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Item type:Item, Er-Yb Codoped Ferroelectrics for Controlling Visible Upconversion Emissions(2009-05-01) ;Huang, Tung-Ching ;Hsieh, Wen-Feng ;光電工程學系Department of PhotonicsUnder a 980 nm laser pumping, quenching of green upconversion (UC) emission accompanied with enhancement of red UC emission observed was dominated by the energy back-transfer (EBT) process in Er(3+) and Yb(3+) codoped PbTiO(3), BaTiO(3), and SrTiO(3) polycrystalline powders. The efficiency of the EBT process depends not only on Yb(3+) concentration but also on level match of the doped Er(3+) and Yb(3+) ions caused by the crystal fields with different symmetries. Our UC emission spectra and X-ray diffraction confirm that the centrosymmetric crystal field arising from reducing tetragonality causes level match of transition (4)S(3/2) -> (4) I(13/2) of Er(3+) and (2)F(7/2) -> (2) F(5/2) of Yb(3+). This level match is responsible for enhancing red UC emission.Item type:Item, Destruction of the short-range disorder due to erbium doping in Pb(0.8)La(0.2)TiO(3)films(2010-05-01) ;Huang, Tung-Ching ;Hsieh, Wen-Feng ;光電工程學系Department of PhotonicsWe show the destruction of a displacement of Ti in the short-range structure by observing the disappearance of emission and Raman signals when the Er(3+) concentration exceeds 7 mol% in sol-gel-derived Pb(0.8)La(0.2)TiO(3) polycrystalline films. It is believed that there always exists disorder due to displacement of B ions in the skeleton of BO(6) in perovskite ABO(3) materials. This disorder due to the displacement of Ti ions breaks the center of symmetry to activate emission of rare-earth ions such as Er(3+) and Raman modes of perovskites. We found that the breaking of symmetry can be diminished by introducing more Er(3+) ions. Copyright (C) 2009 John Wiley & Sons, Ltd.