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Elastic interaction between screw dislocations and a circular surface crack
(1997-03-31)
Lin, KM
;
Lin, HC
;
Chen, KC
;
Chang, HL
;
材料科學與工程學系
The behaviour of a screw dislocation around a circular surface crack was analyzed using the conformal mapping method. The effects of the crack length l and its radius of curvature R on the shielding effect and the strain energy were discussed in detail. It was found that for a dislocation being fixed at a constant distance from the crack tip and located on a plane tangent to crack surface at the tip, there exists a critical crack length l* corresponding to a maximum shielding effect induced by the dislocation on the circular surface crack. The l* increases with R and approaches infinity as the crack becomes planar (i.e. R --> infinity). The shielding effect vanishes as the crack disappears. It increases rapidly with l if 0 < l much less than l*, regardless of R. After reaching the maximum, it decreases slightly for larger R but significantly for smaller R as the crack becomes longer. The shielding is more pronounced for larger R than that for smaller R, with the difference increasing with crack length. As a result, a surface microcrack propagates initially in a rather brittle manner then becomes more ductile. When the crack gets longer, it still keeps ductile for a less curved or a planar crack but becomes relatively brittle for a severely curved crack. In addition, the strain energy is also significantly influenced by crack length and increases rapidly with l when l is rather small, regardless of R. With increasing l, it becomes less affected by l, and the variation with R is still not obvious, with larger R corresponding to a slightly higher strain energy. (C) 1997 Elsevier Science S.A.
Effect of lateral substituents on the mesomorphic properties of side-chain liquid crystalline polysiloxanes containing 4-[(S)-2-methyl-1-butoxy]phenyl 4-(alkenyloxy)benzoate side groups
(1997-09-30)
Hsu, CS
;
Chu, PH
;
Chang, HL
;
Hsieh, TH
;
應用化學系
The synthesis of side-chain liquid crystalline polysiloxanes containing either 4-[(S)-2-methyl-1-butoxy] phenyl 4-(alkenyloxy)benzoate or laterally fluoro-, chloro-, bromo-, and methoxy-substituted 4-[(S)-2-methyl-1-butoxy] phenyl 4-(alkenyl oxy)benzoate mesogenic side groups is presented. The mesomorphic properties of the synthesized polymers have been characterized by optical polarizing microscopy, differential scanning calorimetry, and X-ray diffraction measurements. The effects of spacer length and lateral substituent on the mesomorphic properties of the obtained polymers are examined. The five polymers which contain three methylene units in the spacers show no mesophase, while the five polymers which contain eleven methylene units in the spacer display smectic mesomorphism. Among the other fifteen polymers which contain respectively four, five, or six methylene units in the spacers, those with small fluoro and chloro substituents reveal respectively an Sd phase, while those with bulky bromo and methoxy substituents show no liquid crystalline behavior. The experimental results demonstrate that introducing a bulky lateral substituent into the mesogenic core of a polymer depresses the tendency to form a mesophase. Furthermore, the technique of thermally stimulated current has been used to study the dipolar relaxation mechanisms in a side-chain liquid crystalline polysiloxane. (C) 1997 John Wiley & Sons Inc.
Thermally stimulated deporization current and DSC studies of the dual glass transitions in side-chain liquid crystalline copolysiloxanes
(1996-08-25)
Chang, HL
;
Hsu, CS
;
應用化學系
;
Department of Applied Chemistry
The relationship between the working pressure and accident risks for aggregate-hauling vehicle drivers in Taiwan
(2001)
Chang, HL
;
Yeh, CC
;
運輸與物流管理系註：原交通所+運管所
;
Department of Transportation and Logistics Management
This study is undertaken to explore the sources of stress which enhance the accident risk of AHV drivers and try to develop corresponding strategies to improve the driving safety for AT-TV drivers. In this paper, we introduce the relationship between work pressure and accident risk and develop a conceptual model based on this relationship. An empirical study was conducted by using the data collected from a face to face interview with AHV drivers to verify our hypothetical relationship. The findings of this study provide a set of valuable information to help setting effective policies and strategies.
Thermally stimulated deporization current and DSC studies of the dual glass transitions in side-chain liquid crystalline copolysiloxanes
(1996-08-25)
Chang, HL
;
Hsu, CS
;
應用化學系
;
Department of Applied Chemistry
Effect of thin film coating of Au on joint strength in Invar-Invar packages
(1996-11-01)
Wang, SC
;
Wang, CM
;
Wang, C
;
Chang, HL
;
Tu, YK
The effect of a thin film coating of Au on the joint strength, weld width, and penetration depth in laser welding techniques for Invar-Invar packages is investigated experimentally. It is found that the joint strength, weld width, and penetration depth are strongly dependent on the coating of Au thickness on the Invar material. The welded joints with thick Au coating show narrower weld width, shallower penetration, and hence less joint strength than those of the packages with thin Au coating. The increase in both the thermal conductivity and the vapor volume in the welded joints as the coating of Au thickness increases are the possible mechanisms for the reduction. Detailed knowledge of the effect of thin film coatings of Au on the welded materials, which gives both the highest joint strength and good adhesion, is essential for practical design and fabrication of reliable optoelectronic packaging.

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