, starting with "2017-10-21"

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Infrared absorption spectra of partially deuterated methoxy radicals CH2DO and CHD2O isolated in solid para-hydrogen
(2017-10-21)
Haupa, Karolina A.
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Johnson, Britta A.
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Sibert, Edwin L., III
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Lee, Yuan-Pern
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應用化學系
The investigation of partially deuterated methoxy radicals is important because the symmetry lowering from C-3v to C-s provides new insights into the couplings between rovibronic states via Jahn-Teller and spin-orbit interactions. The vibrational spectrum of the partially deuterated methoxy radical CH2DO in a matrix of p-H-2 has been recorded. This species was prepared by irradiating a p-H-2 matrix containing deuterated d1-nitritomethane (CH2DONO) at 3.3 K with laser light at 355 nm. The identification of the radical is based on the photochemical behavior of the precursor and comparison of observed vibrational wavenumbers and infrared (IR) intensities with those predicted from a refined quartic, curvilinear, internal coordinate force field calculated with the coupled-cluster singles and doubles with perturbative triples/cc-pVTZ method. CH2DO reacts with H-2 with a rate coefficient (3.5 +/- 1.0) x 10(-3) s(-1). Predominantly c-CHDOH and a negligibly small amount of t-CHDOH were produced. This stereoselectivity results from the reaction H + C-s-CH2DOH, which was demonstrated by an additional experiment on irradiation of a CH2DOH/Cl-2/p-H-2 matrix with ultraviolet and IR light to induce the H + CH2DOH reaction; only c-CHDOH was observed from this experiment. Even though the energies of transition states and products for the formation of c-CHDOH and t-CHDOH differ by only similar to 10 cm(-1), the selective formation of c-CHDOH can be explained by tunneling of the hydrogen atom via an optimal tunneling path. Similarly, the vibronic spectrum for the partially deuterated specie d(2)-methoxy radical (CHD2O) was obtained upon irradiation of d(2)-nitritomethane (CHD2ONO) at 355 nm. Lines associated with the fundamental vibrational modes were observed and assigned; line positions agree with theoretically predicted vibrational wavenumbers. CHD2O reacts with H-2 with a rate coefficient (6.0 +/- 1.4) x 10(-3) s(-1); CD2OH was produced as a major product because the barrier for the formation of CHDOH from H + CHD2OH is greater by similar to 400 cm(-1). Rate coefficients of the decays of CH3O, CH2DO, CHD2O, and CD3O and their corresponding potential energy surfaces are compared. Published by AIP Publishing.
Multifunctional nanoparticles with controllable dimensions and tripled orthogonal reactivity
(2017-10-21)
Wu, Chih-Yu
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Chang, Chun-Wei
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Yuan, Ruei-Hung
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Chiang, Yu-Chih
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Chen, Jiun-Tai
Multifunctional nanoparticles featuring three distinct and orthogonal functionalities for performing catalyst-free click reactions of azide-alkyne and maleimide-thiol and atom transfer radical polymerization (ATRP) are fabricated using a simple chemical vapor deposition copolymerization approach with the flexibility to control the particle size and geometry.
最純真的微笑　熊米屋小愉兒餅乾
(2017-10-22)
蔡亞融
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Department of Communication and Technology
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傳播與科技學系
熊米屋是小愉兒（喜憨兒）親自手作的烘焙坊。但由於目前尚無實體店，他們藉由走出台北捷運街頭推廣叫賣，讓更多人認識熊米屋小愉兒的餅乾。
願這一切都不會失去
(2017-10-22)
關子茵
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Department of Communication and Technology
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傳播與科技學系
想家了，請關注遊子們的思鄉病。
浪浪別哭　讓愛不再流浪
(2017-10-22)
蔡璨竹
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Department of Communication and Technology
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傳播與科技學系
「浪浪別哭」，一間結合動物中途之家的咖啡廳，用滿滿的愛，幫助浪浪們找到適合自己的家。
政治場域的舞台鬥爭
(2017-10-22)
王毓楷
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Department of Communication and Technology
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傳播與科技學系
學校究竟是否屬於政治場域的一環，或許同言論自由與意識型態的權衡一樣難以定論。
安靜的鋒芒　為內向者除去污名
(2017-10-22)
簡梵軒
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Department of Communication and Technology
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傳播與科技學系
在講求競爭與速度的現代社會下，外向者特質較受推崇，然而近幾年內向者的價值也逐漸受到注目與肯定，本文藉由分析雙方差異，探討兩者的特質與重要性。
總編輯的話
(2017-10-22)
簡文怡
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Department of Communication and Technology
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傳播與科技學系
本期為喀報271期，各類目稿件平均。本期頭題提及花磚文化的保存，其餘報導則以不同體裁切入科技隱憂、弱勢族群等議題。
張馥　從零追求藝術的女孩
(2017-10-22)
陳品文
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Department of Communication and Technology
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傳播與科技學系
一顆沉睡已久的心如何甦醒，一步步帶領張馥走向藝術的殿堂。
無家者　那些在街頭流浪的人們　
(2017-10-22)
戴葦婷
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Department of Communication and Technology
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傳播與科技學系
無家者是從社會安全網上落下來的人們，理解並包容是幫助他們的開始。
擁抱新科技之前　請先抱持懷疑
(2017-10-22)
葉宜瑩
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Department of Communication and Technology
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傳播與科技學系
在科技蓬勃發展的現在，我們做好迎接的準備了嗎？透過刀劍神域序列爭戰，思考我們即將面臨的未來。
大溪老街　人文薈萃之地
(2017-10-22)
戴淨妍
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Department of Communication and Technology
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傳播與科技學系
桃園大溪是個人文薈萃之地，保留了台灣各個時期歷史印跡。
那些說不出口的愛
(2017-10-22)
王貞懿
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Department of Communication and Technology
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傳播與科技學系
說不出口，不是因為不愛，而是這就是我們表達愛的方式，只是蹩腳了點。
走慢了時間　心靈更富有
(2017-10-22)
黃珮瑄
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Department of Communication and Technology
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傳播與科技學系
張西作的第二本書《你走慢了我的時間》，以故事貿易的模式與陌生人交換心情，字句深刻雋永。
田裡有喵　循環農業再造計畫
(2017-10-22)
顏維萱
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Department of Communication and Technology
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傳播與科技學系
介紹「田裡有喵」貓糞堆肥研究計畫，以「貓便當土」作為出發點，讓貓咪們自給自足的同時，達到提倡循環農業的目的。
厭世代的反抗之聲　老王樂隊
(2017-10-22)
王沛軒
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Department of Communication and Technology
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傳播與科技學系
從新生代樂團「老王樂隊」來看教育制度下，青年對未來的世代焦慮。
活在社會一隅的悲鳴
(2017-10-22)
林育平
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Department of Communication and Technology
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傳播與科技學系
他成天魂牽夢縈的平凡，不過是多少人微不足道的理所當然。
仙人掌真的很好養嗎？
(2017-10-22)
吳佩芸
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Department of Communication and Technology
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傳播與科技學系
透過互動問答認識仙人掌。
熱鬧溫暖　傳統市場的魅力
(2017-10-22)
林明慧
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Department of Communication and Technology
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傳播與科技學系
位於台北市信義區的永春市場，假日人潮熙來攘往，攤販充滿活力的叫賣聲以及親切的笑容為繁華的都市帶來溫暖與活力。
保留懷舊記憶　徐嘉彬的花磚人生
(2017-10-22)
徐仟妤
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Department of Communication and Technology
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傳播與科技學系
紀錄台灣花磚博物館創辦人──徐嘉彬先生的心路歷程。