Browsing by Issue Date, starting with "2019-08-14"

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Characteristics of In0.7Ga0.3As MOS Capacitors Obtained using Hydrochloric Acid Treatment, Ammonium Sulfide Passivation, Methanol Treatment, and Forming Gas Annealing
(2019-08-14)
Chung, Sheng-Ti
;
Huang, Yi-Chin
;
Fu, Yen-Chun
;
Lee, Yao-Jen
;
Chao, Tien-Sheng
This paper proposes a chemical pre-treatment process to reduce sulfate prior to atomic layer deposition of Al2O3 gate dielectrics on n-doped In0.7Ga0.3As layers to form metal oxide semiconductor capacitors (MOSCAPs). Cleaning with methanol was done after hydrogen chloride etching and ammonium sulfide passivation. X-ray photoelectron spectroscopy performed on the sample with methanol cleaning indicated that its native oxide regrowth was effectively prevented on the sulfur-passivated In0.7Ga0.3As surface under air exposure. By analysis using atomic force microscopy of the sample cleaned using methanol, no further increase of surface roughness was observed after 5 months of air exposure. In addition, a mid-gap interface defect density (D-it) of 1.3 x 10(12) cm(-2) eV(-1) was obtained from this sample. After forming gas annealing (FGA), the D-it was improved significantly, to a value below 10(12) cm(-2) eV(-1). The obtained data indicate that the combination of chemical pre-treatment and FGA is advantageous to passivating the trap states on In0.7Ga0.3As MOSCAPs. (C) 2019 The Electrochemical Society.
Forced coplanarity of dithienofluorene-based non-fullerene acceptors to achieve high-efficiency organic solar cells
(2019-08-14)
Cao, Fong-Yi
;
Huang, Po-Kai
;
Su, Yen-Chen
;
Huang, Wen-Chia
;
Chang, Shao-Ling
Ladder-type structures have been the key element for high performance non-fullerene acceptors (NFAs). In this work, two dithieno[3,2-b:6,7-b ']fluorine (DTF)-based nonfullerene acceptors, non-bridged DTFT5-FIC and carbon-bridged DTFT9-FIC, with an identical conjugated backbone were designed and synthesized for investigation of the planarization effect. The chemical rigidification with forced coplanarity indeed plays a pivotal role in determining the molecular properties. Compared to the non-bridged open-chain DTFT5-FIC counterpart, the nonacyclic ladder-type DTFT9-FIC with a fully planarized backbone exhibits higher thermal stability, bathochromic absorption and higher electron mobility. The devices using PBDB-T as the p-type polymer and fully planar DTFT9-FIC as the acceptor showed a high efficiency of 9.58%, which is superior to that of the device using the partially planar DTFT5-FIC material (5.45%). By incorporating PC71BM as the second acceptor to enhance the absorption at shorter wavelengths, optimize the morphology and facilitate electron transport, the ternary-blend device using PBDB-T:DTFT9-FIC:PC71BM achieved the highest PCE of 11.82% with a V-oc of 0.88 V, a higher J(sc) of 20.59 mA cm(-2), and an FF of 65.27%.
Ultrabright Fluorescent Polymer Dots with Thermochromic Characteristics for Full-Color Security Marking
(2019-08-14)
Yang, Jyun-Chi
;
Ho, Yu-Chieh
;
Chan, Yang-Hsiang
;
交大名義發表
;
應用化學系
Innovative and scalable security technologies are in high demand to deter increasing counterfeiting in modern society. Here, we report the first example of thermochromic-fluorescent ink based on semiconducting polymer dots (Pdots) by taking advantage of the unique optical properties of Pdots. We designed and synthesized two types of thermochromic molecules and then incorporated them with multicolor fluorescent Pdots. The resulting Pdots exhibited colorimetric and fluorescent dual-readout abilities in response to different temperatures which greatly increase the security level for anticounterfeiting applications. These multifunctional Pdots can be easily doped into flexible substrates or prepared as inks. These full-color inks can be further loaded into marker pens for handwriting or cartridges for inkjet printing with excellent signal-to-background contrast. Moreover, complex and delicate full-color images can be printed on security documents or currency for practical use. We anticipate that this first example of thermoresponsive dual-readout methodology based on Pdots will have broad use in advanced security marking technologies.
Design, Modeling, and Fabrication of High-Speed VCSEL with Data Rate up to 50 Gb/s
(2019-08-14)
Shen, Chih-Chiang
;
Hsu, Tsung-Chi
;
Yeh, Yen-Wei
;
Kang, Chieh-Yu
;
Lu, Yun-Ting
We have studied the characteristics of frequency response at 850-nm GaAs high-speed vertical-cavity surface-emitting lasers (VCSELs) with different kinds of oxide aperture sizes and cavity length using the PICS3D simulation program. Using 5-mu m oxide aperture sizes, the frequency response behavior can be improved from 18.4 GHz and 15.5 GHz to 21.2 GHz and 19 GHz in a maximum of 3 dB at 25 degrees C and 85 degrees C, respectively. Numerical simulation results also suggest that the frequency response performances improved from 21.2 GHz and 19 GHz to 30.5 GHz and 24.5 GHz in a maximum of 3 dB at 25 degrees C and 85 degrees C due to the reduction of cavity length from 3 lambda/2 to lambda/2. Consequently, the high-speed VCSEL devices were fabricated on a modified structure and exhibited 50-Gb/s data rate at 85 degrees C.
Fourier-transform microwave spectroscopy on weakly bound complexes of CH2OO with Ar, CO, and N-2
(2019-08-14)
Nakajima, Masakazu
;
Endo, Yasuki
;
應用化學系
;
Department of Applied Chemistry
Pure rotational transitions of weakly bound complexes of the simplest Criegee intermediate CH2OO with Ar, CO, and N-2 are observed by Fourier-transform microwave (FTMW) and FTMW-MW double-resonance spectroscopy. Many of the observed lines show doublet peaks associated with the tunneling splitting between the two equivalent configurations of the complexes. The intermolecular distances of the complexes are derived from the precise rotational constants determined in this study. The separations between two components of the doublet peaks observed for c-type transitions of CH2OO-Ar are satisfactorily demonstrated by a one-dimensional hindered rotor model for the internal rotation of the CH2OO monomer. Published under license by AIP Publishing.
【設計獎道理，創新設計思考】
(國立陽明大學, 2019-08-15)
陽明電子報編輯小組
雙
(國立陽明大學, 2019-08-15)
林心亮
;
陽明電子報編輯小組
【失智防治與銀光經濟產業應用學分班】
(國立陽明大學, 2019-08-15)
陽明電子報編輯小組
陽明GLORIA講座：打造生技獨角獸的專屬平台
(國立陽明大學, 2019-08-15)
陽明電子報編輯小組
7月份的生醫領航方舟企業講座，邀請到以研發小分子新藥亮眼的國鼎生技蘇經天總經理蒞臨分享。蘇總經理以其豐富的經歷與獨到的見解...
AIT司徒文前處長、康照洲院長接任陽明副校長
(國立陽明大學, 2019-08-15)
陽明電子報編輯小組
本校於8月進行行政主管人事調整，美國在台協會（AIT）台北辦事處司徒文（William Stanton）前處長，以及食品藥物管理署康照洲前署...
【108年度會計業務研討會】
(國立陽明大學, 2019-08-15)
陽明電子報編輯小組
Temperature-Dependent Electroabsorption and Electrophotoluminescence and Exciton Binding Energy in MAPbBr(3) Perovskite Quantum Dots
(2019-08-15)
Rana, Shailesh
;
Awasthi, Kamlesh
;
Bhosale, Sumit S.
;
Diau, Eric Wei-Guang
;
Ohta, Nobuhiro
Organic inorganic lead halide perovskite nanocrystals have attracted much attention as promising materials for the development of solid-state light-emitting devices, but the existence of free or bound excitons or the formation of trap states remains under debate. We recorded temperature-dependent electroabsorption (E-A) and electrophotoluminescence (E-PL) spectra, that is, electric field-induced change in absorption and photoluminescence spectra, for methylammonium lead tribromide (MAPbBr(3)) colloidal perovskite nanocrystals, that is, quantum dots (QD), doped in a poly(methyl methacrylate) film in the temperature range of 40-290 K. Based on the results, the binding energy of the exciton (electron hole pair) was estimated. The exciton binding energy of QD of MAPbBr(3) estimated from the absorption and E-A spectra (similar to 17 meV) is nearly the same as that of a MAPbBr(3) polycrystalline thin solid film, while the exciton binding energy estimated from the temperature-dependent PL spectra (similar to 70 meV) is much greater than that estimated from the absorption profile. The frequency dependence of the E-A intensity observed at 40 and 290 K for the modulated applied electric field indicates a slow ion migration in nanocrystals, which follows the modulation of the applied electric field at a frequency less than 500 Hz. The observed E-A spectra were analyzed with an integral method on assuming the Stark effect; the magnitudes of the changes in electric dipole moment and polarizability following photoexcitation were determined at each temperature from 40 to 290 K. E-PL spectra show that the PL of QD of MAPbBr(3) is quenched on the application of an external electric field; the extent of quenching is much greater for trap emission than for exciton emission. Exciton phonon scattering, which is responsible for the line broadening of the PL spectra, is also discussed based on the temperature-dependent PL spectra.
生科院暑期實驗營，開啟生醫學習的大門
(國立陽明大學, 2019-08-15)
陽明電子報編輯小組
「107年暑期生物醫學實驗營」佳評如潮，陽明生命科學院今年暑假繼續辦理「暑期生物醫學實驗營」，共有69位來自全國各地的高中與大...
服務規格超越德、日，臺灣輔具暨長照大展再締新猷
(國立陽明大學, 2019-08-15)
陽明電子報編輯小組
由陽明ICF暨輔助科技研究中心主辦的「2019臺灣輔具暨長期照護大展」（ATLife），是臺灣唯一以輔具及長照為主軸的國際專業展會， 7...
Corrosion mechanism of annealed equiatomic AlCoCrFeNi tri-phase high-entropy alloy in 0.5 M H2SO4 aerated aqueous solution
(2019-08-15)
Yen, Chao-Chun
;
Lu, Hsueh-Ning
;
Tsai, Ming-Hung
;
Wu, Bo-Wei
;
Lo, Yu-Chieh
This work investigates the corrosion mechanism of annealed equiatomic AlCoCrFeNi tri-phase alloy in 0.5 M H2SO4 aerated aqueous solution. Experimental results indicate that the B2 matrix is preferentially corroded away while grain-boundary FCC and labyrinth-like BCC endure, consistent with the tendency of formation energy for monolayer hydroxide on the (001) plane of three phases calculated by the first principle based on density function theory. Furthermore, the stable passive current density is related to lower k(sp) values of Co(OH)(3), Fe (OH)(3), and Cr(OH)(3), while the annealing effect on enhancing corrosion resistance is owing to the more uniformity of passive hydroxide film.
An Open-Label, Randomized, Active-Controlled Trial of 8 Versus 12 Weeks of Elbasvir/Grazoprevir for Treatment-Naive Patients With Chronic Hepatitis C Genotype 1b Infection and Mild Fibrosis (EGALITE Study): Impact of Baseline Viral Loads and NS5A Resistance-Associated Substitutions
(2019-08-15)
Huang, Chung-Feng
;
Hung, Chao-Hung
;
Cheng, Pin-Nan
;
Bair, Ming-Jong
;
Huang, Yi-Hsiang
Background. A 12-week grazoprevir/elbasvir regimen is highly effective against hepatitis C virus genotype 1 (HCV-1) infection. The efficacy of an 8-week regimen for treatment-naive HCV-1-infected patients with mild fibrosis has not been determined. Methods. Treatment-naive HCV-1b-infected patients with mild fibrosis were randomly assigned to receive 8 (n = 41) or 12 (n = 41) weeks of grazoprevir/elbasvir therapy. The primary end point was a sustained virologic response, defined as an HCV RNA level of < 12 IU/mL, at posttreatment week 12 (SVR12). Results. SVR12 was achieved by 87.8% of patients (36 of 41) in the 8-week arm and 100% (41 of 41) in the 8-week arm of the full-analysis population and by 90.0% (36 of 40) and 100% (41 of 41), respectively, in the per-protocol population (all P = .055). In the 8-week arm, a significantly lower SVR12 rate was observed among patients with a high HCV-1b load, defined as >= 1 500 000 IU/mL (79% vs 100%; P =.042), and among those with a baseline Y93H resistance-associated substitution (RAS) frequency of >15% in HCV nonstructural protein 5A (NS5A; 40.0% vs 97.1%; P = .004). Between-group analysis demonstrated that, among patient with a high HCV-1b load and a baseline Y93H RAS frequency of >15%, those in the 8-week arm had a substantially lower SVR12 rate than those in the 12-week arm (40.0% vs 100.0%). All 4 HCV-1b relapses had a Y93H RAS frequency of >99% at posttreatment week 12. Conclusions. Twelve weeks of grazoprevir/elbasvir therapy is highly effective for treatment-naive patients with mild fibrosis. A truncated, 8-week grazoprevir/elbasvir regimen might be applied for those with low viral loads or without a significant NS5A RAS frequency.
Lightweight Torque Sensor Based on a Gradient Grating Period Guided-Mode Resonance Filter
(2019-08-15)
Wang, Yen-Chieh
;
Jang, Wen-Yea
;
Huang, Cheng-Sheno
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機械工程學系
;
Department of Mechanical Engineering
This paper describes the design, fabrication, and testing of a lightweight and compact torque sensor system based on a gradient grating period guided-mode resonance (GGP-GMR) filter and a flexure-elastic-force-sensing element. The GMR filter exhibits a characteristic resonant reflection, when illuminated with a broadband light source at normal incidence. Instead of a fixed grating period, the GGP-GMR filter consists of grating periods varying from 250 to 550 nm with an increment of 2 nm. Given the flexibility of the plastic-based GGP-GMR filter, it can be bent conform to the cylindrical surface of the flexure. The applied torque induced deformation of the flexure and angular displacement of the attached GGP-GMR. For a stationary light source, the angular displacement of the GGP-GMR filter results in illumination at different locations (grating periods), leading to a shift of the resonant reflection wavelength. The magnitude of shift in the reflection wavelength can be correlated to the magnitude of deformation and the applied torque. In addition, commercial software based on the finite element method was used to simulate the proposed design, which indicates that the flexure made of medium-carbon steel can withstand the torque of 35 Nm without yielding. Furthermore, the simulation results (torque-induced deformation) were consistent with those obtained using the proposed torque sensor system. Torque measurements from 0 to 25 Nm showed good linearity. The limit of detection achieved was 0.77 Nm.
【全人口腔衛生照護教育訓練】
(國立陽明大學, 2019-08-15)
陽明電子報編輯小組
活隱喻．活博物館──參訪交大藝文中心「六燃文件展」
(國立陽明大學, 2019-08-15)
陽明電子報編輯小組
上學期結束前，藝文中心黃桂瑩主任帶著視文所的同學，一起去參訪交大藝文中心舉辦的「六燃文件展」，並邀請到策展人、交通大學應藝所的賴雯淑老師為大家介紹。這個「今夏最有深度的新竹必看展覽」，讓大家看到新竹多樣的一面，也體驗鮮活生動的「新竹生博物館」。
【周成功老師課程講座】～生命是什麼？
(國立陽明大學, 2019-08-15)
陽明電子報編輯小組