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收集所有交通大學研究人員與學生個人或團體所發表之各項學術著作,涵蓋期刊論文、教師專書、學位論文等項。;;Collections of Publications of NCTU Researchers and Students Like Journal Papers and Thesis.

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Now showing 1 - 5 of 5
  • Item type:Item,
    Metal Nanoparticle-Decorated Two-Dimensional Molybdenum Sulfide for Plasmonic-Enhanced Polymer Photovoltaic Devices
    (2015-08-01)
    Chuang, Ming-Kai
    ;
    Yang, Shun-Shing
    ;
    Chen, Fang-Chung
    ;
    光電工程學系
    ;
    Department of Photonics
    Atomically thin two-dimensional (2D) transition metal dichalcogenides have also attracted immense interest because they exhibit appealing electronic, optical and mechanical properties. In this work, we prepared gold nanoparticle-decorated molybdenum sulfide (AuNP@MoS2) through a simple spontaneous redox reaction. Transmission electron microscopy, UV-Vis spectroscopy, and Raman spectroscopy were used to characterize the properties of the AuNP@MoS2 nanomaterials. Then we employed such nanocomposites as the cathode buffer layers of organic photovoltaic devices (OPVs) to trigger surface plasmonic resonance, leading to noticeable enhancements in overall device efficiencies. We attribute the primary origin of the improvement in device performance to local field enhancement induced by the effects of localized surface plasmonic resonance. Our results suggest that the metal nanoparticle-decorated two-dimensional materials appear to have great potential for use in high-performance OPVs.
  • Item type:Item,
    Photoexfoliation of two-dimensional materials through continuous UV irradiation
    (2017-03-24)
    Lin, Wai-Chen
    ;
    Chuang, Ming-Kai
    ;
    Keshtov, Muchamed L.
    ;
    Sharma, Ganesh D.
    ;
    Chen, Fang-Chung
    This paper describes the preparation of fluorinated graphene nanosheets (FGNs) through photoexfoliation of fluorinated graphite (FG) in the liquid phase. We discovered that UV irradiation of FG dispersions in N-methyl-2-pyrolidone facilitated exfoliation to give FGNs. Transmission electron microscopy and atomic force microscopy revealed that the average thickness of the FGNs was approximately 3 nm; they were considerably thinner than the nanosheets prepared using a conventional sonication approach. Furthermore, when the FGNs were deposited uniformly onto substrates (through spin coating), they formed effective cathode interlayers for polymer solar cells (PSCs), the efficiency of which was 60% greater than that of PSCs containing FGNs prepared through ultrasonication.
  • Item type:Item,
    Plasmonic Effects of Amphiphilic Gold Nanoparticles in Polymer Optoelectronic Devices
    (2016)
    Chuang, Ming-Kai
    ;
    Lin, Chun-Hao
    ;
    Chen, Fang-Chung
    ;
    光電工程學系
    ;
    Department of Photonics
    Amphiphilic gold nanoparticles have been synthesized and employed for improving the performance of polymer optoelectronics devices. Such nanocomposites could be readily incoporated into the buffer and/or photoactive layers, resulting in obvious enhancements in device efficiencies.
  • Item type:Item,
    Efficient and stable polymer solar cells prepared using plasmonic graphene oxides as anode buffers
    (2015-08-01)
    Chen, Chung-Lei
    ;
    Chuang, Ming-Kai
    ;
    Chen, Chyong-Hua
    ;
    Chu, Chih-Wei
    ;
    Keshtov, Muchamed L.
    Gold nanoparticle-decorated graphene oxides (AuNP-GOs) have been incorporated into inverted organic photovoltaic devices (OPVs) as anode interlayers. The OPVs fabricated with AuNP-GOs exhibited significant improvement in both the short-circuit current and fill factor compared to a reference device fabricated with neat GOs. We attribute the improvement in the efficiency of the device to the plasmonic effects of the AuNP-GO nanocomposites, which induced local enhancement of the electromagnetic field. More importantly, the inverted OPVs also exhibited better reliability after the use of AuNP-GO nanocomposites.
  • Item type:Item,
    Solution-Processed Nanocomposites Containing Molybdenum Oxide and Gold Nanoparticles as Anode Buffer Layers in Plasmonic-Enhanced Organic Photovoltaic Devices
    (2013-12-11)
    Tan, Kim-Shih
    ;
    Chuang, Ming-Kai
    ;
    Chen, Fang-Chung
    ;
    Hsu, Chain-Shu
    ;
    應用化學系
    Solution-processed nanocomposites containing molybdenum oxide (MoO3) and gold nanoparticles (Au NPs) have been used as anode buffer layers in organic photovoltaic devices (OPVs). The resulting devices exhibit a remarkable enhancement in power conversion efficiency after Au NPs were incorporated into the device. Such enhancements can be attributed to the localized surface plasmon resonance induced by the metallic nanostructures. We have also found that the rate of exciton generation and the probability of exciton dissociation were increased. Furthermore, the devices made of the MoO3 buffer layer containing Au NPs exhibited superior stability. This work opens up the possibility of fabricating OPVs with both high efficiency and a prolonged lifetime.