Photodissociation dynamics of vinyl chloride investigated with a pulsed slit-jet and time-resolved Fourier-transform spectroscopy

dc.citation.epage	1164	en_US
dc.citation.issue	12	en_US
dc.citation.spage	1161	en_US
dc.citation.volume	57	en_US
dc.contributor.author	Bahou, M	en_US
dc.contributor.author	Lee, YP	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.date.accessioned	2014-12-08T15:39:46Z
dc.date.available	2014-12-08T15:39:46Z
dc.date.issued	2004	en_US
dc.description.abstract	Following photodissociation of vinyl chloride seeded in a He supersonic jet at 193 nm, rotationally resolved infrared emission of HCl ( v) are recorded to yield nascent rotational and vibrational distributions. Preliminary results show that the rotational distribution of HCl free from rotational quenching deviates slightly from Boltzmann-type distribution and agrees well with trajectory calculations; a portion of the low-J component observed previously in a flow system is attributed to quenching. The implications for photodissociation dynamics are discussed.	en_US
dc.identifier.doi	10.1071/CH04117	en_US
dc.identifier.issn	0004-9425	en_US
dc.identifier.journal	AUSTRALIAN JOURNAL OF CHEMISTRY	en_US
dc.identifier.uri	http://dx.doi.org/10.1071/CH04117	en_US
dc.identifier.uri	https://ir.lib.nycu.edu.tw/handle/11536/27165
dc.identifier.wosnumber	WOS:000225599500010
dc.language.iso	en_US	en_US
dc.title	Photodissociation dynamics of vinyl chloride investigated with a pulsed slit-jet and time-resolved Fourier-transform spectroscopy	en_US
dc.type	Article; Proceedings Paper	en_US

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