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收集所有交通大學研究人員與學生個人或團體所發表之各項學術著作,涵蓋期刊論文、教師專書、學位論文等項。;;Collections of Publications of NCTU Researchers and Students Like Journal Papers and Thesis.

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    A simple approach toward low-dielectric polyimide nanocomposites: Blending the polyimide precursor with a fluorinated polyhedral oligomeric silsesquioxane
    (2008-09-15)
    Ye, Yun-Sheng
    ;
    Yen, Ying-Chieh
    ;
    Chen, Wen-Yi
    ;
    Cheng, Chih-Chia
    ;
    Chang, Feng-Chih
    This article describes a new and simple method for preparing polyimide nanocomposites that have very low dielectric constants and good thermal properties: simply through blending the polyimide precursor with a fluorinated polyhedral oligomeric silsesquioxane derivative, octakis(dimethylsiloxyhexafluoropropyl) silsesquioxane (OF). The low polarizability of OF is compatible with polyimide matrices, such that it can improve the dispersion and free volume of the resulting composites. Together, the higher free volume and lower polarizability of OF are responsible for the lower dielectric constants of the PI-OF nanocomposites. This simple method for enhancing the properties of polyimides might have potential applicability in the electronics industry. (C) 2008 Wiley Periodicals, Inc.