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收集所有交通大學研究人員與學生個人或團體所發表之各項學術著作,涵蓋期刊論文、教師專書、學位論文等項。;;Collections of Publications of NCTU Researchers and Students Like Journal Papers and Thesis.
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Item type:Item, Eclipsed digermylenes as building blocks to construct catenated multinuclear germanium chains and rings(2019-08-25) ;Wey, Yu-Te ;Huang, Guo-Tao ;Yu, Jen-Shiang ;Tsai, Yi-Chou生物科技學系Item type:Item, Reversible Cleavage/Formation of the Chromium-Chromium Quintuple Bond in the Highly Regioselective Alkyne Cyclotrimerization(2017-11-27) ;Huang, Yu-Siang ;Huang, Gou-Tao ;Liu, Yao-Lun ;Yu, Jen-Shiang K.Tsai, Yi-ChouHerein we report the employment of the quintuply bonded dichromium amidinates [Cr{(2)-HC(N-2,6-(Pr2C6H3)-Pr-i)(N-2,6-R2C6H3)}](2) (R=iPr (1), Me (7)) as catalysts to mediate the [2+2+2] cyclotrimerization of terminal alkynes giving 1,3,5-trisubstituted benzenes. During the catalysis, the ultrashort Cr-Cr quintuple bond underwent reversible cleavage/formation, corroborated by the characterization of two inverted arene sandwich dichromium complexes (-(6):(6)-1,3,5-(Me3Si)(3)C6H3)[Cr{(2)-HC(N-2,6-(Pr2C6H3)-Pr-i)(N-2,6-R2C6H3)}](2) (R=Pr-i (5), Me (8)). In the presence of sigma donors, such as THF and 2,4,6-Me3C6H2CN, the bridging arene 1,3,5-(Me3Si)(3)C6H3 in 5 and 8 was extruded and 1 and 7 were regenerated. Theoretical calculations were employed to disclose the reaction pathways of these highly regioselective [2+2+2] cylcotrimerization reactions of terminal alkynes.Item type:Item, Theory-Guided Experiments on the Mechanistic Elucidation of the Reduction of Dinuclear Zinc, Manganese, and Cadmium Complexes(2011) ;Lu, Duan-Yen ;Yu, Jen-Shiang K. ;Kuo, Ting-Shen ;Lee, Gene-HsiangWang, YuItem type:Item, Reactions of Metal-Metal Quintuple Bonds with Alkynes: [2+2+2] and [2+2] Cycloadditions(2012) ;Chen, Hong-Zhang ;Liu, Shih-Cheng ;Yen, Chun-Hsu ;Yu, Jen-Shiang K.Shieh, Yun-JenItem type:Item, Stepwise Construction of the Cr-Cr Quintuple Bond and Its Destruction upon Axial Coordination(2012) ;Huang, Yu-Lun ;Lu, Duan-Yen ;Yu, Hsien-Cheng ;Yu, Jen-Shiang K.Hsu, Chia-WeiItem type:Item, An Electron-Rich Molybdenum-Molybdenum Quintuple Bond Spanned by One Lithium Atom(2012) ;Liu, Shin-Cheng ;Ke, Wei-Lun ;Yu, Jen-Shiang K. ;Kuo, Ting-ShenTsai, Yi-ChouItem type:Item, A three-coordinate and quadruply bonded Mo-Mo complex(2006-11-01) ;Tsai, Yi-Chou ;Lin, Yang-Miin ;Yu, Jen-Shiang K. ;Hwang, Jenn-Kang生物科技學系Item type:Item, Structural transformations in dinuclear zinc complexes involving Zn-Zn bonds(2007) ;Tsai, Yi-Chou ;Lu, Duan-Yen ;Lin, Yang-Miin ;Hwang, Jenn-KangYu, Jen-Shiang K.Reduction of Zn-2(mu-eta(2)- Me2Si( NDipp)(2))(2) with 4 equiv. of KC8 resulted in a dramatic structural transformation into [(eta(2)- Me2Si( NDipp)(2)) ZnZn(eta(2)- Me2Si( NDipp)(2))](2-) featuring a Zn - Zn bond instead of [Zn-2(mu-eta(2)- Me2Si( NDipp)(2))(2)](2-); the mechanism of the observed structural transformations arising from the Zn - Zn bond formation involving the intermediate of [Zn-2(mu-eta(2)- Me2Si( NDipp)(2))(2)](-) was elucidated by elaborate computations.Item type:Item, Syntheses and structures of low-coordinate and multiply-bonded M-M complexes(2007-03-25) ;Tsai, Yi-Chou ;Lin, Yang-Miin ;Yu, Jen-Shiang K. ;Hwang, Jenn-Kang生物科技學系Item type:Item, Quintuply-Bonded Dichromium(I) Complexes Featuring Metal-Metal Bond Lengths of 1.74 angstrom(2008) ;Hsu, Chia-Wei ;Yu, Jen-Shiang K. ;Yen, Chun-Hsu ;Lee, Gene-HsiangWang, Yu