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收集所有交通大學研究人員與學生個人或團體所發表之各項學術著作,涵蓋期刊論文、教師專書、學位論文等項。;;Collections of Publications of NCTU Researchers and Students Like Journal Papers and Thesis.
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Item type:Item, Metal Nanoparticle-Decorated Two-Dimensional Molybdenum Sulfide for Plasmonic-Enhanced Polymer Photovoltaic Devices(2015-08-01) ;Chuang, Ming-Kai ;Yang, Shun-Shing ;Chen, Fang-Chung ;光電工程學系Department of PhotonicsAtomically thin two-dimensional (2D) transition metal dichalcogenides have also attracted immense interest because they exhibit appealing electronic, optical and mechanical properties. In this work, we prepared gold nanoparticle-decorated molybdenum sulfide (AuNP@MoS2) through a simple spontaneous redox reaction. Transmission electron microscopy, UV-Vis spectroscopy, and Raman spectroscopy were used to characterize the properties of the AuNP@MoS2 nanomaterials. Then we employed such nanocomposites as the cathode buffer layers of organic photovoltaic devices (OPVs) to trigger surface plasmonic resonance, leading to noticeable enhancements in overall device efficiencies. We attribute the primary origin of the improvement in device performance to local field enhancement induced by the effects of localized surface plasmonic resonance. Our results suggest that the metal nanoparticle-decorated two-dimensional materials appear to have great potential for use in high-performance OPVs.Item type:Item, Solution-Processed Nanocomposites Containing Molybdenum Oxide and Gold Nanoparticles as Anode Buffer Layers in Plasmonic-Enhanced Organic Photovoltaic Devices(2013-12-11) ;Tan, Kim-Shih ;Chuang, Ming-Kai ;Chen, Fang-Chung ;Hsu, Chain-Shu應用化學系Solution-processed nanocomposites containing molybdenum oxide (MoO3) and gold nanoparticles (Au NPs) have been used as anode buffer layers in organic photovoltaic devices (OPVs). The resulting devices exhibit a remarkable enhancement in power conversion efficiency after Au NPs were incorporated into the device. Such enhancements can be attributed to the localized surface plasmon resonance induced by the metallic nanostructures. We have also found that the rate of exciton generation and the probability of exciton dissociation were increased. Furthermore, the devices made of the MoO3 buffer layer containing Au NPs exhibited superior stability. This work opens up the possibility of fabricating OPVs with both high efficiency and a prolonged lifetime.