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收集所有交通大學研究人員與學生個人或團體所發表之各項學術著作,涵蓋期刊論文、教師專書、學位論文等項。;;Collections of Publications of NCTU Researchers and Students Like Journal Papers and Thesis.

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  • Item type:Item,
    Investigations into thermoluminescence and afterglow characterization of strontium aluminates with boron-modification and reductions via sol-gel route
    (2012-10-01)
    Chen, I-Cherng
    ;
    Chen, Ker-Kong
    ;
    Chen, Hong-Sen
    ;
    Du, Je-kang
    ;
    Lin, Tsao-Jen
    The effects of strontium aluminates of SrAl2O4:Eu2+,Dy3+ (SAED) and boron-modified SAED (BSAED) phases synthesized from a sol-gel process on thermoluminescence (TL) along with their afterglow properties were systematically investigated with thermal activation in the different atmospheres. The result showed that the addition of boron and the reduction routes of Eu3+ to Eu2+ in SrAl2O4:Dy3+ were related to phosphorescent decay properties. The aid of Dy3+ to induce the hole-trapping effect required both SAED and BSAED to be heated at 1300 degrees C under the H-2/N-2 (5%: 95%) atmosphere. However, the trapping behavior of the reductions of SAED in nitrogen was similar to the compound without Dy3+ co-doping SrAl2O4:Eu2+ (SAE) in H-2/N-2 (5%: 95%). BSAED showed deeper traps in situ compared to SAED which contained no boron, and this led to the better afterglow properties of BSAED than those of SAED. The afterglow spectrum of BSAED showed two peaks at 400+/-1 nm and 485+/-1 nm, which were two individuals composed and contributed from different depths of traps at 0.57 and 0.76 eV, accordingly. The depth of the traps was calculated from the Hoogenstraaten's plot of glow curves. The calculations for SAED and SAE were at around 0.43 and 0.18 eV, respectively.
  • Item type:Item,
    Synthesis, composition optimization, and VUV photoluminescence characterization of (Y,Gd) (V,P) O-4 : Eu3+ as a potential red-emitting plasma-display panel phosphor
    (2007-12-01)
    Wu, Chia-Chin
    ;
    Cheng, Bing-Ming
    ;
    Chen, Teng-Ming
    ;
    應用化學系
    ;
    Department of Applied Chemistry
    The synthesis, composition optimization, VUV Photoluminescence (PL) spectra, and optical properties, of (Y, Gd) (V, P)O-4 : Eu3+ phosphors were investigated by synchrotron radiation. The VUV PLE spectra and the correlation among VUV PL intensity, lambda(em), and Eu3+, Gd3+, and P-content were established. The PLE spectral studies showed that (Y, Gd) (V, P)O-4: Eu3+ exhibited significant absorption in the VUV range. The VUV PL intensity was found to enhance with PO43- and Gd3+ -doping. Furthermore, the chromaticity characteristics of (Y, Gd) (V, P)O-4: Eu3+ were also found to be (0.6614, 0.3286) and compared against (Y, Gd)BO3:Eu3+ as a reference. Based on the characterization results, we are currently improving and evaluating the potential application of (Y, Gd) (V, P)O-4: Eu3+ as a new red-emitting PDP phosphor.