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收集所有交通大學研究人員與學生個人或團體所發表之各項學術著作，涵蓋期刊論文、教師專書、學位論文等項。;;Collections of Publications of NCTU Researchers and Students Like Journal Papers and Thesis.

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    Luminescent Properties and Energy Transfer of Green-Emitting Ca3Y2(Si3O9)(2):Ce3+,Tb3+ Phosphor
    (2009-01-01)
    Chiu, Yi-Chen
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    Liu, Wei-Ren
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    Yeh, Yao-Tsung
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    Jang, Shyue-Ming
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    Chen, Teng-Ming
    Green-emitting phosphors of Ca3Y2(Si3O9)(2):Ce3+,Tb3+ have been synthesized by solid-state reaction. The luminescence properties were characterized by photoluminescence (PL) and photoluminescence excitation spectra, reflection spectra, and a detection system using an integrating sphere equipped with a spectrofluorometer. With Ce3+ co-doping as a sensitizer, the PL intensity of Ca3Y2(Si3O9)(2):Ce3+,Tb3+ was found to increase dramatically by a factor of 5.8. For comparison, the emission intensity of composition-optimized Ca3Y2(Si3O9)(2):Ce3+,Tb3+ is 126% of green commodity, ZnS:Cu,Al. The quantum efficiency of Ca3Y2(Si3O9)(2):Ce3+,Tb3+ is as high as 77% compared to ZnS:Cu,Al (53%). The energy transfer from Ce3+ to Tb3+ is also of resonant type via a dipole-dipole mechanism with the energy-transfer critical distance of 6.78 A degrees. By utilizing the principle of energy transfer and appropriate tuning of activator contents, we are currently evaluating the potential application of Ca3Y2(Si3O9)(2):Ce3+,Tb3+ as a highly efficient UV-convertible phosphor.
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    Intense blue-emitting Ca2PO4Cl:Eu2+ phosphor for near-ultraviolet converting white light-emitting diodes
    (2010-12-01)
    Chiu, Yi-Chen
    ;
    Liu, Wei-Ren
    ;
    Chang, Chun-Kuei
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    Liao, Cheng-Chun
    ;
    Yeh, Yao-Tsung
    A blue phosphor Ca2PO4Cl:Eu2+ (CAP:Eu2+) was synthesized by solid state reaction. The Ca2PO4Cl:Eu2+ exhibited high quantum efficiency and excellent thermal stability. The luminescent intensity of Ca2PO4Cl:Eu2+ was found to be 128% under excitation at 380 nm, 149% under 400 nm, and 247% under 420 nm as high as that of BaMgAl10O17:Eu2+. The optimal doping concentration was observed to 11 mol.% of CAP:Eu2+. The energy transfer between Eu2+ ions in CAP were occurred via electric multipolar interaction, and the critical transfer distance was estimated to be 1.26 nm. A mixture of blue-emitting Ca2PO4Cl:Eu2+, green-emitting (Ba,Sr)(2)SiO4:Eu2+ and red-emitting CaAlSiN3:Eu2+ phosphors were selected in conjunction with 400 nm chip to fabricate white LED devices. The average color-rendering index R-a and correlated color temperature (T-c) of the white LEDs were found to be 93.4 and 4590 K, respectively. The results indicated that it was a promising candidate as a blue-emitting phosphor for the near-UV white light-emitting diodes.
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    Assessment of Luminescent Downshifting Layers for the Improvement of Light-Harvesting Efficiency in Dye-Sensitized Solar Cells
    (2014-12-01)
    Hosseini, Zahra
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    Diau, Eric Wei-Guang
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    Mehrany, Khashayar
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    Taghavinia, Nima
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    應用化學系
    Luminescence downshifting (LDS) of light can be a practical photon management technique to compensate the narrow absorption band of high-extinction-coefficient dyes in dye-sensitized solar cells (DSSCs). Herein, an optical analysis on the loss mechanisms in a reflective LDS (R-LDS)/DSSC configuration is reported. For squaraine dye (550-700 nm absorption band) and CaAlSiN3:Eu2+ LDS material (550-700 nm emission band), the major loss channels are found to be non-unity luminescence quantum efficiency (QE) and electrolyte absorption. By using an ideal LDS layer (QE=100%), a less absorbing electrolyte (Co-based), and antireflection coatings, approximately 20% better light harvesting is obtained. If the absorption/emission band of dye/LDS is shifted to 800 nm, a maximal short-circuit current density (J(sc)) of 22.1 mAcm(-2) can be achieved. By putting the LDS layer in front of the DSSC (transmissive mode), more significant loss channels are observed, and hence a lower overall efficiency than the R-LDS configuration.