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Item type:Item, Synthesis, composition optimization, and VUV photoluminescence characterization of (Y,Gd) (V,P) O-4 : Eu3+ as a potential red-emitting plasma-display panel phosphor(2007-12-01) ;Wu, Chia-Chin ;Cheng, Bing-Ming ;Chen, Teng-Ming ;應用化學系Department of Applied ChemistryThe synthesis, composition optimization, VUV Photoluminescence (PL) spectra, and optical properties, of (Y, Gd) (V, P)O-4 : Eu3+ phosphors were investigated by synchrotron radiation. The VUV PLE spectra and the correlation among VUV PL intensity, lambda(em), and Eu3+, Gd3+, and P-content were established. The PLE spectral studies showed that (Y, Gd) (V, P)O-4: Eu3+ exhibited significant absorption in the VUV range. The VUV PL intensity was found to enhance with PO43- and Gd3+ -doping. Furthermore, the chromaticity characteristics of (Y, Gd) (V, P)O-4: Eu3+ were also found to be (0.6614, 0.3286) and compared against (Y, Gd)BO3:Eu3+ as a reference. Based on the characterization results, we are currently improving and evaluating the potential application of (Y, Gd) (V, P)O-4: Eu3+ as a new red-emitting PDP phosphor.Item type:Item, Visible quantum cutting in green-emitting BaGdF5 : Tb3+ phosphors via downconversion(2007-01-01) ;Tzeng, Hsin-Yi ;Cheng, Bing-Ming ;Chen, Teng-Ming ;應用化學系Department of Applied ChemistryThe visible quantum cutting (QC) under the excitation at 215 and 187nm in a newly discovered BaGdF5:Tb3+ via downconversion mechanism has been observed and investigated. We have measured the vacuum ultraviolet (VUV) excitation and emission spectra and proposed possible mechanisms to rationalize the observed QC effect. In QC process, one short-wavelength UV or one VUV photon absorbed by Tb3+ was found to split into more than one visible photon emitted by Tb3+ through cross-relaxation and subsequent direct energy transfer between Tb3+ and Tb3+ and/or Gd3+ ions, depending on the excitation wavelength. On the basis of the calculations from the emission spectra in the visible region obtained, we have obtained optimal quantum efficiency as high as 168% and 180% for green-emitting BaGdF5:Tb3+ under excitation at 215 and 187 nm, respectively. (c) 2006 Elsevier B.V. All rights reserved.